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pentan-3-one 96-22-0 MSDS
Name: 3-Pentanone 98% Material Safety Data Sheet
Synonym: Diethyl Ketone; Methacetone
CAS: 96-22-0
Section 1 - Chemical Product   MSDS Name:3-Pentanone 98% Material Safety Data Sheet
Synonym:Diethyl Ketone; Methacetone

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
96-22-0 3-Pentanone 98 202-490-3
Hazard Symbols: XI F
Risk Phrases: 11 37 66 67

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Highly flammable. Irritating to respiratory system. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness.Highly flammable.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Vapors may cause dizziness or suffocation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Will be easily ignited by heat, sparks or flame. Containers may explode if exposed to fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Water may be ineffective. Water may spread fire. If water is the only media available, use in flooding amounts.
For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Scoop up with a nonsparking tool, then place into a suitable container for disposal. Remove all sources of ignition. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat and flame. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 96-22-0: United Kingdom, WEL - TWA: 200 ppm TWA; 716 mg/m3 TWA United Kingdom, WEL - STEL: 250 ppm STEL; 895 mg/m3 STEL Belgium - TWA: 200 ppm VLE; 715 mg/m3 VLE France - VME: 200 ppm VME; 705 mg/m3 VME Germany: 700 mg/m3 TWA Malaysia: 200 ppm TWA; 705 mg/m3 TWA Netherlands: 200 ppm MAC; 705 mg/m3 MAC Spain: 200 ppm VLA-ED; 716 mg/m3 VLA-ED Spain: 300 ppm VLA-EC; 1075 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear, colorless
Odor: acetone-like
pH: Not available.
Vapor Pressure: 20 mbar @ 20 C
Viscosity: 0.469 mPas 20 deg C
Boiling Point: 102 deg C @ 760.00mm Hg
Freezing/Melting Point: 0 deg C
Autoignition Temperature: 445 deg C ( 833.00 deg F)
Flash Point: 13 deg C ( 55.40 deg F)
Explosion Limits, lower: 1.60 vol %
Explosion Limits, upper: 7.70 vol %
Decomposition Temperature:
Solubility in water: 4.7 g/100ml (20 c)
Specific Gravity/Density: .8160g/cm3
Molecular Formula: C5H10O
Molecular Weight: 86.13

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 96-22-0: SA8050000 LD50/LC50:
CAS# 96-22-0: Draize test, rabbit, eye: 50 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 500 mg/24H Mild; Oral, mouse: LD50 = 3100 mg/kg; Oral, mouse: LD50 = 3200 mg/kg; Oral, rat: LD50 = 2140 mg/kg; Skin, rabbit: LD50 = 20 mL/kg; Skin, rat: LD50 = 2100 mg/kg.
Carcinogenicity:
3-Pentanone - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: DIETHYL KETONE
Hazard Class: 3
UN Number: 1156
Packing Group: II
IMO
Shipping Name: DIETHYL KETONE
Hazard Class: 3.2
UN Number: 1156
Packing Group: II
RID/ADR
Shipping Name: DIETHYL KETONE
Hazard Class: 3
UN Number: 1156
Packing group: II

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 37 Irritating to respiratory system.
R 66 Repeated exposure may cause skin dryness or
cracking.
R 67 Vapours may cause drowsiness and dizziness.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 96-22-0: 1
Canada
CAS# 96-22-0 is listed on Canada's DSL List.
CAS# 96-22-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 96-22-0 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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