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Ethyl 2-Cyano-3-ethoxyacrylate
CAS No.: 94-05-3
Synonyms:
Formula: C8H11NO3
Exact Mass: 169.07400
Molecular Weight: 169.17800
PSA: 59.32000
LogP: 0.99348
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Ethyl 2-Cyano-3-ethoxyacrylate 94-05-3 MSDS
Name: Ethyl(ethoxymethylene)cyanoacetate 98% Material Safety Data Sheet
Synonym: Ethyl 2-cyano-3-ethoxyacrylat
CAS: 94-05-3
Section 1 - Chemical Product   MSDS Name:Ethyl(ethoxymethylene)cyanoacetate 98% Material Safety Data Sheet
Synonym:Ethyl 2-cyano-3-ethoxyacrylat

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
94-05-3 Ethyl(ethoxymethylene)cyanoacetate, 98 98% 202-299-5
Hazard Symbols: XN
Risk Phrases: 22 37/38 41 42/43

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to respiratory system and skin.
Risk of serious damage to eyes. May cause sensitization by inhalation and skin contact.Harmful.
Potential Health Effects
Eye:
May cause irreversible eye injury.
Skin:
May cause irritation with burning pain, itching and redness.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid contact with skin and eyes. Do not breathe dust, vapor, mist, or gas.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 94-05-3: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: off-white
Odor: odorless
pH: Not available.
Vapor Pressure: .1 hPa @ 20 deg C
Viscosity: Not available.
Boiling Point: 190 - 191 deg C @ 30.00mm Hg
Freezing/Melting Point: 51 - 53 deg C
Autoignition Temperature: Not available.
Flash Point: 130 deg C ( 266.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: <0.01 g/l (20 c)
Specific Gravity/Density:
Molecular Formula: C8H11NO3
Molecular Weight: 169.18

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, strong reducing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 94-05-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethyl(ethoxymethylene)cyanoacetate, 98% - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Daphniatoxicity: EC50 (Daphnia magna): 211.4 mg/l/40h

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 37/38 Irritating to respiratory system and skin.
R 41 Risk of serious damage to eyes.
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 94-05-3: 1
Canada
CAS# 94-05-3 is listed on Canada's NDSL List.
CAS# 94-05-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 94-05-3 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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