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2-Bromopropane 75-26-3 MSDS
Name: 2-Bromopropane 99% Material Safety Data Sheet
Synonym: Isopropyl bromide
CAS: 75-26-3
Section 1 - Chemical Product   MSDS Name:2-Bromopropane 99% Material Safety Data Sheet
Synonym:Isopropyl bromide

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
75-26-3 2-Bromopropane 99 200-855-1
Hazard Symbols: T F
Risk Phrases: 11 48/20 60 66

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Highly flammable. Harmful : danger of serious damage to health by prolonged exposure through inhalation. May impair fertility.
Repeated exposure may cause skin dryness or cracking.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Repeated or prolonged exposure may cause drying and cracking of the skin.
Ingestion:
May cause central nervous system depression, kidney damage, and liver damage. Symptoms may include: headache, excitement, fatigue, nausea, vomiting, stupor, and coma. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion. Adverse reproductive effects have been reported in humans.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Flammable liquid and vapor.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation. Approach spill from upwind.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Do not breathe vapor. Use only with adequate ventilation.
Keep away from heat, sparks and flame.
Storage:
Keep away from heat, sparks, and flame. Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use explosion-proof ventilation equipment. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 75-26-3: Japan: 1 ppm OEL; 5 mg/m3 OEL Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 224 mbar @ 20 C
Viscosity: Not available.
Boiling Point: 59 deg C @ 760 mm Hg
Freezing/Melting Point: -89 deg C
Autoignition Temperature: Not available.
Flash Point: 1 deg C ( 33.80 deg F)
Explosion Limits, lower: 4.60 vol %
Explosion Limits, upper: .00 vol %
Decomposition Temperature:
Solubility in water: 0.3g/100ml
Specific Gravity/Density: 1.3100g/cm3
Molecular Formula: C3H7Br
Molecular Weight: 122.99

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 75-26-3: TX4111000 LD50/LC50:
CAS# 75-26-3: Inhalation, mouse: LC50 = 31171 ppm/4H; Inhalation, mouse: LC50 = 36000 mg/m3.
Carcinogenicity:
2-Bromopropane - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: BROMOPROPANES
Hazard Class: 3
UN Number: 2344
Packing Group: II
IMO
Shipping Name: BROMOPROPANES
Hazard Class: 3.2
UN Number: 2344
Packing Group: II
RID/ADR
Shipping Name: BROMOPROPANES
Hazard Class: 3
UN Number: 2344
Packing group: II

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 48/20 Harmful : danger of serious damage to health
by prolonged exposure through inhalation.
R 60 May impair fertility.
R 66 Repeated exposure may cause skin dryness or
cracking.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 16 Keep away from sources of ignition - No
smoking.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 75-26-3: No information available.
Canada
CAS# 75-26-3 is listed on Canada's DSL List.
CAS# 75-26-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-26-3 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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