|Name:||4-Chloro-1-butanol 85% balance THF and HCl Material Safety Data Sheet|
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 10 20/21/22 36/37/38
Section 3 - HAZARDS IDENTIFICATION
Flammable. Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Causes eye irritation.
Causes skin irritation. Harmful if absorbed through the skin.
Harmful if swallowed. May cause irritation of the digestive tract.
Harmful if inhaled. Causes respiratory tract irritation.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid. Wash mouth out with water.
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Flammable liquid and vapor.
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Section 7 - HANDLING and STORAGE
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Store in a tightly closed container. Refrigerator/flammables.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 928-51-8: Personal Protective Equipment Eyes: Not available.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Clear liquid
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 58 - 60 deg C @ 3 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 36 deg C ( 96.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Solubility in water:
Specific Gravity/Density: 1.089
Molecular Formula: C4H9ClO
Molecular Weight: 108.5154
Section 10 - STABILITY AND REACTIVITY
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
CAS# 928-51-8: EL1325000 LD50/LC50:
CAS# 928-51-8: Oral, mouse: LD50 = 990 mg/kg; Oral, mouse: LD50 = 990 mg/kg.
4-Chloro-1-butanol - Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1933
Packing Group: III
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
S 16 Keep away from sources of ignition - No
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 928-51-8: No information available.
CAS# 928-51-8 is listed on Canada's DSL List.
CAS# 928-51-8 is not listed on Canada's Ingredient Disclosure List.
CAS# 928-51-8 is listed on the TSCA inventory.
SECTION 16 - ADDITIONAL INFORMATION