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|Name:||Tetramethylgermanium 97% Material Safety Data Sheet|
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 11 20/21/22
Section 3 - HAZARDS IDENTIFICATION
Highly flammable. Harmful by inhalation, in contact with skin and if swallowed.
Potential Health Effects
May cause eye irritation.
May cause skin irritation. Harmful if absorbed through the skin. May cause dermatitis.
Harmful if swallowed. May cause irritation of the digestive tract.
Harmful if inhaled. May cause respiratory tract irritation.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid. Wash mouth out with water.
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Flammable liquid and vapor.
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
Section 7 - HANDLING and STORAGE
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 865-52-1: Personal Protective Equipment Eyes: Not available.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Odor: Not available.
pH: Not available.
Vapor Pressure: 6.74 psi @ 20 deg C
Viscosity: Not available.
Boiling Point: 43-44 deg C @ 740 mmHg
Freezing/Melting Point: -88 deg C (Dec.)
Autoignition Temperature: Not available.
Flash Point: -37 deg C ( -34.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Solubility in water:
Specific Gravity/Density: 0.978
Molecular Formula: C4H12Ge
Molecular Weight: 132.73
Section 10 - STABILITY AND REACTIVITY
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
CAS# 865-52-1: LY5345000 LD50/LC50:
Tetramethylgermanium - Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
Shipping Name: Flammable liquid, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
Shipping Name: Flammable liquid, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
No information available.
Section 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
R 11 Highly flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
S 33 Take precautionary measures against static
S 36/37 Wear suitable protective clothing and
WGK (Water Danger/Protection)
CAS# 865-52-1: No information available.
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 865-52-1 is not listed on Canada's Ingredient Disclosure List.
CAS# 865-52-1 is not listed on the TSCA inventory.
It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION