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Tripiperazine bis(2-hydroxypropane-1,2,3-tricarboxylate) pentahydrate 41372-10-5 MSDS

Section 1. Chemical Product and Company Identification
    Piperazine, anhydrous
    Common Name/
    Trade Name
    Commercial Name(s)
    Chemical Name
    Chemical Family
    Piperazine, anhydrous
    Potential Chronic Health        Slightly hazardous in case of skin contact (sensitizer), of inhalation (lung irritant, lung sensitizer).    
    CARCINOGENIC EFFECTS: Not available.
    MUTAGENIC EFFECTS: Not available.
    TERATOGENIC EFFECTS: Not available.
    The substance may be toxic to lungs, upper respiratory tract, skin.
    Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure of
    the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skin
    destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or
    lung damage.

Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for    
    at least 15 minutes. Cold water may be used. Get medical attention immediately.
    Skin Contact        In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing    
    contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash
    clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
    Serious Skin Contact        Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate    
    medical attention.
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.    
    Get medical attention immediately.
    Serious Inhalation        Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or    
    waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
    resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth
    resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention.
    Ingestion        Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an    
    unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen
    tight clothing such as a collar, tie, belt or waistband.
    Serious Ingestion        Not available.    

Section 5. Fire and Explosion Data
    Flammability of the Product May be combustible at high temperature.
    Auto-Ignition Temperature 454.97°C (850.9°F)
    Flash Points        OPEN CUP: 107°C (224.6°F).    
    Flammable Limits        LOWER: 1.6% UPPER: 12.5%    
    Products of Combustion        These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).    
    Fire Hazards in Presence of Slightly flammable to flammable in presence of heat, of oxidizing materials.
    Various Substances        Non-flammable in presence of shocks.    
    Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
    of Various Substances        Risks of explosion of the product in presence of static discharge: Not available.    
    Slightly explosive in presence of heat.
    SMALL FIRE: Use DRY chemical powder.
    Fire Fighting Media
    and Instructions        LARGE FIRE: Use water spray, fog or foam. Do not use water jet.    
    Special Remarks on        It may burn, but does not ignite readily. When heated to decomposition it emits highly toxic fumes. As with    
    most organic solids, fire is possible at elevated temperatures
    Fire Hazards
    Special Remarks on Explosion Containers may explode when heated.
    Piperazine, anhydrous

Section 6. Accidental Release Measures
    Small Spill        Use appropriate tools to put the spilled solid in a convenient waste disposal container.    
    Large Spill        Corrosive solid.    
    Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
    reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition

Section 7. Handling and Storage
    Precautions        Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not    
    ingest. Do not breathe dust. Never add water to this product. If ingested, seek medical advice immediately
    and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such
    as oxidizing agents, acids.
    Storage        Keep container tightly closed. Keep container in a cool, well-ventilated area. Sensitive to light. Store in    
    light-resistant containers. Hygroscopic

Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below    
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep
    exposure to airborne contaminants below the exposure limit.
    Personal Protection        Splash goggles. Synthetic apron. Dust respirator. Be sure to use an approved/certified respirator or    
    equivalent. Gloves.
    Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be
    a Large Spill        used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a    
    specialist BEFORE handling this product.
    Exposure Limits        Not available.    

Section 9. Physical and Chemical Properties
    Physical state and appearance Solid. (Deliquescent crystals solid.)        Characteristic. Amine like. Ammoniacal.    
    Taste        Saline.    
    Molecular Weight        86.14 g/mole    
    Color        Colorless.    
    pH (1% soln/water)        Not available.    
    Boiling Point        146°C (294.8°F)    
    Melting Point        106°C (222.8°F)    
    Critical Temperature        Not available.    
    1.1 (Water = 1)
    Specific Gravity
    Vapor Pressure        Not applicable.    
    3 (Air = 1)
    Vapor Density
    Volatility        Not available.    
    Odor Threshold        Not available.    
    Water/Oil Dist. Coeff.        The product is more soluble in water; log(oil/water) = -1.2    
    Ionicity (in Water)        Not available.    
    See solubility in water.
    Dispersion Properties
    Solubility        Easily soluble in cold water.    
    Insoluble in diethyl ether.
    Freely soluble in glycerol, and glycols.
    Piperazine, anhydrous

Section 10. Stability and Reactivity Data
    The product is stable.
    Instability Temperature        Not available.    
    Conditions of Instability        Excess heat, incompatible materials, moisture/moist air    
    Incompatibility with various        Reactive with oxidizing agents, acids.    
    Non-corrosive in presence of glass.
    Special Remarks on        Sensitive to light. Hygroscopic; keep container tightly closed.    
    Reactivity        Also incompatible with acid chlorides, acid anhydrides, dicyanofurazan.    
    Not available.
    Special Remarks on
    Polymerization        Will not occur.    

Section 11. Toxicological Information
    Routes of Entry        Absorbed through skin. Inhalation. Ingestion.    
    Toxicity to Animals        Acute oral toxicity (LD50): 600 mg/kg [Mouse].    
    Acute toxicity of the dust (LC50): 5400 mg/m3 2 hours [Mouse].
    Chronic Effects on Humans May cause damage to the following organs: lungs, upper respiratory tract, skin.
    Other Toxic Effects on        Hazardous in case of skin contact (irritant), of ingestion, of inhalation (lung sensitizer, lung corrosive).    
    Humans        Slightly hazardous in case of skin contact (corrosive, sensitizer, permeator), of eye contact (corrosive).    
    Special Remarks on        Not available.    
    Toxicity to Animals
    Special Remarks on        Not available.    
    Chronic Effects on Humans
    Special Remarks on other        Acute Potential Health Effects:    
    Toxic Effects on Humans        Skin: Causes skin irritation and possible burns. It can be absorbed though the skin and cause system    
    Eyes: Eye contact can cause severe irritation or burns.
    Inhalation: May cause respiratory tract irritation (irritation of bronchial tubes, lungs) wheezing, severe hacking
    cough, and shortness of breath (dypnea). Inhalation of high concentrations can affect behavior/central
    nervous system, and vision and cause weakness, reduced coordination, and balance, lethargy, tremors,
    trigger seizures (epileptic attacks), and blurred vision. It can also interefere with the ability of the blood to
    carry oxygen (a condition called methemoglobinemia). This can cause headaches, dizziness, nausea, and a
    bluish color to the skin and lips.
    Ingestion: May be harmful if swallowed. It can cause digestive tract irritation with possible burns, nausea,
    vomiting, clonic spasms, diarrhea. It can cause vague ocular disturbances, urticaria, and affect
    behavior/central nervous system with symptoms similar to those of acute inhalation as well as euphoria,
    inabililty to think clearly, and/or hallucinations, dropping of objects, loss of conciousness, dysarthria, apraxia,
    dysphagia, vertigo. It may affect the liver, respiration, cardiovascular system.
    Chronic Potential Health Effects:
    Skin: Prolonged or repeated skin contact may cause skin allergy (rash with itching).
    Inhalation: Prolonged or repeated inhalation may cause lung allergy or asthma(wheezing, chest tightness).

Section 12. Ecological Information
    Ecotoxicity        Not available.    
    Not available.
    BOD5 and COD
    Products of Biodegradation        Possibly hazardous short term degradation products are not likely. However, long term degradation products    
    may arise.
    The products of degradation are less toxic than the product itself.
    Toxicity of the Products
    of Biodegradation
    Piperazine, anhydrous
    Not available.
    Special Remarks on the
    Products of Biodegradation

Section 13. Disposal Considerations
    Waste Disposal        Waste must be disposed of in accordance with federal, state and local environmental    
    control regulations.

Section 14. Transport Information
    DOT Classification        Class 8: Corrosive material    
    UNNA: 2579 : Piperazine PG: III
    Special Provisions for        Not available.    
    DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
    Federal and State        Pennsylvania RTK: Piperazine, anhydrous    
    Massachusetts RTK: Piperazine, anhydrous
    Massachusetts spill list: Piperazine, anhydrous
    New Jersey: Piperazine, anhydrous
    TSCA 8(b) inventory: Piperazine, anhydrous
    California prop. 65: This product contains the following ingredients for which the State of California has
    found to cause cancer which would require a warning under the statute: No products were found.
    Proposition 65
    California prop. 65: This product contains the following ingredients for which the State of California has
    found to cause birth defects which would require a warning under the statute: No products were found.
    Other Regulations        OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).    
    EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS
    No. 203-808-3).
    Canada: Listed on Canadian Domestic Substance List (DSL).
    China: Listed on National Inventory.
    Japan: Listed on National Inventory (ENCS).
    Korea: Listed on National Inventory (KECI).
    Philippines: Listed on National Inventory (PICCS).
    Australia: Listed on AICS.
    Other Classifications        WHMIS (Canada) CLASS E: Corrosive solid.    
    DSCL (EEC)        R34- Causes burns.        S22- Do not breathe dust.    
    R42/43- May cause sensitization by        S26- In case of contact with eyes, rinse    
    inhalation and skin contact.        immediately with plenty of water and seek    
    R63- Possible risk of harm to the        medical advice.    
    unborn child.        S36/37/39- Wear suitable protective clothing,    
    gloves and eye/face protection.
    S45- In case of accident or if you feel unwell,
    seek medical advice immediately (show the
    label where possible).
    Health Hazard
    HMIS (U.S.A.)        3 National Fire Protection    
    1 Flammability
    1 Association (U.S.A.)
    Fire Hazard
    3 0 Reactivity
    Specific hazard
    Personal Protection
    Piperazine, anhydrous
    WHMIS (Canada)
    DSCL (Europe)
    TDG (Canada)
    ADR (Europe)
    Protective Equipment
    Synthetic apron.
    Dust respirator. Be sure to use an
    approved/certified respirator or
    equivalent. Wear appropriate
    respirator when ventilation is


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