1,3-dichloropropan-2-ol 96-23-1 MSDS
Name: 1 3-Dichloro-2-propanol 99% Material Safety Data Sheet
Synonym: alpha-Dichlorohydrin; sym-Dichloroisopropyl alcohol
CAS: 96-23-1
Section 1 - Chemical Product   MSDS Name:1 3-Dichloro-2-propanol 99% Material Safety Data Sheet
Synonym:alpha-Dichlorohydrin; sym-Dichloroisopropyl alcohol

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
96-23-1 1,3-Dichloro-2-propanol 99 202-491-9
Hazard Symbols: T
Risk Phrases: 21 25 45

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful in contact with skin. Toxic if swallowed. May cause cancer.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes mild skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. May cause narcotic effects in high concentration.
Chronic:
Animal studies indicate that the product may affect the liver and kidneys.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustible liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back.
Vapors can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide or alcohol type foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Keep away from heat and flame.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 96-23-1: Russia: 5 mg/m3 TWA Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear yellow
Odor: Ethereal odor
pH: Not available.
Vapor Pressure: 0.75 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 172-176 deg C @ 760 mm Hg
Freezing/Melting Point: -4 deg C
Autoignition Temperature: Not available.
Flash Point: 85 deg C ( 185.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.3510g/cm3
Molecular Formula: C3H6Cl2O
Molecular Weight: 128.99

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Unstable.
Conditions to Avoid:
Ignition sources.
Incompatibilities with Other Materials:
Strong acids, acid anhydrides, acid chlorides, strong oxidizing agents, strong reducing agents.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 96-23-1: UB1400000 LD50/LC50:
CAS# 96-23-1: Oral, mouse: LD50 = 25 mg/kg; Oral, mouse: LD50 = 93 mg/kg; Oral, rat: LD50 = 81 mg/kg; Oral, rat: LD50 = 81 mg/kg; Skin, rabbit: LD50 = 800 uL/kg; Skin, rabbit: LD50 = 590 mg/kg.
Carcinogenicity:
1,3-Dichloro-2-propanol - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: 1,3-DICHLOROPROPANOL-2
Hazard Class: 6.1
UN Number: 2750
Packing Group: II
IMO
Shipping Name: 1,3-DICHLOROPROPANOL-2
Hazard Class: 6.1
UN Number: 2750
Packing Group: II
RID/ADR
Shipping Name: 1,3-DICHLOROPROPANOL-2
Hazard Class: 6.1
UN Number: 2750
Packing group: II

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 45 May cause cancer.
R 21 Harmful in contact with skin.
R 25 Toxic if swallowed.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 96-23-1: 2
Canada
CAS# 96-23-1 is listed on Canada's DSL List.
CAS# 96-23-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 96-23-1 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

Home   |   Announcement   |   Partners   |   Business Cooperation   |   Suppliers   |   Products    |   About Us   |   Contact Us   |   Privacy Policy   |   Terms & Conditions   |   Legal Statement

Copyright © 2013-2016 MOLBASE All Rights Reserved ICP Shanghai 14014220