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|Name:||Bis(pentamethylcyclopentadienyl)manganese Material Safety Data Sheet|
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed.
Section 3 - HAZARDS IDENTIFICATION
Air sensitive.Moisture sensitive.
Potential Health Effects
May cause eye irritation.
May cause skin irritation. May be harmful if absorbed through the skin.
May cause irritation of the digestive tract. May be harmful if swallowed.
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic manganese toxicity through inhalation may result in "manganism", which is a disease of the central nervous system involving psychic and neurological disorders.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid. Wash mouth out with water.
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Vacuum or sweep up material and place into a suitable disposal container.
Section 7 - HANDLING and STORAGE
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Handle under argon.
Store in a cool, dry place. Store in a tightly closed container.
Store under argon.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 67506-86-9: United States OSHA: 5 mg/m3 Ceiling (as Mn) (listed under Mangan compounds, n.o.s.).
Belgium - TWA: (listed as manganese compounds, n.o.s.): 0.2 mg/m3 (as Mn) Japan: (listed as manganese compounds, n.o.s.): 0.3 mg/m3 OEL (ex organic compounds, as Mn) Netherlands: (listed as manganese compounds, n.o.s.): 3 mg/m3 STE (as Mn) Netherlands: (listed as manganese compounds, n.o.s.): 1 mg/m3 MAC Mn) Personal Protective Equipment Eyes: Not available.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Crystals
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 230 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Solubility in water:
Molecular Formula: C20H30Mn
Molecular Weight: 325.39
Section 10 - STABILITY AND REACTIVITY
Conditions to Avoid:
Incompatible materials, moisture, exposure to air.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
CAS# 67506-86-9 unlisted.
Bis(pentamethylcyclopentadienyl)manganese - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
Not regulated as a hazardous material.
Not regulated as a hazardous material.
No information available.
Section 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 67506-86-9: No information available.
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 67506-86-9 is not listed on Canada's Ingredient Disclosure List.
CAS# 67506-86-9 is not listed on the TSCA inventory.
It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION