Picric acid 88-89-1 MSDS
Name: 2% Picric acid aqueous Material Safety Data Sheet
Synonym: None Known
CAS: 88-89-1
Section 1 - Chemical Product   MSDS Name:2% Picric acid aqueous Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
88-89-1 Picric acid 2.0% 201-865-9
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. If absorbed, causes symptoms similar to those of ingestion. May cause sensitization by skin contact.
Ingestion:
May cause irritation of the digestive tract. May cause liver and kidney damage. May cause headache. May cause tremors and convulsions.
May cause unconsciousness. May cause blood abnormalities.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to those described for ingestion. May cause kidney damage.
Chronic:
Prolonged or repeated skin contact may cause sensitization dermatitis and possible destruction and/or ulceration.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. This material is an explosion hazard when exposed to heat, mechanical shock, or friction.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Loosen closure cautiously before opening. Avoid contact with skin and eyes. Do not allow water to evaporate from product. Dry picric acid is explosive.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.
Exposure Limits CAS# 88-89-1: United Kingdom, WEL - TWA: 0.1 mg/m3 TWA United Kingdom, WEL - STEL: 0.3 mg/m3 STEL United States OSHA: 0.1 mg/m3 TWA Belgium - TWA: 0.1 mg/m3 VLE France - VME: 0.1 mg/m3 VME Germany: 0.1 mg/m3 TWA (inhalable fraction) Germany: Skin absorber Malaysia: 0.1 mg/m3 TWA Netherlands: 0.1 mg/m3 MAC Spain: 0.1 mg/m3 VLA-ED CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: Solution
Molecular Weight: 0

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Do not allow water to evaporate from product. Dry picric acid is explosive. Explodes above 572F (300C) with release of oxides of nitrogen.
Conditions to Avoid:
High temperatures, Do not allow water to evaporate from product. Dry picric acid is explosive..
Incompatibilities with Other Materials:
Metals; strong bases; ammonia; strong reducing agents; strong oxidizing agents; concrete; plaster; Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 88-89-1: TJ7875000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
CAS# 88-89-1: Oral, rat: LD50 = 200 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Picric acid - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Rainbow trout (Salmo gairdneri), LC50=109.6 mg/L/96 hr; American oysters (Crassotrea virginica), LC50=254.9 mg/L/14 hr; Bluegill (Lepomis macrachirus), LC50=193 mg/L/24 hr

Section 13 - DISPOSAL CONSIDERATIONS
  Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: Trinitrophenol, Wetted With >30% Water By Mass
Hazard Class: 4.1
UN Number: 1344
Packing Group: I
IMO
Shipping Name: Trinitrophenol, Wetted With >30% Water By Mass
Hazard Class: 4.1
UN Number: 1344
Packing Group: I
RID/ADR
Shipping Name: Trinitrophenol, Wetted With >30% Water By Mass
Hazard Class: 4.1
UN Number: 1344
Packing group: I

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 88-89-1: 2
CAS# 7732-18-5: No information available.
Canada
CAS# 88-89-1 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 88-89-1 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 88-89-1 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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