|Name:||1 1 2-TRICHLOROTRIFLUOROETHANE P.A. Material Safety Data Sheet|
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed.
Section 3 - HAZARDS IDENTIFICATION
Potential Health Effects
The toxicological properties of this material have not been investigated. Use appropriate procedures to prevent opportunities for direct contact with the skin or eyes and to prevent inhalation.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Use agent most appropriate to extinguish fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section.
Section 7 - HANDLING and STORAGE
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Store in a cool, dry place. Keep container closed when not in use.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 76-13-1: United Kingdom, OES - TWA: 1000 ppm TWA; 7790 mg/m3 TWA United Kingdom, OES - STEL: 1250 ppm STEL; 9740 mg/m3 STEL United States OSHA: 1000 ppm TWA; 7600 mg/m3 TWA Belgium - TWA: 1000 ppm VLE; 7781 mg/m3 VLE Belgium - STEL: 1250 ppm VLE; 9729 mg/m3 VLE France - VME: 1000 ppm VME; 7600 mg/m3 VME France - VLE: 1250 ppm VLE; 9500 mg/m3 VLE Germany: 500 ppm TWA; 3900 mg/m3 TWA Japan: 500 ppm OEL; 3800 mg/m3 OEL Malaysia: 1000 ppm TWA; 7670 mg/m3 TWA Netherlands: 150 ppm MAC; 1170 mg/m3 MAC Russia: 5000 mg/m3 TWA Spain: 1000 ppm VLA-ED; 7795 mg/m3 VLA-ED Spain: 1250 ppm VLA-EC; 9745 mg/m3 VLA-EC Personal Protective Equipment Eyes: Not available.
Wear appropriate protective gloves and clothing to prevent skin exposure.
Wear appropriate protective clothing to minimize contact with skin.
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Not available.
Color: Clear colourless liquid
Odor: None reported.
pH: Not available.
Vapor Pressure: 368 hPa @ 20 C
Viscosity: 0.71 MPA 20.00 deg
Boiling Point: 45.0 - 47.0 deg C @ 760.00mm Hg
Freezing/Melting Point: 0 deg C
Autoignition Temperature: 680 deg C ( 1,256.00 deg F)
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Solubility in water: immiscible
Specific Gravity/Density: 1.5700g/cm3
Molecular Formula: C2Cl3F3
Molecular Weight: 187.38
Section 10 - STABILITY AND REACTIVITY
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Aluminum, finely powdered metals, magnesium, zinc, potassium, sodium.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
CAS# 76-13-1: KJ4000000 LD50/LC50:
CAS# 76-13-1: Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 260 gm/m3/2H; Inhalation, mouse: LC50 = 467000 mg/m3/2H; Inhalation, rabbit: LC50 = 59500 ppm/2H; Inhalation, rabbit: LC50 = 59.5 ppm/2H; Inhalation, rat: LC50 = 38500 ppm/4H; Inhalation, rat: LC50 = 53.3 ppm/4H; Inhalation, rat: LC50 = 38.5 ppm/4H; Inhalation, rat: LC50 = 52.5 ppm/4H; Oral, rat: LD50 = 43 gm/kg; Oral, rat: LD50 = 43 gm/kg.
1,1,2-TRICHLOROTRIFLUOROETHANE, P.A. - Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
Not regulated as a hazardous material.
Not regulated as a hazardous material.
Shipping Name: Not regulated.
Section 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 76-13-1: 2
CAS# 76-13-1 is listed on Canada's DSL List.
CAS# 76-13-1 is listed on Canada's Ingredient Disclosure List.
CAS# 76-13-1 is listed on the TSCA inventory.
SECTION 16 - ADDITIONAL INFORMATION