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chlorobenzilate 510-15-6 MSDS
    Version 1.3
    Regulation (EC) No 1907/2006

    1 - Product and Company Information

    Product Name        CHLOROBENZILATE, 1X1ML, CH2CL2, 200UG/ML    

    2 - Hazards Identification

    SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
    May cause cancer. Possible risk of harm to the unborn child. May
    cause sensitization by skin contact. Irritating to eyes,
    respiratory system and skin. Toxic by inhalation, in contact with
    skin and if swallowed.

    3 - Composition/Information on Ingredients

    Product Name        CAS #        EC no        Annex I    
    Index Number
    CHLOROBENZILATE SOLUTION        None        None        None    
    Ingredient Name        Percent CAS #        EC no        Annex I    
    Index Number
    METHANE, DICHLORO-        >= 99.98 75-09-2        200-838-9        602-004-00-3    
    <= 100
    Carc. Cat.3
    Symbols: Xn
    R-Phrases: 40
    Limited evidence of a carcinogenic effect.
    CHLOROBENZENE-D(5), * <= 0.02 3114-55-4 221-482-0 602-033-00-1
    (ATOM % D)
    Symbols: Xn-N
    R-Phrases: 10-20-51/53
    Flammable. Harmful by inhalation. Toxic to aquatic organisms, may
    cause long-term adverse effects in the aquatic environment.

    4 - First Aid Measures

    AFTER INHALATION
    If inhaled, remove to fresh air. If not breathing give
    artificial respiration. If breathing is difficult, give oxygen.
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    AFTER SKIN CONTACT
    In case of skin contact, flush with copious amounts of water for
    at least 15 minutes. Remove contaminated clothing and shoes.
    Call a physician.
    AFTER EYE CONTACT
    In case of contact with eyes, flush with copious amounts of
    water for at least 15 minutes. Assure adequate flushing by
    separating the eyelids with fingers. Call a physician.
    AFTER INGESTION
    If swallowed, wash out mouth with water provided person is
    conscious. Call a physician immediately.

    5 - Fire Fighting Measures

    EXTINGUISHING MEDIA
    Suitable: For small (incipient) fires, use media such as
    "alcohol" foam, dry chemical, or carbon dioxide. For large
    fires, apply water from as far as possible. Use very large
    quantities (flooding) of water applied as a mist or spray; solid
    streams of water may be ineffective. Cool all affected
    containers with flooding quantities of water.
    SPECIAL RISKS
    Specific Hazard(s): Emits toxic fumes under fire conditions.
    SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
    Wear self-contained breathing apparatus and protective clothing
    to prevent contact with skin and eyes.

    6 - Accidental Release Measures

    PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
    Evacuate area.
    PROCEDURE(S) OF PERSONAL PRECAUTION(S)
    Wear self-contained breathing apparatus, rubber boots, and heavy
    rubber gloves. Wear disposable coveralls and discard them after
    use.
    METHODS FOR CLEANING UP
    Absorb on sand or vermiculite and place in closed containers for
    disposal. Ventilate area and wash spill site after material
    pickup is complete.

    7 - Handling and Storage

    HANDLING
    Directions for Safe Handling: Do not breathe vapor. Do not get
    in eyes, on skin, on clothing. Avoid prolonged or repeated
    exposure. For protection and handling requirements consult CFR
    title 29 part 1910.1052.
    STORAGE
    Conditions of Storage: Keep tightly closed. Store in a cool dry
    place. Store under nitrogen.
    SPECIAL REQUIREMENTS: Heat sensitive.

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    8 - Exposure Controls / Personal Protection

    ENGINEERING CONTROLS
    Use only in a chemical fume hood. Safety shower and eye bath.
    GENERAL HYGIENE MEASURES
    Wash contaminated clothing before reuse. Wash thoroughly after
    handling.
    PERSONAL PROTECTIVE EQUIPMENT
    Respiratory Protection: Use respirators and components tested and
    approved under appropriate government standards such as NIOSH (US)
    or CEN (EU). Use supplied-air or SCBA respirators. Europe permits
    the use of type AXBEK full-face cartridge respirators (EN 14387).
    Hand Protection: Compatible chemical-resistant gloves.
    Eye Protection: Chemical safety goggles.

    9 - Physical and Chemical Properties

    Appearance        Physical State: Liquid    
    Property        Value        At Temperature or Pressure    
    pH N/A
    BP/BP Range        N/A    
    MP/MP Range        N/A    
    Flash Point        N/A    
    Flammability        N/A    
    Autoignition Temp        N/A    
    Oxidizing Properties N/A
    Explosive Properties N/A
    Explosion Limits        N/A    
    Vapor Pressure        N/A    
    Partition Coefficient N/A
    Viscosity        N/A    
    Vapor Density        N/A    
    Saturated Vapor Conc. N/A
    Evaporation Rate        N/A    
    Bulk Density        N/A    
    Decomposition Temp.        N/A    
    Solvent Content        N/A    
    Water Content        N/A    
    Surface Tension        N/A    
    Conductivity        N/A    
    Miscellaneous Data        N/A    
    Solubility        N/A    

    10 - Stability and Reactivity

    STABILITY
    Stable: Stable.
    Conditions to Avoid: Heat.
    Materials to Avoid: Alkali metals, Aluminum.
    HAZARDOUS DECOMPOSITION PRODUCTS
    Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
    Hydrogen chloride gas, Phosgene gas.
    HAZARDOUS POLYMERIZATION
    Hazardous Polymerization: Will not occur
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    11 - Toxicological Information

    SIGNS AND SYMPTOMS OF EXPOSURE
    Pulmonary edema. Effects may be delayed. Conjunctivitis.
    Convulsions. Somnolence. Irregular breathing. Ingestion can
    cause gastrointestinal disorders, nausea, and vomiting.
    Weakness. Drowsiness. Increased liver enzymes. Paresthesia.
    Dichloromethane is metabolized in the body producing carbon
    monoxide which increases and sustains carboxyhemoglobin levels
    in the blood, reducing the oxygen-carrying capacity of the
    blood. A simple asphyxiant, exposure can cause anesthetic
    action, difficulty in breathing, headache, and dizziness.
    Prolonged or repeated contact with skin can cause defatting and
    dermatitis. Contact with eyes can cause redness, tearing, and
    blurred vision. Ingestion may cause gastrointestinal irritation.
    CNS depression.
    ROUTE OF EXPOSURE
    Skin Contact: Causes skin irritation.
    Skin Absorption: May be harmful if absorbed through the skin.
    Eye Contact: Causes eye irritation.
    Inhalation: Material is irritating to mucous membranes and upper
    respiratory tract. May be harmful if inhaled.
    Ingestion: Harmful if swallowed.
    TARGET ORGAN INFORMATION
    Target organ: central nervous system because of possible
    dizziness, headache, loss of consciousness and death at high
    concentrations. Liver. Pancreas. Blood. Target organ: heart
    because methylene chloride is converted to carbon monoxide in
    the body.
    CONDITIONS AGGRAVATED BY EXPOSURE
    Existing data suggests that methylene chloride may be a weak
    mutagen in mammalian systems.
    CHRONIC EXPOSURE - CARCINOGEN
    Result: This is or contains a component that has been reported
    to be carcinogenic based on its IARC, OSHA, ACGIH, NTP, or EPA
    classification.
    CHRONIC EXPOSURE - TERATOGEN
    Result: Possible risk of congenital malformation in the fetus.

    12 - Ecological Information

    No data available.

    13 - Disposal Considerations

    SUBSTANCE DISPOSAL
    Contact a licensed professional waste disposal service to dispose
    of this material. Observe all federal, state, and local
    environmental regulations.

    14 - Transport Information

    RID/ADR
    UN#: 1593
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    Class: 6.1
    PG: III
    Proper Shipping Name: Dichloromethane
    IMDG
    UN#: 1593
    Class: 6.1
    PG: III
    Proper Shipping Name: Dichloromethane
    Marine Pollutant: No
    Severe Marine Pollutant: No
    IATA
    UN#: 1593
    Class: 6.1
    PG: III
    Proper Shipping Name: Dichloromethane
    Inhalation Packing Group I: No

    15 - Regulatory Information

    CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
    INDICATION OF DANGER: T
    Toxic.
    R-PHRASES: 45-63-43-36/37/38-23/24/25
    May cause cancer. Possible risk of harm to the unborn child.
    May cause sensitization by skin contact. Irritating to eyes,
    respiratory system and skin. Toxic by inhalation, in contact
    with skin and if swallowed.
    S-PHRASES: 23-36/37-24/25
    Do not breathe vapor. Wear suitable protective clothing and
    gloves. Avoid contact with skin and eyes.
    Caution: Substance not yet fully tested (EU).
    COUNTRY SPECIFIC INFORMATION
    Germany
    WGK: 2
    Self-Classification

    16 - Other Information

    WARRANTY
    The above information is believed to be correct but does not
    purport to be all inclusive and shall be used only as a guide. The
    information in this document is based on the present state of our
    knowledge and is applicable to the product with regard to
    appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Inc.,
    shall not be held liable for any damage resulting from handling or
    from contact with the above product. See reverse side of invoice
    or packing slip for additional terms and conditions of sale.
    Copyright 2010 Co. License granted to make
    unlimitedpaper copies for internal use only.
    DISCLAIMER
    For R&D use only. Not for drug, household or other uses.
    SUPELCO        www.molbase.com    


SECTION 16 - ADDITIONAL INFORMATION
N/A

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