bis(3-aminopropyl)amine
CAS No.: 56-18-8
Synonyms:
Formula: C6H17N3
Exact Mass: 131.14200
Molecular Weight: 131.21900
PSA: 64.07000
LogP: 1.06510
bis(3-aminopropyl)amine 56-18-8 MSDS
Name: 3 3 -Diaminodipropylamine 99% (GC) Material Safety Data Sheet
Synonym: 3,3'-Diaminodipropylamine; Bis-(3-aminopropyl)amine; Dipropylenetriamine; Norspermidin
CAS: 56-18-8
Section 1 - Chemical Product   MSDS Name:3 3 -Diaminodipropylamine 99% (GC) Material Safety Data Sheet
Synonym:3,3'-Diaminodipropylamine; Bis-(3-aminopropyl)amine; Dipropylenetriamine; Norspermidin

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
56-18-8 3,3'-Iminobispropylamine 99 200-261-2
Hazard Symbols: T+ C
Risk Phrases: 22 24 26 35 43

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful if swallowed. Toxic in contact with skin. Very toxic by inhalation. Causes severe burns. May cause sensitization by skin contact.Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
May be fatal if absorbed through the skin. May cause severe irritation and possible burns.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. May be harmful if swallowed.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire. Do NOT get water inside containers. Contact with water or steam may produce toxic and flammable vapors.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Do not get water inside containers.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Keep containers tightly closed.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 56-18-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colourless
Odor: none reported
pH: Not available.
Vapor Pressure: 0.05 mbar @ 20
Viscosity: Not available.
Boiling Point: 235 deg C @ 760.00mm Hg
Freezing/Melting Point: -14 deg C
Autoignition Temperature: 280 deg C ( 536.00 deg F)
Flash Point: 118 deg C ( 244.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Not available.
Specific Gravity/Density: .9380g/cm3
Molecular Formula: C6H17N3
Molecular Weight: 131.22

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, strong acids, acid chlorides, acid anhydrides, chloroformates.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 56-18-8: JL9450000 LD50/LC50:
CAS# 56-18-8: Draize test, rabbit, eye: 47 mg Severe; Inhalation, rat: LC50 = 30 mg/m3/4H; Oral, mouse: LD50 = 435 mg/kg; Oral, rabbit: LD50 = 210 mg/kg; Oral, rat: LD50 = 738 mg/kg; Skin, rabbit: LD50 = 110 uL/kg.
Carcinogenicity:
3,3'-Iminobispropylamine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: 3,3'-IMINODIPROPYLAMINE
Hazard Class: 8
UN Number: 2269
Packing Group: III
IMO
Shipping Name: 3,3'-IMINODIPROPYLAMINE
Hazard Class: 8
UN Number: 2269
Packing Group: III
RID/ADR
Shipping Name: 3,3'-IMINODIPROPYLAMINE
Hazard Class: 8
UN Number: 2269
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ C
Risk Phrases:
R 22 Harmful if swallowed.
R 24 Toxic in contact with skin.
R 26 Very toxic by inhalation.
R 35 Causes severe burns.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 56-18-8: 2
Canada
CAS# 56-18-8 is listed on Canada's DSL List.
CAS# 56-18-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 56-18-8 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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