|Name:||2-(N-Ethylperfluorooctanesulfonamido)ethyl methacrylate stab. w/ Material Safety Data Sheet|
|Synonym:||2-(Ethyl((heptadecafluorooctyl)sulfonyl)-amino)-ethyl methacrylate; monomer for incorporating perfluoroalkyl groups in polymers|
Synonym:2-(Ethyl((heptadecafluorooctyl)sulfonyl)-amino)-ethyl methacrylate; monomer for incorporating perfluoroalkyl groups in polymers
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed.
Section 3 - HAZARDS IDENTIFICATION
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
May cause eye irritation.
May cause skin irritation. May be harmful if absorbed through the skin. The toxicological properties of this material have not been fully investigated.
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Polymerizes readily if not inhibited; heat can initiate reaction.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not let this chemical enter the environment.
Section 7 - HANDLING and STORAGE
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.)
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 92-84-2: Belgium - TWA: 5 mg/m3 VLE France - VME: 5 mg/m3 VME Malaysia: 5 mg/m3 TWA Netherlands: 5 mg/m3 MAC Spain: 5 mg/m3 VLA-ED CAS# 150-76-5: Belgium - TWA: 5 mg/m3 VLE France - VME: 5 mg/m3 VME Germany: 5 mg/m3 TWA Malaysia: 5 mg/m3 TWA Netherlands: 5 mg/m3 MAC Spain: 5 mg/m3 VLA-ED CAS# 376-14-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 48-55 C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Solubility in water:
Molecular Formula: C16H14F17NO4S
Molecular Weight: 639.33
Section 10 - STABILITY AND REACTIVITY
Stable only if stored and handled under recommended conditions. The stability of the product depends upon the availability of both dissolved oxygen and MEHQ inhibitor(CAS=150-76-5). The presence of oxygen is necessary for the MEHQ to function effectively. The product should never be stored under an inert gas atmosphere, but should always be stored under an atmosphere containing 5-21% oxygen by volume.
Conditions to Avoid:
Dust generation, loss of inhibitor.
Incompatibilities with Other Materials:
Strong oxidizing agents, polymerizing initiators.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: May occur.
Section 11 - TOXICOLOGICAL INFORMATION
CAS# 92-84-2: SN5075000 CAS# 150-76-5: SL7700000 CAS# 376-14-7 unlisted.
CAS# 92-84-2: Oral, mouse: LD50 = 5 gm/kg; Oral, rabbit: LD50 = 4 gm/kg.
CAS# 150-76-5: Draize test, rabbit, skin: 6 gm/12D (Intermittent) Mild; Draize test, rabbit, skin: 10%; Oral, rat: LD50 = 1600 mg/kg.
Phenothiazine - Not listed by ACGIH, IARC, or NTP.
4-Methoxyphenol - Not listed by ACGIH, IARC, or NTP.
2-(N-Ethylperfluorooctanesulfonamido)ethyl methacrylate - Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
Shipping Name: Not regulated.
Shipping Name: Not regulated.
Shipping Name: Not regulated.
Section 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
WGK (Water Danger/Protection)
CAS# 92-84-2: 2
CAS# 150-76-5: 1
CAS# 376-14-7: 2
CAS# 92-84-2 is listed on Canada's DSL List.
CAS# 150-76-5 is listed on Canada's DSL List.
CAS# 376-14-7 is listed on Canada's NDSL List.
CAS# 92-84-2 is listed on Canada's Ingredient Disclosure List.
CAS# 150-76-5 is listed on Canada's Ingredient Disclosure List.
CAS# 376-14-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 92-84-2 is listed on the TSCA inventory.
CAS# 150-76-5 is listed on the TSCA inventory.
CAS# 376-14-7 is listed on the TSCA inventory.
SECTION 16 - ADDITIONAL INFORMATION