Section 1. Chemical Product and Company Identification
Section 4. First Aid Measures
Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Cold water may be used. Get medical attention if irritation occurs.
Skin Contact In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient.
Remove contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse.
Thoroughly clean shoes before reuse. Get medical attention.
Serious Skin Contact Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek
immediate medical attention.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical attention.
Serious Inhalation Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. Seek medical attention.
Ingestion If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical
Serious Ingestion Not available.
Section 5. Fire and Explosion Data
Flammability of the Product May be combustible at high temperature.
Auto-Ignition Temperature Not available.
Flammable Limits Not available.
Products of Combustion These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).
Fire Hazards in Presence of Slightly flammable to flammable in presence of heat.
Various Substances Non-flammable in presence of shocks.
Risks of explosion of the product in presence of mechanical impact: Not available.
Explosion Hazards in
Risks of explosion of the product in presence of static discharge: Not available.
Presence of Various
Fire Fighting Media SMALL FIRE: Use DRY chemical powder.
and Instructions LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Not available.
Special Remarks on Explosion Not available.
Section 6. Accidental Release Measures
Small Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill Poisonous solid.
Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray
to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all
Section 7. Handling and Storage
Precautions Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do
not ingest. Do not breathe dust. Avoid contact with skin. Wear suitable protective clothing. In case of
insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately
and show the container or the label.
Keep container tightly closed. Keep container in a cool, well-ventilated area. Sensitive to light. Store in
Section 8. Exposure Controls/Personal Protection
Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels
below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep
exposure to airborne contaminants below the exposure limit.
Personal Protection Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be
a Large Spill used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a
specialist BEFORE handling this product.
Exposure Limits Not available.
Section 9. Physical and Chemical Properties
Physical state and appearance Solid. (Solid powder.) Odor Odorless.
pH (1% soln/water)
Boiling Point Not available.
Melting Point 150°C (302°F)
Critical Temperature Not available.
Specific Gravity Not available.
Vapor Density Not available.
Odor Threshold Not available.
Water/Oil Dist. Coeff. Not available.
Ionicity (in Water) Not available.
Dispersion Properties See solubility in water, methanol.
Soluble in cold water, methanol.
Solubility in water - 1 g/40 ml water
Section 10. Stability and Reactivity Data
The product is stable.
Instability Temperature Not available.
Conditions of Instability Excess heat, incompatible materials
Incompatibility with various Reactive with oxidizing agents, acids.
Non-corrosive in presence of glass.
Special Remarks on Sensitive to light. May discolor on exposure to light.
Special Remarks on
Polymerization Will not occur.
Section 11. Toxicological Information
Routes of Entry Eye contact. Inhalation. Ingestion.
Toxicity to Animals Acute oral toxicity (LD50): 18 mg/kg [Rat].
Chronic Effects on Humans Not available.
Other Toxic Effects on Very hazardous in case of ingestion, of inhalation.
Hazardous in case of skin contact (permeator).
Slightly hazardous in case of skin contact (irritant).
Special Remarks on Not available.
Toxicity to Animals
Special Remarks on Not available.
Chronic Effects on Humans
Special Remarks on other Acute Potential Health Effects:
Toxic Effects on Humans Warning: May Be Habit Forming.
Skin: It may cause skin irritation. It may be absorbed through intact skin. Harmful if absorbed through skin.
Symptoms may parallel that of ingestion.
Eyes: It may cause mild irritation. It may have a strong narcotic effect (pupil contraction) and the eyes may
serve as an absorption route to the body in general.
Inhalation: Narcotic. Harmful if inhaled. It can cause respiratory tract irritation and sneezing or coughing.
It may also have an anesthetic effect. Inhalation of large amounts may produce lung edema, respiratory
difficulties, and affect behavior/central nervous system (affects similar to ingestion).
Ingestion: Toxic! Narcotic. It may be fatal if swallowed. It may cause gastric disturbances such as stomach
pain, upset stomach, nausea, vomiting, and constipation. Ingestion of large amounts may affect
behavior/central nervous system/peripheral nervous system (central nervous system depression or
excitation - general anesthetic, headache, restlessness, skeletal and thoracic muscle rigidity, euphoria,
somnolence, convulsions, lightheadedness, drowsiness, fainting, dizziness; flaccid paralysis),
respiration(respiratory depressant), eyes (miosis (pupil contraction), blurred vision)and cardiovascular
system (hypotension, hypertension, bradycardia, circulatory depression, cardiac arrest). When ingested with
a tranquilizer, the following adverse reactions may occur: increased risk of cardiovascular depression chills
and/or shivering, restlessness, hallucinatory episodes, mental depression.
Chronic Potential Health Effects:
Ingestion: May be habit forming upon prolonged or repeated ingestion.
Skin and Inhalation: Prolonged or repeated exposure may cause allergic reactions with skin rashes, itiching,
coughs, stuffy nose, asthma.
Section 12. Ecological Information
BOD5 and COD
Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation
products may arise.
Toxicity of the Products The products of degradation are less toxic than the product itself.
Special Remarks on the Not available.
Products of Biodegradation
Section 13. Disposal Considerations
Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental
Section 14. Transport Information
DOT Classification CLASS 6.1: Poisonous material.
UNNA: 2811 : Toxic Solid, Organic, n.o.s.(Fentanyl Citrate) PG: II
Special Provisions for
Section 15. Other Regulatory Information and Pictograms
No products were found.
Federal and State
California California prop. 65: This product contains the following ingredients for which the State of California has
Proposition 65 found to cause cancer which would require a warning under the statute: No products were found.
California prop. 65: This product contains the following ingredients for which the State of California has
found to cause birth defects which would require a warning under the statute: No products were found.
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances
Canada: Not listed on Canadian Domestic Substance List (DSL) or Canadian Non- Domestic Substance
China: Not listed on National Inventory.
Japan: Not listed on National Inventory (ENCS).
Korea: Not listed on National Inventory (KECI).
Philippines: Not listed on National Inventory (PICCS).
Australia: Listed on AICS.
WHMIS (Canada) CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).
DSCL (EEC) R23/24- Toxic by inhalation and in S36/37/39- Wear suitable protective clothing,
contact with skin. gloves and eye/face protection.
R28- Very toxic if swallowed. S45- In case of accident or if you feel unwell,
R42/43- May cause sensitization by seek medical advice immediately (show the
inhalation and skin contact. label where possible).
HMIS (U.S.A.) 3 National Fire Protection
1 Association (U.S.A.)
3 0 Reactivity
Dust respirator. Be sure to use an
approved/certified respirator or
SECTION 16 - ADDITIONAL INFORMATION