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Section 1 - Chemical Product
MSDS Name:Phosphorus pentachloride Material Safety Data Sheet
Synonym:Phosphorus Perchloride; Phosphoric Chloride
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
|| Chemical Name
|| Phosphorus Pentachloride
|| ca 100
Hazard Symbols: C
Risk Phrases: 34 37
Section 3 - HAZARDS IDENTIFICATION
Causes burns. Irritating to respiratory system.Corrosive.Water-Reactive.
Potential Health Effects
Causes severe eye burns.
Causes skin burns.
Causes digestive tract burns with immediate pain, swelling of the throat, convulsions, and possible coma. May be harmful if swallowed.
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Call a poison control center.
Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Use extinguishing media appropriate to the surrounding fire. Substance is noncombustible. Contact with water can cause violent liberation of heat and splattering of the material.
Do NOT use water directly on fire. Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. If water is the only media available, use in flooding amounts. Use carbon dioxide or dry chemical.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Vacuum or sweep up material and place into a suitable disposal container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Section 7 - HANDLING and STORAGE
Wash thoroughly after handling. Wash hands before eating. Minimize dust generation and accumulation. Follow all MSDS and label precautions even after container is emptied because they may contain product residues. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Do not allow contact with water.
Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Keep containers tightly closed.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: solid
Appearance: white to pale yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 167 deg C
Autoignition Temperature: Noncombustible
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Reacts with water.
Specific Gravity/Density: Not available.
Molecular Formula: PCl5
Molecular Weight: 208.2388
Section 10 - STABILITY AND REACTIVITY
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, contact with water.
Incompatibilities with Other Materials:
Reacts violently with water. Alcohols, amines, aluminum, sodium, potassium acids.
Hazardous Decomposition Products:
Hydrogen chloride, oxides of phosphorus, irritating and toxic fumes and gases, phosphorous fumes.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
CAS# 10026-13-8: TB6125000 LD50/LC50:
CAS# 10026-13-8: Inhalation, rat: LC50 = 205 mg/m3; Oral, rat: LD50 = 660 mg/kg.
Phosphorus Pentachloride - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
No information available.
No information available.
No information available.
Section 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives
Hazard Symbols: C
R 34 Causes burns.
R 37 Irritating to respiratory system.
S 7/8 Keep container tightly closed and dry.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
WGK (Water Danger/Protection)
CAS# 10026-13-8: 1
United Kingdom Occupational Exposure Limits
CAS# 10026-13-8: OES-United Kingdom, TWA 0.1 ppm TWA; 0.87 mg/m3 TWA
CAS# 10026-13-8 is listed on Canada's DSL List.
CAS# 10026-13-8 is listed on Canada's Ingredient Disclosure List.
CAS# 10026-13-8: OEL-AUSTRALIA:TWA 0.1 ppm (1 mg/m3)
OEL-BELGIUM:TWA 0.1 ppm (0.85 mg/m3)
OEL-DENMARK:TWA 1 mg/m3
OEL-FINLAND:STEL 1 mg/m3;Skin
OEL-FRANCE:TWA 0.1 ppm (1 mg/m3)
OEL-GERMANY:TWA 1 mg/m3
OEL-JAPAN:TWA 0.1 ppm (0.85 mg/m3)
OEL-THE NETHERLANDS:TWA 1 mg/m3
OEL-THE PHILIPPINES:TWA 1 mg/m3
OEL-POLAND:TWA 0.3 mg/m3
OEL-RUSSIA:TWA 0.1 ppm;STEL 0.2 mg/m3;Skin
OEL-SWITZERLAND:TWA 1 mg/m3;STEL 2 mg/m3
OEL-THAILAND:TWA 1 mg/m3
OEL-TURKEY:TWA 1 mg/m3
OEL-UNITED KINGDOM:TWA 0.1 ppm (1 mg/m3)
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 10026-13-8 is listed on the TSCA inventory.
SECTION 16 - ADDITIONAL INFORMATION