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2,6-dichloroaniline 608-31-1 MSDS
Name: 2,6-Dichloroaniline, 98% Material Safety Data Sheet
Synonym: 1-Amino-2,6-dichlorobenzene; 2,6-Dichlorobenzeneamine; 2,6-Dichloroaniline.
CAS: 608-31-1
Section 1 - Chemical Product MSDS Name: 2,6-Dichloroaniline, 98% Material Safety Data Sheet
Synonym: 1-Amino-2,6-dichlorobenzene; 2,6-Dichlorobenzeneamine; 2,6-Dichloroaniline.
SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
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SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Potential Health Effects
Eye:
Causes eye irritation. Causes redness and pain.
Skin:
Causes skin irritation. May be absorbed through the skin. Absorption into the body may cause cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood). Causes redness and pain. Toxic in contact with skin.
Ingestion:
May cause irritation of the digestive tract. Poison by ingestion. May cause nausea and vomiting.
Inhalation:
Causes respiratory tract irritation. Toxic if inhaled. May cause nausea, dizziness, and headache.
Chronic:
May cause liver and kidney damage. Absorption into the body leads to the formation of methemoglobin which in sufficient concentrations causes cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood).
SECTION 4 - FIRST AID MEASURES
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
SECTION 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products.
Extinguishing Media:
Water or foam may cause frothing. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation.
SECTION 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid breathing dust.
Storage:
Store in a cool place in the original container and protect from sunlight. Store in a tightly closed container. Store in a dry area. Do not exceed 30C (86F). Isolate from oxidizing materials and acids.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 608-31-1: CAS# 27134-27-6: Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: white - brown
Odor: aromatic odor
pH: Not available.
Vapor Pressure: 0.02 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 228 deg C
Freezing/Melting Point: 36 -38 deg C
Autoignition Temperature: > 600 deg C (> 1,112.00 deg F)
Flash Point: 118 deg C ( 244.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 390 deg C
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C6H5Cl2N
Molecular Weight: 162.02
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Light, dust generation, exposure to air.
Incompatibilities with Other Materials:
Oxidizing agents, acids, acid chlorides, acid anhydrides.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, aniline.
Hazardous Polymerization: Has not been reported.
SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 608-31-1: CX9862655 CAS# 27134-27-6 unlisted.
LD50/LC50:
CAS# 608-31-1: Oral, rat: LD50 = 3167 mg/kg. CAS# 27134-27-6.
Carcinogenicity:
2,6-Dichloroaniline - Not listed by ACGIH, IARC, or NTP. Dichloroanilines - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
SECTION 12 - ECOLOGICAL INFORMATION
SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations.
SECTION 14 - TRANSPORT INFORMATION IATA
Shipping Name: DICHLOROANILINES, SOLID
Hazard Class: 6.1
UN Number: 1590
Packing Group: II IMO
Shipping Name: DICHLOROANILINES, SOLID
Hazard Class: 6.1
UN Number: 1590
Packing Group: II RID/ADR
Shipping Name: DICHLOROANILINES
Hazard Class: 6.1
UN Number: 1590
Packing group: II
SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R 33 Danger of cumulative effects. R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Phrases:
S 28A After contact with skin, wash immediately with plenty of water. S 36/37 Wear suitable protective clothing and gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 60 This material and its container must be disposed of as hazardous waste. S 61 Avoid release to the environment. Refer to special instructions/safety data sheets. WGK (Water Danger/Protection) CAS# 608-31-1: 3 CAS# 27134-27-6: No information available. Canada CAS# 608-31-1 is listed on Canada's NDSL List. CAS# 608-31-1 is not listed on Canada's Ingredient Disclosure List. CAS# 27134-27-6 is listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 608-31-1 is listed on the TSCA inventory. CAS# 27134-27-6 is not listed on the TSCA inventory. It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION Text for R-phrases from Section 2
MSDS Creation Date: 1/28/2000 Revision #2 Date: 5/13/2002 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.

SECTION 16 - ADDITIONAL INFORMATION
N/A

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