Regulation (EC) No 1907/2006
1 - Product and Company Information
Product Name CHLOROBENZILATE, 1X1ML, CH2CL2, 200UG/ML
2 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
May cause cancer. Possible risk of harm to the unborn child. May
cause sensitization by skin contact. Irritating to eyes,
respiratory system and skin. Toxic by inhalation, in contact with
skin and if swallowed.
3 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
CHLOROBENZILATE SOLUTION None None None
Ingredient Name Percent CAS # EC no Annex I
METHANE, DICHLORO- >= 99.98 75-09-2 200-838-9 602-004-00-3
Limited evidence of a carcinogenic effect.
CHLOROBENZENE-D(5), * <= 0.02 3114-55-4 221-482-0 602-033-00-1
(ATOM % D)
Flammable. Harmful by inhalation. Toxic to aquatic organisms, may
cause long-term adverse effects in the aquatic environment.
4 - First Aid Measures
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
If swallowed, wash out mouth with water provided person is
conscious. Call a physician immediately.
5 - Fire Fighting Measures
Suitable: For small (incipient) fires, use media such as
"alcohol" foam, dry chemical, or carbon dioxide. For large
fires, apply water from as far as possible. Use very large
quantities (flooding) of water applied as a mist or spray; solid
streams of water may be ineffective. Cool all affected
containers with flooding quantities of water.
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves. Wear disposable coveralls and discard them after
METHODS FOR CLEANING UP
Absorb on sand or vermiculite and place in closed containers for
disposal. Ventilate area and wash spill site after material
pickup is complete.
7 - Handling and Storage
Directions for Safe Handling: Do not breathe vapor. Do not get
in eyes, on skin, on clothing. Avoid prolonged or repeated
exposure. For protection and handling requirements consult CFR
title 29 part 1910.1052.
Conditions of Storage: Keep tightly closed. Store in a cool dry
place. Store under nitrogen.
SPECIAL REQUIREMENTS: Heat sensitive.
8 - Exposure Controls / Personal Protection
Use only in a chemical fume hood. Safety shower and eye bath.
GENERAL HYGIENE MEASURES
Wash contaminated clothing before reuse. Wash thoroughly after
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US)
or CEN (EU). Use supplied-air or SCBA respirators. Europe permits
the use of type AXBEK full-face cartridge respirators (EN 14387).
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Physical State: Liquid
Property Value At Temperature or Pressure
BP/BP Range N/A
MP/MP Range N/A
Flash Point N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
Partition Coefficient N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Miscellaneous Data N/A
10 - Stability and Reactivity
Conditions to Avoid: Heat.
Materials to Avoid: Alkali metals, Aluminum.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Hydrogen chloride gas, Phosgene gas.
Hazardous Polymerization: Will not occur
11 - Toxicological Information
SIGNS AND SYMPTOMS OF EXPOSURE
Pulmonary edema. Effects may be delayed. Conjunctivitis.
Convulsions. Somnolence. Irregular breathing. Ingestion can
cause gastrointestinal disorders, nausea, and vomiting.
Weakness. Drowsiness. Increased liver enzymes. Paresthesia.
Dichloromethane is metabolized in the body producing carbon
monoxide which increases and sustains carboxyhemoglobin levels
in the blood, reducing the oxygen-carrying capacity of the
blood. A simple asphyxiant, exposure can cause anesthetic
action, difficulty in breathing, headache, and dizziness.
Prolonged or repeated contact with skin can cause defatting and
dermatitis. Contact with eyes can cause redness, tearing, and
blurred vision. Ingestion may cause gastrointestinal irritation.
ROUTE OF EXPOSURE
Skin Contact: Causes skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes eye irritation.
Inhalation: Material is irritating to mucous membranes and upper
respiratory tract. May be harmful if inhaled.
Ingestion: Harmful if swallowed.
TARGET ORGAN INFORMATION
Target organ: central nervous system because of possible
dizziness, headache, loss of consciousness and death at high
concentrations. Liver. Pancreas. Blood. Target organ: heart
because methylene chloride is converted to carbon monoxide in
CONDITIONS AGGRAVATED BY EXPOSURE
Existing data suggests that methylene chloride may be a weak
mutagen in mammalian systems.
CHRONIC EXPOSURE - CARCINOGEN
Result: This is or contains a component that has been reported
to be carcinogenic based on its IARC, OSHA, ACGIH, NTP, or EPA
CHRONIC EXPOSURE - TERATOGEN
Result: Possible risk of congenital malformation in the fetus.
12 - Ecological Information
No data available.
13 - Disposal Considerations
Contact a licensed professional waste disposal service to dispose
of this material. Observe all federal, state, and local
14 - Transport Information
Proper Shipping Name: Dichloromethane
Proper Shipping Name: Dichloromethane
Marine Pollutant: No
Severe Marine Pollutant: No
Proper Shipping Name: Dichloromethane
Inhalation Packing Group I: No
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: T
May cause cancer. Possible risk of harm to the unborn child.
May cause sensitization by skin contact. Irritating to eyes,
respiratory system and skin. Toxic by inhalation, in contact
with skin and if swallowed.
Do not breathe vapor. Wear suitable protective clothing and
gloves. Avoid contact with skin and eyes.
Caution: Substance not yet fully tested (EU).
COUNTRY SPECIFIC INFORMATION
16 - Other Information
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2010 Co. License granted to make
unlimitedpaper copies for internal use only.
For R&D use only. Not for drug, household or other uses.
SECTION 16 - ADDITIONAL INFORMATION