|Name:||2-Picolyl chloride hydrochloride, 98% Material Safety Data Sheet|
|Synonym:||2-(Chloromethyl)pyridine hydrochloride; 2-Pyridiylmethylchloride hydrochloride; Pyridine, 2-chloromethyl-, hydrochloride|
Synonym: 2-(Chloromethyl)pyridine hydrochloride; 2-Pyridiylmethylchloride hydrochloride; Pyridine, 2-chloromethyl-, hydrochloride
SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
|6959-47-3||2-Picolyl chloride hydrochloride||98||230-149-9|
Risk Phrases: 22
SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful if swallowed.Hygroscopic (absorbs moisture from the air).Toxic. Potential Health Effects
Causes eye irritation. May cause conjunctivitis and corneal inflammation.
Causes skin irritation. Substance is readily absorbed through the skin.
Harmful if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Causes irritation of the mucous membrane and upper respiratory tract.
No information found.
SECTION 4 - FIRST AID MEASURES
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
SECTION 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Clean up spills immediately, observing precautions in the Protective Equipment section. Cover with sand, dry lime or soda ash and place in a closed container for disposal. Provide ventilation.
SECTION 7 - HANDLING and STORAGE
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Use only in a chemical fume hood.
Store in a cool, dry place. Keep container closed when not in use. Keep containers tightly closed.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 6959-47-3: Personal Protective Equipment
Wear safety glasses and chemical goggles if splashing is possible.
Wear appropriate protective gloves and clothing to prevent skin exposure. Rubber and plastic gloves should not be relied upon to prevent skin contact.
Wear appropriate protective clothing to minimize contact with skin. Rubber and plastic gloves should not be relied upon to prevent skin contact.
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Crystalline powder
Color: beige to light brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 128.00 - 129.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: C6H6ClN.HCl
Molecular Weight: 164.04
SECTION 10 - STABILITY AND REACTIVITY
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, chloride fumes.
Hazardous Polymerization: Has not been reported.
SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 6959-47-3: US6825000
CAS# 6959-47-3: Oral, mouse: LD50 = 316 mg/kg; Oral, rat: LD50 = 316 mg/kg.
2-Picolyl chloride hydrochloride - Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
SECTION 12 - ECOLOGICAL INFORMATION Other No information available.
SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations.
SECTION 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material.
SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: XN
R 22 Harmful if swallowed.
S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 6959-47-3: No information available. Canada CAS# 6959-47-3 is listed on Canada's DSL List. CAS# 6959-47-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 6959-47-3 is not listed on the TSCA inventory. It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.
SECTION 16 - ADDITIONAL INFORMATION