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4,7,10-Trioxa-1,13-Tridecanediamine 4246-51-9 MSDS
Name: 4 7 10-Trioxa-1 13-tridecanediamine 95% Material Safety Data Sheet
Synonym: O,O'-Bis(3-aminopropyl)diethylene glyco
CAS: 4246-51-9
Section 1 - Chemical Product   MSDS Name:4 7 10-Trioxa-1 13-tridecanediamine 95% Material Safety Data Sheet
Synonym:O,O'-Bis(3-aminopropyl)diethylene glyco

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
4246-51-9 4,7,10-Trioxa-1,13-tridecanediamine 95% 224-207-2
Hazard Symbols: C
Risk Phrases: 34 52/53

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Causes burns. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. May cause blistering of the skin.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
In case of fire, use carbon dioxide, dry chemical powder or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Do not flush into a sewer. Cover with soda ash or sodium bicarbonate and place in a closed container for disposal.

Section 7 - HANDLING and STORAGE
  Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Take precautionary measures against static discharges. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 4246-51-9: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Clear liquid
Color: colorless to yellow
Odor: amine-like
pH: >12 (100 g/l H2O)
Vapor Pressure: <0.001 @hPa deg C
Viscosity: 14.4 mPa.s @20 deg C
Boiling Point: 146 - 148 deg C @0.8mmHg
Freezing/Melting Point: -32 deg C
Autoignition Temperature: 260 deg C ( 500.00 deg F)
Flash Point: 139 deg C ( 282.20 deg F)
Explosion Limits, lower: 1.1 Vol %
Explosion Limits, upper: 4.5 Vol %
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.010
Molecular Formula: C10H24N2O3
Molecular Weight: 220.31

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 4246-51-9: ID6475000 LD50/LC50:
CAS# 4246-51-9: Oral, rat: LD50 = 4290 uL/kg; Skin, rabbit: LD50 = 2500 uL/kg.
Carcinogenicity:
4,7,10-Trioxa-1,13-tridecanediamine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Leuciscus idus: EC50 = 8.13-8.71 mg/L; 96HDaphnia: Daphnia: EC50 = 8.13-8.71 mg/L; 48HAlgae: EC50 = 8.13-8.71 mg/L; 72H;DOC or COD reduction <20%.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 8
UN Number: 2735
Packing Group: II
IMO
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing Group: II
RID/ADR
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing group: II

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
R 52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 4246-51-9: 2
Canada
CAS# 4246-51-9 is listed on Canada's DSL List.
CAS# 4246-51-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4246-51-9 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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