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2-methylthio-1,3-benzothiazole 615-22-5 MSDS
Name: 2-(Methylthio)benzothiazole 98% (gc) Material Safety Data Sheet
Synonym: Benzothiazole; USAF EK-4008; Mercapto-2-methyl; 2-methyl mercapto Benzothiozole; Benzothiazole-6-amino-2-mercapt
CAS: 615-22-5
Section 1 - Chemical Product   MSDS Name:2-(Methylthio)benzothiazole 98% (gc) Material Safety Data Sheet
Synonym:Benzothiazole; USAF EK-4008; Mercapto-2-methyl; 2-methyl mercapto Benzothiozole; Benzothiazole-6-amino-2-mercapt

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
615-22-5 Benzothiazole, 2-(methylthio)- 210-417-1
Hazard Symbols: None Listed.
Risk Phrases: 15/29

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Contact with water liberates toxic, extremely flammable gas.Water-reactive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause digestive tract disturbances.
Inhalation:
May cause irritation of the mucous membranes.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Contact with moisture or water may generate sufficient heat to ignite nearby combustible materials. Contact with acid or acid fumes evolves heat and flammable vapors. May re-ignite after fire is extinguished. May be ignited by heat, sparks, and flame.
Extinguishing Media:
DO NOT USE WATER OR FOAM. For small fires, use dry chemical, soda ash, lime or sand. For large fires, use dry sand, dry chemical, soda ash or lime or withdraw from area and let fire burn. Contact with water or steam may produce toxic and flammable vapors.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Do not get water on spilled substances or inside containers. Cover with dry earth, dry sand, or other non-combustible material followed with plastic sheet to minimize spreading and contact with water. DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not allow water to get into the container because of violent reaction. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Use with adequate ventilation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Water free area. Keep away from acids.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 615-22-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: yellow
Odor: unpleasant odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 47.00 - 49.00 deg C
Autoignition Temperature: Not available.
Flash Point: > 230 deg F (> 110.00 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H7NS2
Molecular Weight: 181.28

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures. Reacts with water to form toxic fumes.
Conditions to Avoid:
Incompatible materials, contact with water, acids, excess heat.
Incompatibilities with Other Materials:
Acids, water, strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, toxic fumes of sodium oxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 615-22-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Benzothiazole, 2-(methylthio)- - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
R 15/29 Contact with water liberates toxic,
extremely flammable gas.
Safety Phrases:
S 14C Keep away from water, acids and alkali.
S 24/25 Avoid contact with skin and eyes.
S 30 Never add water to this product.
WGK (Water Danger/Protection)
CAS# 615-22-5: No information available.
Canada
CAS# 615-22-5 is listed on Canada's NDSL List.
CAS# 615-22-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 615-22-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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