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2,5-Diphenyloxazole
CAS No.: 92-71-7
Synonyms:
Formula: C15H11NO
Exact Mass: 221.08400
Molecular Weight: 221.25400
PSA: 26.03000
LogP: 4.00860
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2,5-Diphenyloxazole 92-71-7 MSDS
Name: CytoScint Liquid Scintillation Fluid Material Safety Data Sheet
Synonym: Non
CAS: 92-71-7
Section 1 - Chemical Product   MSDS Name:CytoScint Liquid Scintillation Fluid Material Safety Data Sheet
Synonym:Non

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
92-71-7 2,5-Diphenyloxazole <1 202-181-3
Hazard Symbols: XN N
Risk Phrases: 10 36/37/38 20 51/53

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Irritating to eyes, respiratory system and skin. Harmful by inhalation. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Contact with the skin defats the skin. May cause an allergic reaction in certain individuals. No skin absorption data found.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal. May cause central nervous system depression.
Inhalation:
May cause drowsiness, unconsciousness, and central nervous system depression. Causes irritation of the mucous membrane and upper respiratory tract.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Repeated inhalation may cause chronic bronchitis. May cause anemia and other blood cell abnormalities. Prolonged exposure may produce a narcotic effect. Prolonged or repeated exposure may cause nausea, dizziness, and headache.

Section 4 - FIRST AID MEASURES
  Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
Potential for aspiration if swallowed. Get medical aid immediately.
Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. This liquid floats on water and may travel to a source of ignition and spread fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Water may be ineffective. This material is lighter than water and insoluble in water. The fire could easily be spread by the use of water in an area where the water cannot be contained. Do NOT use straight streams of water.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Take precautionary measures against static discharges. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Keep away from heat, sparks and flame. Avoid breathing vapor or mist.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 92-71-7: CAS# 95-63-6: United Kingdom, WEL - TWA: (listed as trimethyl benzene): 25 ppm 125 mg/m3 TWA United Kingdom, WEL - STEL: (listed as trimethyl benzene): 75 ppm STEL; 375 mg/m3 STEL Belgium - TWA: (listed as trimethyl benzene): 20 ppm VLE; 120 mg/ VLE France - VME: (listed as trimethyl benzene): 25 ppm VME; 125 mg/m VME Germany: 20 ppm TWA; 100 mg/m3 TWA Japan: 25 ppm OEL; 120 mg/m3 OEL Malaysia: (listed as trimethyl benzene): 25 ppm TWA; 123 mg/m3 TW Netherlands: 20 ppm MAC; 100 mg/m3 MAC Spain: 20 ppm VLA-ED; 100 mg/m3 VLA-ED CAS# 9016-45-9: CAS# 13280-61-0: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear colorless
Odor: aromatic odor - pleasant odor
pH: Not available.
Vapor Pressure: 2.1 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 169 deg C @ 760 mm Hg
Freezing/Melting Point: -43.8 deg C
Autoignition Temperature: 500 deg C ( 932.00 deg F)
Flash Point: 49 deg C ( 120.20 deg F)
Explosion Limits, lower: 0.9 vol %
Explosion Limits, upper: 6.4 vol %
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 0.9 g/cm3
Molecular Formula: Not applicable.
Molecular Weight:

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 92-71-7: RP6825000 CAS# 95-63-6: DC3325000 CAS# 9016-45-9: AX0247000 AX0257000 MD0900000 MD0905000 OQ0248333 WZ4200000 WZ4375000 WZ4550000 WZ4725000 WZ4750000 CAS# 13280-61-0 unlisted.
LD50/LC50:
Not available.
CAS# 95-63-6: Inhalation, rat: LC50 = 18000 mg/m3/4H; Oral, mouse: LD50 = 6900 mg/kg; Oral, rat: LD50 = 5 gm/kg.
CAS# 9016-45-9: Draize test, rabbit, eye: 5 mg Severe; Draize test, rabbit, eye: 5 mg Severe; Draize test, rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, eye: 15 mg Severe; Draize test, rabbit, eye: 5 mg Severe; Oral, mouse: LD50 = >50 gm/kg; Oral, rat: LD50 = 4 gm/kg; Oral, rat: LD50 = 1310 mg/kg; Oral, rat: LD50 = 2590 uL/kg; Oral, rat: LD50 = >3 gm/kg; Oral, rat: LD50 = 4290 uL/kg; Oral, rat: LD50 = 3670 uL/kg; Oral, rat: LD50 = 3730 uL/kg; Oral, rat: LD50 = 4 gm/kg; Oral, rat: LD50 = 16 gm/kg; Skin, rabbit: LD50 = 2 mL/kg; Skin, rabbit: LD50 = 2830 uL/kg; Skin, rabbit: LD50 = 2520 uL/kg; Skin, rabbit: LD50 = 1780 uL/kg; Skin, rabbit: LD50 = 3970 uL/kg; Skin, rabbit: LD50 = 4490 uL/kg.
CAS# 13280-61-0.
Carcinogenicity:
2,5-Diphenyloxazole - Not listed by ACGIH, IARC, or NTP.
1,2,4-Trimethylbenzene - Not listed by ACGIH, IARC, or NTP.
Ethoxylated nonylphenol nonionic surfactant - Not listed by ACGIH, IARC, or NTP.
Benzene, 1,4-bis[2-(2-methylphenyl)ethenyl]- - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Fathead Minnow: LC50 = 7.72 mg/L; 96 Hr; Flow-through at 25 C (pH 7.24)Estimated Koc value = 720. 1,2,4-trimethylbenzene will have low mobility in soil. Volatilization from moist and dry soil surfaces is expected to occur. 1,2,4-Trimethylbenzene is expected to aerobically biodegrade in both soil and water. Anaerobic aquifer microcosms did not show significant biodegradation in comparison to poisoned controls. In water, 1,2,4-trimethylbenzene may adsorb to sediment or particulate matter.

Section 13 - DISPOSAL CONSIDERATIONS
  Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 10 Flammable.
R 20 Harmful by inhalation.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 92-71-7: No information available.
CAS# 95-63-6: 3
CAS# 9016-45-9: 2
CAS# 13280-61-0: No information available.
Canada
CAS# 92-71-7 is listed on Canada's DSL List.
CAS# 95-63-6 is listed on Canada's DSL List.
CAS# 9016-45-9 is listed on Canada's DSL List.
CAS# 13280-61-0 is listed on Canada's DSL List.
CAS# 92-71-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 95-63-6 is listed on Canada's Ingredient Disclosure List.
CAS# 9016-45-9 is not listed on Canada's Ingredient Disclosure List.
CAS# 13280-61-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 92-71-7 is listed on the TSCA inventory.
CAS# 95-63-6 is listed on the TSCA inventory.
CAS# 9016-45-9 is listed on the TSCA inventory.
CAS# 13280-61-0 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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