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|Name:||Ammonia Monitor Reagent Material Safety Data Sheet|
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
|637-39-8||Ethanol, 2,2',2''-nitrilotris-, hydroc||1.59||211-284-2|
Risk Phrases: None Listed.
Section 3 - HAZARDS IDENTIFICATION
Potential Health Effects
May cause severe eye irritation. May result in corneal injury.
May cause painful sensitization to light. May cause conjunctivitis.
May cause skin irritation. May cause photosensitive skin reactions in certain individuals.
May cause irritation of the digestive tract.
May cause respiratory tract irritation.
Prolonged or repeated skin contact may cause dermatitis.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Not flammable, but reacts with most metals to form flammable hydrogen gas. Use water spray to keep fire-exposed containers cool.
Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Large spills may be neutralized with dilute alkaline solutions of soda ash (sodium carbonate, Na2CO3), or lime (calcium oxide, CaO).
Clean up spills immediately, observing precautions in the Protective Equipment section. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Do not use combustible materials such as sawdust.
Section 7 - HANDLING and STORAGE
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Keep away from heat and flame. Do not store in direct sunlight.
Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 637-39-8: CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Odor: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Miscible with water.
Specific Gravity/Density: 1.01 (Water=1)
Molecular Formula: Mixture
Section 10 - STABILITY AND REACTIVITY
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light.
Incompatibilities with Other Materials:
Acetate, acetic anhydride, alcohols + hydrogen cyanide, 2-aminoethanol, ammonium hydroxide, calcium carbide, calcium phosphide, cesium acetylene carbide, cesium carbide, chlorosulfonic acid, 1,1-difluoroethylene, ethylene diamine, ethyleneimine, fluorine, lithium silicide, magnesium boride, mercuric sulfate, oleum, perchloric acid, potassium permanganate, b-propiolactone, propylene oxide, rubidum acetylene carbide, rubidum carbide, silver perchlorate + carbon tetrachloride, sodium, sodium hydroxide, sulfuric acid, uranium phosphide, vinyl acetate. Substance polymerizes on contact with aldehydes or epoxides.
Hazardous Decomposition Products:
Hydrogen chloride, hydrogen gas.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
CAS# 637-39-8: KL9346500 CAS# 7732-18-5: ZC0110000 LD50/LC50:
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Ethanol, 2,2',2''-nitrilotris-, hydrochloride - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Trout LC100=10 mg/L/24H Shrimp LC50=100-330 ppm Starfish LC50=100-330mg/L/48H Shore crab LC50=240 mg/L/48H Chronic plant toxicity=100 ppm
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
No information available.
No information available.
No information available.
Section 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
WGK (Water Danger/Protection)
CAS# 637-39-8: 1
CAS# 7732-18-5: No information available.
CAS# 637-39-8 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 637-39-8 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 637-39-8 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
SECTION 16 - ADDITIONAL INFORMATION