|Name:||1 3-Dichloropropene mixture of isomers tech. 90% Material Safety Data Sheet|
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 10 20/21 25 36/37/38 43 50/53
Section 3 - HAZARDS IDENTIFICATION
Flammable. Harmful by inhalation and in contact with skin. Toxic if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Dangerous for the environment.
Potential Health Effects
Causes eye irritation.
Causes skin irritation. Harmful if absorbed through the skin.
Toxic if swallowed.
Harmful if inhaled. Causes respiratory tract irritation. Aspiration may lead to pulmonary edema.
May cause liver and kidney damage. Repeated exposure may cause sensitization dermatitis. Effects may be delayed.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas.
Use water spray to cool fire-exposed containers. Use foam, dry chemical, or carbon dioxide.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Section 7 - HANDLING and STORAGE
Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 542-75-6: Belgium - TWA: 1 ppm VLE; 4.6 mg/m3 VLE Germany: 0.11 ppm TWA; 0.5 mg/m3 TWA Germany: Skin absorber Malaysia: 1 ppm TWA; 4.5 mg/m3 TWA Netherlands: 1 ppm MAC; 5 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 1 ppm VLA-ED; 4.6 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: colorless to yellow
Odor: characteristic odor
pH: Not available.
Vapor Pressure: 40 mbar @20 deg C
Viscosity: Not available.
Boiling Point: 108 deg C @760mmHg
Freezing/Melting Point: -60 deg C
Autoignition Temperature: Not available.
Flash Point: 27 deg C ( 80.60 deg F)
Explosion Limits, lower: 5.3 Vol %
Explosion Limits, upper: 14.5 Vol %
Solubility in water:
Specific Gravity/Density: 1.200
Molecular Formula: C3H4Cl2
Molecular Weight: 110.97
Section 10 - STABILITY AND REACTIVITY
Not currently available.
Conditions to Avoid:
Incompatibilities with Other Materials:
Oxidizing agents, rubber, plastics.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
CAS# 542-75-6: UC8310000 LD50/LC50:
CAS# 542-75-6: Inhalation, mouse: LC50 = 3220 mg/m3/2H; Oral, mouse: LD50 = 640 mg/kg; Oral, rat: LD50 = 470 mg/kg; Skin, rabbit: LD50 = 333 mg/kg; Skin, rat: LD50 = 775 mg/kg.
1,3-dichloropropene - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 1/1/89 NTP: Suspect carcinogen IARC: Group 2B carcinogen Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Fish: Fathead Minnow: LC50 = 4.1 mg/L; 96 Hr.; Static Conditions; 18 degrees CFish: Rainbow trout: LC50 = 5.9 mg/L; 96 Hr.; Static Conditions; 11-13 degrees CFish: Bluegill/Sunfish: LC50 = 6.1 mg/L; 96 Hr.; Static Conditions; 21-23 degrees CWater flea Daphnia: EC50 = 6.15 mg/L; 48 Hr.; Static Conditions; 21-23 degrees CBacteria: Phytobacterium phosphoreum: EC50 = 5.1 mg/L; 30 minutes; Microtox testAlgae: EC50 = 4.95 mg/L; 96 Hr.; None
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
No information available.
No information available.
No information available.
USA RQ: CAS# 542-75-6: 100 lb final RQ; 45.4 kg final RQ
Section 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
R 10 Flammable.
R 20/21 Harmful by inhalation and in contact with
R 25 Toxic if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
S 36/37 Wear suitable protective clothing and
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 542-75-6: 3
CAS# 542-75-6 is listed on Canada's NDSL List.
CAS# 542-75-6 is listed on Canada's Ingredient Disclosure List.
CAS# 542-75-6 is listed on the TSCA inventory.
SECTION 16 - ADDITIONAL INFORMATION