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fluazinam 79622-59-6 MSDS
  Fluazinam
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        Fluazinam    

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified    
  HEALTH HAZARDS
  Acute toxicity (Inhalation)        Category 2    
    Category 2A
  Serious eye damage/eye irritation
  Skin sensitization        Category 1    
    Liver, Digestive tract
  Specific target organ toxicity
  - Repeated exposure [Category 2]
  ENVIRONMENTAL HAZARDS
  Acute aquatic hazard        Category 1    
    Category 1
  Long-term aquatic hazard
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
  Signal word        Danger    
    Fatal if inhaled
  Hazard statements
    Causes serious eye irritation
    May cause an allergic skin reaction
    May cause damage to organs through prolonged or
    repeated exposure : Liver Digestive tract
    Very toxic to aquatic life
    Very toxic to aquatic life with long lasting effects
  Precautionary statements:
    Do not breathe dust/fume/gas/mist/vapours/spray.
  [Prevention]
    Use only outdoors or in a well-ventilated area.
    Avoid release to the environment.
    Contaminated work clothing should not be allowed out of the workplace.
    Wear respiratory protection.
    Wear protective gloves/eye protection/face protection.
  Fluazinam

Section 2. HAZARDS IDENTIFICATION
  [Response]        IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for    
    breathing. Immediately call a POISON CENTER or doctor/physician.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN: Gently wash with plenty of soap and water.
    Wash hands thoroughly after handling.
    If skin irritation or rash occurs: Get medical advice/attention.
    Wash contaminated clothing before reuse.
    Get medical advice/attention if you feel unwell.
    Collect spillage.
  [Storage]        Store in a well-ventilated place. Keep container tightly closed.    
    Store locked up.
  [Disposal]        Dispose of contents/container through a waste management company authorized by    
    the local government.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance    
    Fluazinam
  Components:
  Percent:        >98.0%(LC)(T)    
  CAS Number:        79622-59-6    
  Synonyms:        3-Chloro-N-(3-chloro-2,6-dinitro-4-trifluoromethylphenyl)-5-trifluoromethyl-2-    
    pyridylamine
  Chemical Formula:        C13H4Cl2F6N4O4    

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.    
    Immediately call a POISON CENTER or doctor/physician.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of    
    soap and water. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present    
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Get medical advice/attention if you feel unwell. Rinse mouth.    
    A rescuer should wear personal protective equipment, such as rubber gloves and air-
  Protection of first-aiders:
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.    
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.    
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.    
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use extra personal protective equipment (self-contained breathing apparatus). Keep    
  protective equipment and people away from and upwind of spill/leak. Entry to non-involved personnel should
  emergency procedures: be controlled around the leakage area by roping off, etc.
  Environmental precautions: Be careful not to let it flow into rivers, etc., since adverse effects on the environment
    are concerned.
  Fluazinam

Section 6. ACCIDENTAL RELEASE MEASURES
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.    
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a closed system if possible. Use a local exhaust if dust or aerosol will be
    generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool, dark and well-ventilated place.    
    Store locked up.
    Store away from incompatible materials such as oxidizing agents.
    Comply with laws.
  Packaging material:

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust. Also install safety shower and eye bath.    
  Personal protective equipment
  Respiratory protection: Dust respirator, self-contained breathing apparatus(SCBA), supplied air respirator,
    etc. Use respirators approved under appropriate government standards and follow
    local and national regulations.
    Impervious gloves.
  Hand protection:
  Eye protection:        Safety goggles. A face-shield, if the situation requires.    
  Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid    
  Form:        Crystal- Powder    
    Pale yellow - Deep yellow
  Colour:
  Odour:        No data available    
  pH: No data available
  Melting point/freezing point:118°C
    No data available
  Boiling point/range:
  Flash point:        No data available    
  Flammability or explosive
  limits:
  Lower:        No data available    
  Upper:        No data available    
  Relative density:        No data available    
  Solubility(ies):
    Slightly soluble
  [Water]
  [Other solvents]
  Very soluble:        Ethyl acetate    
  Soluble:        Methanol, Ether, Ethanol, Toluene, Dichloromethane    
  Slightly soluble:        Acetone, Hexane    
  Log Pow:        4.1    

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.    
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents
  Fluazinam

Section 10. STABILITY AND REACTIVITY
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx), Hydrogen fluoride,
  products:        Hydrogen chloride    

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        orl-qal LD50:1782 mg/kg    
    ihl-rat LC50:470 mg/m3
  Skin corrosion/irritation: No data available
  Serious eye        No data available    
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available    
  NTP =        No data available    
  Reproductive toxicity:        No data available    
  RTECS Number:        UR8085000    

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
    96h LC50:0.15 mg/L (Cyprinus carpio)
  Fish:
  Crustacea:        48h EC50:0.22 mg/L (Daphnia magna)    
    No data available
  Algae:
  Persistence / degradability: No data available
  Bioaccumulative        348 - 1850    
  potential(BCF):
  Mobility in soil
  Log Pow:        4.1    
    1705 - 2316
  Soil adsorption (Koc):
  Henry's Law        25.3    
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        6.1: Toxic substance.    
    2811
  UN-No:
  Proper shipping name:        Toxic solid, organic, n.o.s.    
    II
  Packing group:
  Marine pollutant        Y    

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.
  Fluazinam


SECTION 16 - ADDITIONAL INFORMATION
N/A

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