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Diethyl ethoxymethylenemalonate
CAS No.: 87-13-8
Synonyms:
Formula: C10H16O5
Exact Mass: 216.10000
Molecular Weight: 216.23100
PSA: 61.83000
LogP: 1.03300
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Diethyl ethoxymethylenemalonate 87-13-8 MSDS
Name: Diethyl Ethoxymethylenemalonate 99+% Material Safety Data Sheet
Synonym: Ethoxymethylenmalonic Acid Diethyleste
CAS: 87-13-8
Section 1 - Chemical Product   MSDS Name:Diethyl Ethoxymethylenemalonate 99+% Material Safety Data Sheet
Synonym:Ethoxymethylenmalonic Acid Diethyleste

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
87-13-8 Diethyl Ethoxymethylenemalonate 99+% 201-725-7
Hazard Symbols: XN
Risk Phrases: 42/43

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
May cause sensitization by inhalation and skin contact.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Ingestion Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 87-13-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 279.0 - 281.0 deg C @ 760.00m
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 144 deg C ( 291.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >279 deg C
Solubility in water: insoluble
Specific Gravity/Density: 1.0800g/cm3
Molecular Formula: C10H16O5
Molecular Weight: 216.23

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, acids, bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 87-13-8: OO1100000 LD50/LC50:
CAS# 87-13-8: Draize test, rabbit, skin: 500 mg/24H Moderate; Oral, mouse: LD50 = 2227 mg/kg; Oral, rat: LD50 = 925 mg/kg.
Carcinogenicity:
Diethyl Ethoxymethylenemalonate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 27 Take off immediately all contaminated clothing.
WGK (Water Danger/Protection)
CAS# 87-13-8: 1
Canada
CAS# 87-13-8 is listed on Canada's NDSL List.
CAS# 87-13-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 87-13-8 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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