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2-hydroxyethyl methacrylate 868-77-9 MSDS
Name: 2-Hydroxyethyl Methacrylate (Stabilized With 0.02 % w/v Material Safety Data Sheet
Synonym: Ethylene Glycol, Monomethacrylate; 2-Hydroxyethyl Ester Methacrylic Acid; Glycol Monomethacrylate
CAS: 868-77-9
Section 1 - Chemical Product   MSDS Name:2-Hydroxyethyl Methacrylate (Stabilized With 0.02 % w/v Material Safety Data Sheet
Synonym:Ethylene Glycol, Monomethacrylate; 2-Hydroxyethyl Ester Methacrylic Acid; Glycol Monomethacrylate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
868-77-9 2-Hydroxyethyl Methacrylate >99 % 212-782-2
Hazard Symbols: XI
Risk Phrases: 36/38 43

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Irritating to eyes and skin. May cause sensitization by skin contact.Moisture sensitive.Light sensitive.Heat sensitive.
Potential Health Effects
Eye:
Causes severe eye irritation.
Skin:
May cause severe skin irritation. May be absorbed through the skin in harmful amounts. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
May cause reproductive and fetal effects.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Do NOT get water inside containers. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Scoop up with a nonsparking tool, then place into a suitable container for disposal. Remove all sources of ignition. Provide ventilation. Do not get water inside containers.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Do not get on skin or in eyes. Avoid ingestion and inhalation. Store protected from light. Do not allow contact with water. Container should be opened by a technically qualified person.
Keep from contact with moist air and steam.
Storage:
Keep away from sources of ignition. Store in a cool place in the original container and protect from sunlight. Keep refrigerated.
(Store below 4C/39F.) Store in a tightly closed container. Store protected from moisture. Store protected from light.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 868-77-9: Netherlands: 0.05 ppm MAC; 0.24 mg/m3 MAC Russia: 20 mg/m3 TWA Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless to light yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.01 mm Hg @ 25 C
Viscosity: Not available.
Boiling Point: 250 deg C
Freezing/Melting Point: < -60 deg C
Autoignition Temperature: Not applicable.
Flash Point: 207 deg F ( 97.22 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Miscible with water.
Specific Gravity/Density: 1.07
Molecular Formula: C6H10O3
Molecular Weight: 130.0682

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Unstable.
Conditions to Avoid:
High temperatures, incompatible materials, light, ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Moisture.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: May occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 868-77-9: OZ4725000 LD50/LC50:
CAS# 868-77-9: Oral, mouse: LD50 = 3275 mg/kg; Oral, rat: LD50 = 5050 mg/kg.
Carcinogenicity:
2-Hydroxyethyl Methacrylate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION
 
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
with...
WGK (Water Danger/Protection)
CAS# 868-77-9: 1
Canada
CAS# 868-77-9 is listed on Canada's DSL List.
CAS# 868-77-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 868-77-9 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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