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cadmium dichloride hemipentahydrate 7790-78-5 MSDS
Name: Cadmium chloride hemipentahydrate reagent ACS crystals Material Safety Data Sheet
Synonym: Cadmium dichloride
CAS: 7790-78-5
Section 1 - Chemical Product   MSDS Name:Cadmium chloride hemipentahydrate reagent ACS crystals Material Safety Data Sheet
Synonym:Cadmium dichloride

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
7790-78-5 Cadmium chloride hemipentahydrate 100 unlisted
Hazard Symbols: T+ N
Risk Phrases:

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Toxic if swallowed. Very toxic by inhalation. May cause cancer. May cause heritable genetic damage. Toxic : danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
May impair fertility. May cause harm to the unborn child. Very toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment.Hygroscopic.
Potential Health Effects
Eye:
May cause eye irritation. Exposure to the substance as an aqueous solution may cause irritation and corneal abnormalities.
Skin:
May cause skin irritation. May be absorbed through the skin in harmful amounts.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Exposure may cause severe swelling of face and neck areas with possible death.
Inhalation:
May be fatal if inhaled. Irritation may lead to chemical pneumonitis and pulmonary edema. May cause ulceration and perforation of the nasal septum if inhaled in excessive quantities.
Chronic:
May cause respiratory tract cancer. Prolonged or repeated exposure may cause permanent bone structure abnormalities. Chronic inhalation may cause nasal septum ulceration and perforation. Chronic inhalation of cadmium compounds has been associated with lung and prostate cancer. The primary target organ for chronic cadmium disease is clearly the kidney. An inhalation study of cadmium chloride in rats exposed 23 hrs/day for 18 mo at 12.5, 25 or 50 ug/m3, as Cd, produced a frequency of primary lung carcinomas of 15.4%, 52.6% and 71.4%, respectively. There were no primary lung carcinomas in the controls.

Section 4 - FIRST AID MEASURES
  Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Poison material. If inhaled, get medical aid immediately. Remove victim to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Notes to Physician:
Antidote: The use of Calcium disodium EDTA as a chelating agent should be determined by qualified medical personnel.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Wear a self contained breathing apparatus and appropriate Personal protection. (See Exposure Controls, Personal Protection section). Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not breathe dust. Use only with adequate ventilation.
Storage:
Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use substance with extreme caution and designate regulated areas for use.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear impervious gloves.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystals
Color: white
Odor: odorless
pH: Not available.
Vapor Pressure: 10 mm Hg @ 656 deg C
Viscosity: Not available.
Boiling Point: 960 deg C @ 760 mm Hg
Freezing/Melting Point: 568 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 1400 g/L (20C)
Specific Gravity/Density: 3.33 g/cm3 @ 25C
Molecular Formula: CdCl2.2.5H2O
Molecular Weight: 228.34

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, bromine trifluoride, sulfur, potassium, selenium, tellurium, hydrogen azide.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, cadmium fumes, chloride fumes, toxic cadmium oxide fumes.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 7790-78-5: EV0178000 CAS# 10108-64-2: EV0175000 LD50/LC50:
CAS# 7790-78-5: Oral, mouse: LD50 = 194 mg/kg; Oral, rat: LD50 = 665 mg/kg.
CAS# 10108-64-2: Oral, mouse: LD50 = 60 mg/kg; Oral, mouse: LD50 = 3.3 mg/kg; Oral, rat: LD50 = 88 mg/kg.
Carcinogenicity:
Cadmium chloride hemipentahydrate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Cadmium chloride anhydrous - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Bluegill/Sunfish: 1.94ppm; 96HJapanese quail, oral LC50=2584 ppm/5D Ring-necked pheasant, oral LC50=767 ppm/5D

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: CADMIUM COMPOUND
Hazard Class: 6.1
UN Number: 2570
Packing Group: I
IMO
Shipping Name: CADMIUM COMPOUND
Hazard Class: 6.1
UN Number: 2570
Packing Group: I
RID/ADR
Shipping Name: CADMIUM COMPOUND
Hazard Class: 6.1
UN Number: 2570
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ N
Risk Phrases:
R 25 Toxic if swallowed.
R 26 Very toxic by inhalation.
R 45 May cause cancer.
R 46 May cause heritable genetic damage.
R 48/23/25 Toxic : danger of serious damage to
health by prolonged exposure through inhalation and if
swallowed.
R 60 May impair fertility.
R 61 May cause harm to the unborn child.
R 50/53 Very toxic to aquatic organisms; may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and/or its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/Safety data sheets.
WGK (Water Danger/Protection)
CAS# 7790-78-5: No information available.
CAS# 10108-64-2: No information available.
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7790-78-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 10108-64-2 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7790-78-5: OEL-ARAB Republic of Egypt:TWA 0.05 mg(Cd)/m3
OEL-AUSTRALIA:TWA 0.05 mg(Cd)/m3
OEL-BELGIUM:TWA 0.05 mg(Cd)/m3
OEL-CZECHOSLOVAKIA:TWA 0.05 mg(Cd)/m3;STEL 0.1 mg(Cd)/m3
OEL-DENMARK:TWA 0.01 mg(Cd)/m3
OEL-FINLAND:TWA 0.02 mg(Cd)/m3;Carcinogen
OEL-GERMANY;Carcinogen
OEL-INDIA:TWA 0.05 mg(Cd)/m3
OEL-JAPAN:TWA 0.05 mg(Cd)/m3
OEL-THE NETHERLANDS:TWA 0.02 mg(Cd)/m3;STEL 0.1 mg(Cd)/m3
OEL-THE PHILIPPINES:TWA 0.2 mg(Cd)/m3
OEL-RUSSIA:TWA 0.01 mg(Cd)/m3;STEL 0.05 mg(Cd)/m3
OEL-SWEDEN:TWA 0.02 mg(Cd)/m3;Carcinogen
OEL-SWITZERLAND:TWA 0.05 mg(Cd)/m3
OEL-THAILAND:TWA 0.2 mg(Cd)/m3;STEL 0.5 mg(Cd)/m3
OEL-TURKEY:TWA 0.2 mg(Cd)/m3
OEL-UNITED KINGDOM:TWA 0.01 mg(Cd)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 10108-64-2: OEL-ARAB Republic of Egypt:TWA 0.05 mg(Cd)/m3
OEL-AUSTRALIA:TWA 0.05 mg(Cd)/m3
OEL-BELGIUM:TWA 0.05 mg(Cd)/m3
OEL-CZECHOSLOVAKIA:TWA 0.05 mg(Cd)/m3;STEL 0.1 mg(Cd)/m3
OEL-DENMARK:TWA 0.01 mg(Cd)/m3
OEL-FINLAND:TWA 0.02 mg(Cd)/m3;Carcinogen
OEL-FRANCE;Skin
OEL-GERMANY;Carcinogen
OEL-INDIA:TWA 0.05 mg(Cd)/m3
OEL-JAPAN:TWA 0.05 mg(Cd)/m3
OEL-THE NETHERLANDS:TWA 0.02 mg(Cd)/m3;STEL 0.1 mg(Cd)/m3
OEL-THE PHILIPPINES:TWA 0.2 mg(Cd)/m3
OEL-RUSSIA:TWA 0.01 mg(Cd)/m3;STEL 0.05 mg(Cd)/m3
OEL-SWEDEN:TWA 0.02 mg(Cd)/m3;Carcinogen
OEL-SWITZERLAND:TWA 0.05 mg(Cd)/m3
OEL-SWITZERLAND;Carcinogen
OEL-THAILAND:TWA 0.2 mg(Cd)/m3;STEL 0.5 mg(Cd)/m3
OEL-TURKEY:TWA 0.2 mg(Cd)/m3
OEL-UNITED KINGDOM:TWA 0.01 mg(Cd)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 7790-78-5 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 10108-64-2 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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