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diethyl phthalate 84-66-2 MSDS
Name: Diethyl Phthalate 99% Material Safety Data Sheet
Synonym:
CAS: 84-66-2
Section 1 - Chemical Product   MSDS Name:Diethyl Phthalate 99% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
84-66-2 Diethyl Phthalate 99 201-550-6
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Contact produces irritation, tearing, and burning pain.
Skin:
Causes skin irritation.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
Inhalation:
Causes respiratory tract irritation. May cause narcotic effects in high concentration.
Chronic:
May cause fetal effects.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Appearance: colourless
Odor: Odorless.
pH: Not available.
Vapor Pressure: 14 mm Hg @163C
Viscosity: 12 cPs 20 deg C
Boiling Point: 298 - 299 deg C @ 760.00mm Hg
Freezing/Melting Point: -3 deg C
Autoignition Temperature: Not available.
Flash Point: 160 deg C ( 320.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: IN WATER: 0.15% (25C)
Specific Gravity/Density: 1.1180g/cm3
Molecular Formula: C12H14O4
Molecular Weight: 222.24

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Strong acids such as nitric acid, strong oxidizing agents, and permanganates.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 84-66-2: TI1050000 LD50/LC50:
CAS# 84-66-2: Oral, mouse: LD50 = 6172 mg/kg; Oral, rabbit: LD50 = 1 gm/kg; Oral, rat: LD50 = 8600 mg/kg.
Carcinogenicity:
Diethyl Phthalate - ACGIH: A4 - Not Classifiable as a Human Carcinogen See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 84-66-2: 2
United Kingdom Occupational Exposure Limits
CAS# 84-66-2: OES-United Kingdom, TWA 5 mg/m3 TWA
CAS# 84-66-2: OES-United Kingdom, STEL 10 mg/m3 STEL
Canada
CAS# 84-66-2 is listed on Canada's DSL List.
CAS# 84-66-2 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 84-66-2: OEL-AUSTRALIA:TWA 5 mg/m3
OEL-BELGIUM:TWA 5 mg/m3
OEL-DENMARK:TWA 5 mg/m3
OEL-FINLAND:TWA 5 mg/m3;STEL 10 mg/m3;Skin
OEL-FRANCE:TWA 5 mg/m3
OEL-THE NETHERLANDS:TWA 5 mg/m3
OEL-RUSSIA:STEL 0.5 mg/m3
OEL-SWEDEN:TWA 3 mg/m3;STEL 5 mg/m3
OEL-SWITZERLAND:TWA 5 mg/m3
OEL-UNITED KINGDOM:TWA 5 mg/m3;STEL 10 mg/m3 JAN9
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 84-66-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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