fentanyl citrate 990-73-8 MSDS

Section 1. Chemical Product and Company Identification
    Fentanyl citrate
    Common Name/
    Trade Name
    Fentanyl citrate

Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water    
    for at least 15 minutes. Cold water may be used. Get medical attention if irritation occurs.
    Skin Contact        In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient.    
    Remove contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse.
    Thoroughly clean shoes before reuse. Get medical attention.
    Serious Skin Contact        Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek    
    immediate medical attention.
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.    
    Get medical attention.
    Serious Inhalation        Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or    
    waistband. Seek medical attention.
    Ingestion        If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by    
    mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical
    attention immediately.
    Serious Ingestion        Not available.    

Section 5. Fire and Explosion Data
    Flammability of the Product May be combustible at high temperature.
    Auto-Ignition Temperature Not available.
    Not available.
    Flash Points
    Flammable Limits        Not available.    
    Products of Combustion        These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).    
    Fire Hazards in Presence of Slightly flammable to flammable in presence of heat.
    Various Substances        Non-flammable in presence of shocks.    
    Risks of explosion of the product in presence of mechanical impact: Not available.
    Explosion Hazards in
    Risks of explosion of the product in presence of static discharge: Not available.
    Presence of Various
    Fire Fighting Media        SMALL FIRE: Use DRY chemical powder.    
    and Instructions        LARGE FIRE: Use water spray, fog or foam. Do not use water jet.    
    Special Remarks on        Not available.    
    Fire Hazards
    Special Remarks on Explosion Not available.

Section 6. Accidental Release Measures
    Small Spill        Use appropriate tools to put the spilled solid in a convenient waste disposal container.    
    Large Spill        Poisonous solid.    
    Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray
    to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all
    Fentanyl citrate

Section 7. Handling and Storage
    Precautions        Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do    
    not ingest. Do not breathe dust. Avoid contact with skin. Wear suitable protective clothing. In case of
    insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately
    and show the container or the label.
    Keep container tightly closed. Keep container in a cool, well-ventilated area. Sensitive to light. Store in
    light-resistant containers.

Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels    
    below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep
    exposure to airborne contaminants below the exposure limit.
    Personal Protection        Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.    
    Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be
    a Large Spill        used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a    
    specialist BEFORE handling this product.
    Exposure Limits        Not available.    

Section 9. Physical and Chemical Properties
    Physical state and appearance Solid. (Solid powder.)        Odor        Odorless.    
    Not available.
    528.61 g/mole
    Molecular Weight
    Not available.
    pH (1% soln/water)
    Boiling Point        Not available.    
    Melting Point        150°C (302°F)    
    Critical Temperature        Not available.    
    Specific Gravity        Not available.    
    Not applicable.
    Vapor Pressure
    Vapor Density        Not available.    
    Not available.
    Odor Threshold        Not available.    
    Water/Oil Dist. Coeff.        Not available.    
    Ionicity (in Water)        Not available.    
    Dispersion Properties        See solubility in water, methanol.    
    Soluble in cold water, methanol.
    Solubility in water - 1 g/40 ml water

Section 10. Stability and Reactivity Data
    The product is stable.
    Instability Temperature        Not available.    
    Conditions of Instability        Excess heat, incompatible materials    
    Incompatibility with various Reactive with oxidizing agents, acids.
    Non-corrosive in presence of glass.
    Special Remarks on        Sensitive to light. May discolor on exposure to light.    
    Fentanyl citrate
    Not available.
    Special Remarks on
    Polymerization        Will not occur.    

Section 11. Toxicological Information
    Routes of Entry        Eye contact. Inhalation. Ingestion.    
    Toxicity to Animals        Acute oral toxicity (LD50): 18 mg/kg [Rat].    
    Chronic Effects on Humans Not available.
    Other Toxic Effects on        Very hazardous in case of ingestion, of inhalation.    
    Hazardous in case of skin contact (permeator).
    Slightly hazardous in case of skin contact (irritant).
    Special Remarks on        Not available.    
    Toxicity to Animals
    Special Remarks on        Not available.    
    Chronic Effects on Humans
    Special Remarks on other        Acute Potential Health Effects:    
    Toxic Effects on Humans        Warning: May Be Habit Forming.    
    Skin: It may cause skin irritation. It may be absorbed through intact skin. Harmful if absorbed through skin.
    Symptoms may parallel that of ingestion.
    Eyes: It may cause mild irritation. It may have a strong narcotic effect (pupil contraction) and the eyes may
    serve as an absorption route to the body in general.
    Inhalation: Narcotic. Harmful if inhaled. It can cause respiratory tract irritation and sneezing or coughing.
    It may also have an anesthetic effect. Inhalation of large amounts may produce lung edema, respiratory
    difficulties, and affect behavior/central nervous system (affects similar to ingestion).
    Ingestion: Toxic! Narcotic. It may be fatal if swallowed. It may cause gastric disturbances such as stomach
    pain, upset stomach, nausea, vomiting, and constipation. Ingestion of large amounts may affect
    behavior/central nervous system/peripheral nervous system (central nervous system depression or
    excitation - general anesthetic, headache, restlessness, skeletal and thoracic muscle rigidity, euphoria,
    somnolence, convulsions, lightheadedness, drowsiness, fainting, dizziness; flaccid paralysis),
    respiration(respiratory depressant), eyes (miosis (pupil contraction), blurred vision)and cardiovascular
    system (hypotension, hypertension, bradycardia, circulatory depression, cardiac arrest). When ingested with
    a tranquilizer, the following adverse reactions may occur: increased risk of cardiovascular depression chills
    and/or shivering, restlessness, hallucinatory episodes, mental depression.
    Chronic Potential Health Effects:
    Ingestion: May be habit forming upon prolonged or repeated ingestion.
    Skin and Inhalation: Prolonged or repeated exposure may cause allergic reactions with skin rashes, itiching,
    coughs, stuffy nose, asthma.

Section 12. Ecological Information
    Not available.
    Not available.
    BOD5 and COD
    Products of Biodegradation        Possibly hazardous short term degradation products are not likely. However, long term degradation    
    products may arise.
    Toxicity of the Products        The products of degradation are less toxic than the product itself.    
    of Biodegradation
    Special Remarks on the        Not available.    
    Products of Biodegradation
    Fentanyl citrate

Section 13. Disposal Considerations
    Waste Disposal        Waste must be disposed of in accordance with federal, state and local environmental    
    control regulations.

Section 14. Transport Information
    DOT Classification        CLASS 6.1: Poisonous material.    
    UNNA: 2811 : Toxic Solid, Organic, n.o.s.(Fentanyl Citrate) PG: II
    Not available.
    Special Provisions for
    DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
    No products were found.
    Federal and State
    California        California prop. 65: This product contains the following ingredients for which the State of California has    
    Proposition 65        found to cause cancer which would require a warning under the statute: No products were found.    
    California prop. 65: This product contains the following ingredients for which the State of California has
    found to cause birth defects which would require a warning under the statute: No products were found.
    OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
    Other Regulations
    EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances
    Canada: Not listed on Canadian Domestic Substance List (DSL) or Canadian Non- Domestic Substance
    List (NDSL).
    China: Not listed on National Inventory.
    Japan: Not listed on National Inventory (ENCS).
    Korea: Not listed on National Inventory (KECI).
    Philippines: Not listed on National Inventory (PICCS).
    Australia: Listed on AICS.
    WHMIS (Canada) CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).
    Other Classifications
    DSCL (EEC)        R23/24- Toxic by inhalation and in        S36/37/39- Wear suitable protective clothing,    
    contact with skin.        gloves and eye/face protection.    
    R28- Very toxic if swallowed.        S45- In case of accident or if you feel unwell,    
    R42/43- May cause sensitization by        seek medical advice immediately (show the    
    inhalation and skin contact.        label where possible).    
    Health Hazard
    HMIS (U.S.A.)        3 National Fire Protection    
    1 Flammability
    1 Association (U.S.A.)
    Fire Hazard
    3 0 Reactivity
    Specific hazard
    Personal Protection
    WHMIS (Canada)
    DSCL (Europe)
    Fentanyl citrate
    TDG (Canada)
    ADR (Europe)
    Protective Equipment
    Lab coat.
    Dust respirator. Be sure to use an
    approved/certified respirator or


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