Lithium amide
CAS No.: 7782-89-0
Synonyms:
Formula: H2LiN
Exact Mass: 23.03470
Molecular Weight: 22.96360
PSA: 26.02000
LogP: 0.10970
Lithium amide 7782-89-0 MSDS
Name: Lithium amide 95% Material Safety Data Sheet
Synonym: Lithamide; Lithium amide, powered
CAS: 7782-89-0
Section 1 - Chemical Product   MSDS Name:Lithium amide 95% Material Safety Data Sheet
Synonym:Lithamide; Lithium amide, powered

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
7782-89-0 Lithium amide 95.0 231-968-4
Hazard Symbols: F
Risk Phrases: 14/15

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Reacts violently with water liberating extremely flammable gases.Moisture sensitive.Water-reactive.
Potential Health Effects
Eye:
Causes severe eye irritation.
Skin:
Causes severe skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Causes irritation of mucous membrane. Causes severe respiratory tract irritation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Antidote: None reported.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Flammable when exposed to flame. May ignite or explode on contact with steam or moist air.
Extinguishing Media:
Do NOT use water directly on fire. DO NOT USE WATER! Contact professional fire-fighters immediately. For large fires, use dry sand, dry chemical, soda ash or lime or withdraw from area and let fire burn. For small fires, use dry chemical, soda ash, lime or dry sand.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation. Do not expose spill to water. Do not get water on spilled substances or inside containers. DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.
Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting waters.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not allow water to get into the container because of violent reaction. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Do not allow contact with water. Keep from contact with moist air and steam.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use explosion-proof ventilation equipment. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7782-89-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Powder
Color: white
Odor: ammonia-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 430 deg C @ 760.00mmHg
Freezing/Melting Point: 373 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: .13g sol in 100ml water @25 C
Specific Gravity/Density: 1.1780g/cm3
Molecular Formula: H2LiN
Molecular Weight: 22.95

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Reacts with water to form toxic fumes. Combines vigorously or explosively with water. Stable in air-tight containers.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, ammonia and/or derivatives.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 7782-89-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Lithium amide - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: ALKALI METAL AMIDES
Hazard Class: 4.3
UN Number: 1390
Packing Group: II
IMO
Shipping Name: ALKALI METAL AMIDE
Hazard Class: 4.3
UN Number: 1390
Packing Group: II
RID/ADR
Shipping Name: ALKALI METAL AMIDES
Hazard Class: 4.3
UN Number: 1390
Packing group: II

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 14/15 Reacts violently with water liberating
extremely flammable gases.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 43B In case of fire, use fire-fighting equipment
on basis of sodium chloride, sodium bicarbonate (never
use water).
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7782-89-0: No information available.
Canada
CAS# 7782-89-0 is listed on Canada's DSL List.
CAS# 7782-89-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7782-89-0 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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