methyl methacrylate
CAS No.: 80-62-6 Formula: C5H8O2 Molecular Weight: 100.11600
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methyl methacrylate

CAS No.: 80-62-6 Formula: C5H8O2 Molecular Weight: 100.11600
Suppliers: All (75) China Suppliers (75) Price Available (13) Contractor (3)

Description

Methyl methacrylate (MMA) is an organic compound with the formula CH2=C(CH3)COOCH3. This colourless liquid, the methyl ester of methacrylic acid (MAA) is a monomer produced on a large scale for the production of poly(methyl methacrylate) (PMMA).

Basic Info

Chemical Name methyl methacrylate
Synonyms

2-Propenoicacid, 2-methyl-, methyl ester; Methyl methacrylate; 2-Propenoic acid, 2-methyl-, methyl ester;

CAS No. 80-62-6
Molecular Formula C5H8O2
Molecular Weight 100.11600
PSA 26.30000
LogP 0.73550

Properties

Appearance & Physical State COLOURLESS LIQUID
Density 0.943
Boiling Point 100ºC
Melting Point -48ºC
Flash Point 8ºC
Refractive Index 1.413-1.415
Storage Condition Refrigerator

Safety Info

Safety Statements S24-S37-S46
HS Code 3824909990
Packing Group II
RIDADR UN 1247
Risk Statements R11; R37/38; R43
Hazard Codes F

Synthesis Route

Total 104 Documents >>
Yoshida, Akihiro; Hao, Xiuhua; Yamazaki, Osamu; Nishikido, Joji
Molecules, 2006 , vol. 11, # 8 p. 627 - 640
Asahi Kasei Kogyo Kabushiki Kaisha
Patent: US4518796 A1, 1985 ;
Sumitomo Chemical Co., Ltd
Patent: EP2487179 A1, 2012 ;
Location in patent: Page/Page column 19 ;
SDS Version: 1.0 Expand

SDS Version: 1.0

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Download/Modify | Technical supported by XiXisys.com. For US version, EU version (23 languages) and more, please refer to xixisys.com/en/sds/search

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name methyl methacrylate

1.2 Other means of identification

Product number -
Other names 2-Propenoic acid, 2-methyl-, methyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Methyl methacrylate is used in the manufacture of methacrylate resins and plastics (e.g., Plexiglas). (,,,11) The principal uses of methyl methacrylate are: cast sheet and other grades (advertising signs and displays, lighting fixtures, glazing and skylights, building panels and sidings, and plumbing and bathroom fixtures), molding/extrusion powder, and coatings (latex paints, lacquer, and enamel resins). Methyl methacrylate is used in the impregnation of concrete to make it water-repellent, and also has uses in the fields of medicine and dentistry to make prosthetic devices and as a ceramic filler or cement.
Uses advised against no data available

1.4 Supplier's details

Company XiXisys.com
Address XiXisys.com
Telephone XiXisys.com
Fax XiXisys.com

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Flammable liquids, Category 2

Skin irritation, Category 2

Skin sensitization, Category 1

Specific target organ toxicity – single exposure, Category 3

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word

Danger

Hazard statement(s)

H225 Highly flammable liquid and vapour

H315 Causes skin irritation

H317 May cause an allergic skin reaction

H335 May cause respiratory irritation

Precautionary statement(s)
Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P233 Keep container tightly closed.

P240 Ground and bond container and receiving equipment.

P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment.

P242 Use non-sparking tools.

P243 Take action to prevent static discharges.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P264 Wash ... thoroughly after handling.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P272 Contaminated work clothing should not be allowed out of the workplace.

P271 Use only outdoors or in a well-ventilated area.

Response

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

P370+P378 In case of fire: Use ... to extinguish.

P302+P352 IF ON SKIN: Wash with plenty of water/...

P321 Specific treatment (see ... on this label).

P332+P313 If skin irritation occurs: Get medical advice/attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P312 Call a POISON CENTER/doctor/…if you feel unwell.

Storage

P403+P235 Store in a well-ventilated place. Keep cool.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Disposal

P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS number EC number Concentration
methyl methacrylate methyl methacrylate 80-62-6 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

Fresh air, rest. Refer for medical attention.

In case of skin contact

Remove contaminated clothes. Rinse and then wash skin with water and soap.

In case of eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

If swallowed

Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .

4.2 Most important symptoms/effects, acute and delayed

Irritation of eyes, nose, and throat. Nausea and vomiting. Liquid may cause skin irritation. (USCG, 1999)

4.3 Indication of immediate medical attention and special treatment needed, if necessary

Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Esters and related compounds/

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Use dry chemical, carbon dioxide, or foam extinguishers. Vapors are heavier than air and will collect in low areas. Vapors may travel long distances to ignition sources and flashback. Vapors in confined areas may explode when exposed to fire. Containers may explode in fire. Storage containers and parts of containers may rocket great distances, in many directions. If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated waters. Notify local health and fire officials and pollution control agencies. From a secure, explosion-proof location, use water spray to cool exposed containers. If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of deforming), withdraw immediately to a secure position.

5.2 Specific hazards arising from the chemical

Behavior in Fire: Vapor is heavier than air and may travel a considerable distance to a source of ignition and flash back. Containers may explode in fire or when heated because of polymerization. (USCG, 1999)

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Personal protection: chemical protection suit and filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Remove all ignition sources. Do NOT wash away into sewer. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

6.3 Methods and materials for containment and cleaning up

SRP: Wastewater from contaminant suppression, cleaning of protective clothing/equipment, or contaminated sites should be contained and evaluated for subject chemical or decomposition product concentrations. Concentrations shall be lower than applicable environmental discharge or disposal criteria. Alternatively, pretreatment and/or discharge to a permitted wastewater treatment facility is acceptable only after review by the governing authority and assurance that "pass through" violations will not occur. Due consideration shall be given to remediation worker exposure (inhalation, dermal and ingestion) as well as fate during treatment, transfer and disposal. If it is not practicable to manage the chemical in this fashion, it must be evaluated in accordance with EPA 40 CFR Part 261, specifically Subpart B, in order to determine the appropriate local, state and federal requirements for disposal.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Fireproof. Separated from strong oxidants, strong bases and strong acids. Cool. Keep in the dark. Keep in a well-ventilated room. Store only if stabilized.Before entering confined space where this chemical may be present, check to make sure that an explosive concentration does not exist. Methyl methacrylate must be stored to avoid contact with oxidizers, such as nitrates, permanganates, perchlorates, chlorates, and peroxides; strong alkalis, such as sodium hydroxide and potassium hydroxide, and strong acids, such as nitric acid, hydrochloric acid, and sulfuric acid, since violent reactions occur. Store in tightly closed containers in a cool, well ventilated area away from light, heat, and ionizing radiation, because methyl methacrylate will react and release heat quickly causing an explosion. Store with an appropriate inhibitor. Lack of an appropriate inhibitor may cause an explosive reaction.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

Recommended Exposure Limit: 10 hr Time-Weighted avg: 100 ppm (410 mg/cu m).

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state COLOURLESS LIQUID
Colour Colorless volatile liquid
Odour Characteristic quality: sulfur-like, sweet, sharp; hedonic tone: unpleasant
Melting point/ freezing point 162°C(lit.)
Boiling point or initial boiling point and boiling range 100°C
Flammability Class IB Flammable Liquid: Fl.P. below 22.78°C and BP at or above 37.78°C.Highly flammable.
Lower and upper explosion limit / flammability limit Lower 1.7%; Upper 8.2% (by volume)
Flash point 9°C(lit.)
Auto-ignition temperature 421.11°C (USCG, 1999)
Decomposition temperature no data available
pH no data available
Kinematic viscosity no data available
Solubility 1 to 10 mg/mL at 17.5°C
Partition coefficient n-octanol/water (log value) log Kow = 1.38
Vapour pressure 40 mm Hg at 25.5°C
Density and/or relative density 0.943
Relative vapour density 3.45 (Relative to Air)
Particle characteristics no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

A very dangerous fire hazard when exposed to heat or flame ...The vapour mixes well with air, explosive mixtures are easily formed. Vapours are uninhibited and may polymerize, causing blockage of vents.METHYL METHACRYLATE MONOMER, may polymerize if contaminated or subjected to heat. If polymerization takes place in a container, the container is subject to violent rupture. Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979. p.151-154, 164]. Peroxides may also initiate exothermic polymierization of the bulk material [Bretherick 1979. p. 160]. Benzoyl peroxide was weighed into a beaker that had previously been rinsed with methyl methacrylate. The peroxide catalyzed polymerization of the methyl methacrylate and the build-up of heat ignited the remaining peroxide [MCA Case History 996. 1964].

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

... Can react with oxidizing materials.

10.6 Hazardous decomposition products

When heated to decomposition it emits acrid smoke and irritating fumes.

11.Toxicological information

Acute toxicity

  • Oral: LD50 Rat oral 9400 mg/kg.
  • Inhalation: LC50 Rat inhalation 11,250 - 12,500 ppm/2 hr
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

Evaluation: There is inadequate evidence in humans for the carcinogenicity of methyl methacrylate. There is evidence suggesting lack of carcinogenicity of methyl methacrylate in experimental animals. Overall evaluation: Methyl methacrylate is not classifiable as to its carcinogenicity to humans (Group3).

Reproductive toxicity

No adequate reproductive or developmental studies in humans are available. Inhalation exposure of rats to maternally-toxic levels of methyl methacrylate resulted in fetal abnormalities (hematomas and skeletal anomalies) and decreased fetal weight and crown-rump length.

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

  • Toxicity to fish: LC50; Species: Lepomis macrochirus (Bluegill, juvenile, length 3.65 cm, weight 0.90 g); Conditions: freshwater, flow through, 22°C, pH 6-8, dissolved oxygen >7.5 mg/L; Concentration: 420 mg/L for 1 hr /practical grade
  • Toxicity to daphnia and other aquatic invertebrates: LC50; Species: Daphnia magna (Water flea, age < or =24 hr); Conditions: freshwater, static, 20-22°C, pH 7.6-7.7; Concentration: 1760 mg/L for 24 hr /formulation
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available

12.2 Persistence and degradability

AEROBIC: Methyl methacrylate, present at 100 mg/L, reached 94% of its theoretical BOD in 2 weeks using an activated sludge inoculum in the Japanese MITI test(1). In the modified Japanese MITI test, methyl methacrylate reached 32% of its theoretical BOD after 28 days; in a closed bottle test, methyl methacrylate released 88% of carbon dioxide evolution after 28 days; and >95% methyl methacrylate was degraded in the Zahn-Wellens test, time not specified(2). Methyl methacrylate was reported to be completely degraded by activated sludge in approximately 20 hours(3). In a standard biodegradability test using sewage seed, 42% of the theoretical BOD was consumed in 19 days, including a 3-4 day lag period; with acclimated seed, 66% of the theoretical BOD was consumed in 22 days(4). The biodegradation rate for methyl methacrylate at 75 ppm starting concentration, treated using a mixed microbial population immobilized in calcium alginate gel, was 9.3 ppm/hr; this corresponded to 89% removal due to biodegradation(5).

12.3 Bioaccumulative potential

An estimated BCF of 4 was calculated in fish for methyl methacrylate(SRC), using a log Kow of 1.38(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).

12.4 Mobility in soil

The Koc of methyl methacrylate has been measured as 9-72(1) and as high as 95(2). According to a classification scheme(3), this Koc range suggests that methyl methacrylate is expected to have very high to high mobility in soil.

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: UN1247 IMDG: UN1247 IATA: UN1247

14.2 UN Proper Shipping Name

ADR/RID: METHYL METHACRYLATE MONOMER, STABILIZED
IMDG: METHYL METHACRYLATE MONOMER, STABILIZED
IATA: METHYL METHACRYLATE MONOMER, STABILIZED

14.3 Transport hazard class(es)

ADR/RID: 3 IMDG: 3 IATA: 3

14.4 Packing group, if applicable

ADR/RID: II IMDG: II IATA: II

14.5 Environmental hazards

ADR/RID: no IMDG: no IATA: no

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS number EC number
methyl methacrylate methyl methacrylate 80-62-6 none
European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
EC Inventory Listed.
United States Toxic Substances Control Act (TSCA) Inventory Listed.
China Catalog of Hazardous chemicals 2015 Listed.
New Zealand Inventory of Chemicals (NZIoC) Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.
Vietnam National Chemical Inventory Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

16.Other information

Information on revision

Creation Date Aug 12, 2017
Revision Date Aug 12, 2017

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
MSDS Expand
1H NMR : 90 MHz in CDCl3Expand

NMR Spectrum 1H NMR : 90 MHz in CDCl3

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C5 H8 O2 0.04 ml : 0.5 ml CDCl3
methyl methacrylate

Assign. Shift(ppm)
A 6.098
B 5.554
C 3.752
D 1.946

J(A,B)=1.7HZ, J(A,D)=-1.0HZ, J(B,D)=-1.6HZ

IR : liquid filmExpand
Mass spectrum (electron ionization)Expand
Raman : 4880 A,200 M,liquidExpand
UV/Visible spectrumExpand

GC Analysis

Total 32 Documents >>
Column type Active phase Temperature (°C) Retention Index (I) Temperature Control Method
Capillary RTX-5 100. 714.3 isothermal
Capillary RTX-5 120. 717.33 isothermal
Capillary RTX-5 60. 716.28 isothermal
Capillary RTX-5 80. 713.44 isothermal
Capillary OV-101 120. 696. isothermal
Exposure Route Type of Test Species Observed Dose/Duration Toxic Effects
Administration onto the skin Open irritation test Rodent - rabbit 10 gm/kg -
Administration into the eye Standard Draize test Rodent - rabbit 150 mg -
Inhalation TCLo - Lowest published toxic concentration Human 125 ppm 1.Behavioral-sleep
2.Behavioral-excitement
3.Behavioral-anorexia (human)
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