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2,4,6-trichlorophenol 88-06-2 MSDS
Name: 2 4 6-Trichlorophenol 98% Material Safety Data Sheet
Synonym: 1-Hydroxy-2,4,6-Trichlorobenzene
CAS: 88-06-2
Section 1 - Chemical Product   MSDS Name:2 4 6-Trichlorophenol 98% Material Safety Data Sheet
Synonym:1-Hydroxy-2,4,6-Trichlorobenzene

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
88-06-2 2,4,6-Trichlorophenol 98 201-795-9
Hazard Symbols: XN
Risk Phrases: 22 36/38 40

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes and skin. Limited evidence of a carcinogenic effect.
Potential Health Effects
Eye:
Causes severe eye irritation. May cause chemical conjunctivitis and corneal damage.
Skin:
May be harmful if absorbed through the skin. Causes skin irritation and possible burns. Substance is readily absorbed through the skin.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.
Inhalation:
Dust is irritating to the respiratory tract. Causes irritation of mucous membrane.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use carbon dioxide, dry chemical powder or water spray.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Cover with an activated carbon adsorbent and place into a closed container for disposal. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Use only in a chemical fume hood. Do not breathe dust.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 88-06-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystalline chunks
Color: light beige
Odor: None reported.
pH: Moderately acidic
Vapor Pressure: 1 hPa @ 77 deg C
Viscosity: Not available.
Boiling Point: 246 deg C @ 760 mm Hg
Freezing/Melting Point: 64 - 66 deg C
Autoignition Temperature: Not applicable.
Flash Point: 99 deg C ( 210.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 800 mg/L @ 25C
Specific Gravity/Density: 1.409
Molecular Formula: C6H3Cl3O
Molecular Weight: 197.45

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acid chlorides, acid anhydrides.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, chloride fumes.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 88-06-2: SN1575000 LD50/LC50:
CAS# 88-06-2: Draize test, rabbit, eye: 250 ug/24H Severe; Draize test, rabbit, skin: 20 mg/24H Moderate; Oral, mouse: LD50 = 770 mg/kg; Oral, rat: LD50 = 820 mg/kg.
Carcinogenicity:
2,4,6-Trichlorophenol - California: carcinogen, initial date 1/1/88 NTP: Suspect carcinogen Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Bluegill/Sunfish: LC50 = 0.72 mg/L; 24 hours; not specifiedFish: Bluegill/Sunfish: LC50 = 0.32 mg/L; 96 hours; not specifiedFish: Fathead Minnow: LC50 = 9.16 mg/L; 96 hours; flow through bioassay with measured concentrationsFish: Fathead Minnow: LC50 = 4.55 mg/L; 96 hours; flow through bioassay with measured concentrationsFish: Fathead Minnow: EC50 = 4.27 mg/L; 96 hours; flow through bioassay with measured concentrationsFish: Fathead Minnow: LC50 = 2.80 mg/L; 96 hours; flow through bioassay with measured concentrations

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: CHLOROPHENOLS, SOLID
Hazard Class: 6.1
UN Number: 2020
Packing Group: III
IMO
Shipping Name: CHLOROPHENOLS, SOLID
Hazard Class: 6.1
UN Number: 2020
Packing Group: III
RID/ADR
Shipping Name: CHLOROPHENOLS, SOLID
Hazard Class: 6.1
UN Number: 2020
Packing group: III
USA RQ: CAS# 88-06-2: 10 lb final RQ; 4.54 kg final RQ

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 88-06-2: No information available.
Canada
CAS# 88-06-2 is listed on Canada's NDSL List.
CAS# 88-06-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 88-06-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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