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3-Heptylacrolein 3913-81-3 MSDS

Section I.Chemical Product and Company Identification
    Chemical Name        trans-2-Decen-1-al    
    (contains trans-2-Decen-1-al Diethylacetal)(10% in Ethanol)
    Ethanol
    Portland OR
    Synonym        Not available.    
    Chemical Formula        C10H18O    
    3913-81-3
    CAS Number
    64-17-5 (Ethanol)

Section II.        Composition and Information on Ingredients    
    Chemical Name        CAS Number Percent (%)        TLV/PEL        Toxicology Data    
    trans-2-Decen-1-al        3913-81-3        Ca. 10%        This chemical is classified as a (Ethanol)    
    (contains trans-2-Decen-1-al Diethylacetal)(10% in Ethanol)
    64-17-5        Ca. 90        possible carcinogen. There is Rat LD50 (oral) 7060 mg/kg    
    Ethanol
    %(Ethanol)        no acceptable exposure limit for Mouse LD50 (oral) 3450 mg/kg    
    (Ethanol)
    a carcinogen.
    This compound is classified as
    a mutagen. There is no
    acceptable exposure limit for a
    mutagen.

Section III. Hazards Identification
    Toxic if ingested or inhaled. Avoid prolonged contact with this material. Overexposure may result in serious illness or death.
    Acute Health Effects
    Irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system. Inflammation of the
    eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or,
    occasionally, blistering.
    Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.
    CARCINOGENIC EFFECTS : Not available.
    Chronic Health Effects
    MUTAGENIC EFFECTS : Not available.
    TERATOGENIC EFFECTS : Not available.
    DEVELOPMENTAL TOXICITY: Reproductive effects
    (Ethanol)
    Rat LDLo (Intraperitoneal) 600 mg/kg Feamel 8-15 days of pregnancy.
    Toxic effects:
    Effects on fertility- Post-implantation mortality
    Effects on Embryo or Fetus- Extra embryonic structures
    Effects on Embryo or Fetus- Fetotoxicity
    Rat TDLo (Oral) 135 gm/kg Female 1 day of pregnancy-7 days after birth
    Toxic effects:
    Effects on Newborn- Behavioral
    Effects on Newborn- Physical
    Rat TDLo (Oral) 147 mg/kg Feamle 1-21 days of pregnancy.
    Toxic effects:
    Specific Developmental Abnormalities- Endocrine system
    Effects on Newborn- Delayed effects
    Repeated exposure to an highly toxic material may produce general deterioration of health by an accumulation in one or
    many human organs.
    Continued on Next Page
    trans-2-Decen-1-al
    (contains trans-2-Decen-1-al Diethylacetal)(10% in Ethanol)
    Ethanol

Section IV.        First Aid Measures    
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15    
    minutes. Get medical attention.
    Skin Contact        In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing    
    and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
    If the victim is not breathing, perform mouth-to-mouth resuscitation. Loosen tight clothing such as a collar, tie, belt or
    Inhalation
    waistband. If breathing is difficult, oxygen can be administered. Seek medical attention if respiration problems do not
    improve.
    INDUCE VOMITING by sticking finger in throat. Lower the head so that the vomit will not reenter the mouth and throat.
    Ingestion
    Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth
    resuscitation. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic
    material was ingested; the absence of such signs, however, is not conclusive.

Section V.        Fire and Explosion Data    
    363°C (685.4°F) (Ethanol)
    Flammable.        Auto-Ignition    
    Flammability
    Flash Points        Flammable Limits        LOWER: 3.3% UPPER: 19% (Ethanol)    
    12°C (53.6°F).
    These products are toxic carbon oxides (CO, CO2).
    Combustion Products
    Fire Hazards
    Not available.
    Risks of explosion of the product in presence of mechanical impact: Not available.
    Explosion Hazards
    Risks of explosion of the product in presence of static discharge: Not available.
    Fire Fighting Media
    Flammable liquid.
    SMALL FIRE: Use DRY chemical powder.
    and Instructions
    LARGE FIRE: Use alcohol foam, water spray or fog.
    Consult with local fire authorities before attempting large scale fire-fighting operations.

Section VI.        Accidental Release Measures    
    Spill Cleanup        Flammable liquid. Toxic material. Irritating material. Mutagenic material. Possibly carcinogenic material. Environmentally    
    hazardous material. Hygroscopic material.
    Instructions
    Keep away from heat. Mechanical exhaust required. Stop leak if without risk. Absorb with DRY earth, sand or other
    non-combustible material. DO NOT get water inside container. DO NOT touch spilled material. Use water spray to reduce
    vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Consult federal, state, and/or local
    authorities for assistance on disposal.

Section VII. Handling and Storage
    FLAMMABLE. TOXIC. IRRITANT. MUTAGEN. POSSIBLE CARCINOGEN. ENVIRONMENTAL HAZARD. HYGROSCOPIC.
    Handling and Storage
    Keep locked up. Keep away from heat. Mechanical exhaust required. Avoid excessive heat and light. DO NOT ingest. Do
    Information
    not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. If ingested, seek medical advice immediately and
    show the container or the label. Treat symptomatically and supportively.
    Always store away from incompatible compounds such as oxidizing agents.

Section VIII. Exposure Controls/Personal Protection
    Engineering Controls        Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective    
    threshold limit value. Ensure that eyewash station and safety shower is proximal to the work-station location.
    Personal Protection        Splash goggles. Lab coat. Vapor respirator. Boots. Gloves. A MSHA/NIOSH approved respirator must be used to avoid    
    inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
    product.
    Exposure Limits        This chemical is classified as a possible carcinogen. There is no acceptable exposure limit for a carcinogen.    
    This compound is classified as a mutagen. There is no acceptable exposure limit for a mutagen.

Section IX. Physical and Chemical Properties
    Physical state @ 20°C        Liquid. (Clear. Colorless, slightly pale        Solubility        Soluble in alcohol.    
    yellow.)
    0.84 (water=1)
    Specific Gravity
    0.79 (Ethanol)
    Molecular Weight        154.25        Partition Coefficient        LOG Pow: 3.792    
    LOG Pow: -0.32 (Ethanol)
    46.07 (ethanol)
    Boiling Point        78°C - 80°C (172.4°F - 176°F) (ethanol)        Vapor Pressure        5.8 kPa @ 20°C (Ethanol)    
    Melting Point        Not available.        Vapor Density        1.6 (Ethanol)    
    Not available.        Not available.    
    Refractive Index        Volatility    
    Not available.
    Critical Temperature        Not available.        Odor    
    Viscosity        Not available.        Taste        Not available.    
    Continued on Next Page
    trans-2-Decen-1-al
    (contains trans-2-Decen-1-al Diethylacetal)(10% in Ethanol)
    Ethanol

Section X.        Stability and Reactivity Data    

This material is stable if stored under proper conditions. (See Section VII for instructions)
    Stability
    Conditions of Instability        Avoid excessive heat and light.    
    Incompatibilities        Reactive with oxidizing agents.    
    Reactive with peroxides, ammonia, alkali metals. (Ethanol)

Section XI. Toxicological Information
    KQ6300000 (Ethanol)
    RTECS Number
    Eye Contact. Ingestion. Inhalation.
    Routes of Exposure
    (Ethanol)
    Toxicity Data
    Rat LD50 (oral) 7060 mg/kg
    Mouse LD50 (oral) 3450 mg/kg
    Chronic Toxic Effects        CARCINOGENIC EFFECTS : Not available.    
    MUTAGENIC EFFECTS : Not available.
    TERATOGENIC EFFECTS : Not available.
    DEVELOPMENTAL TOXICITY: Reproductive effects
    (Ethanol)
    Rat LDLo (Intraperitoneal) 600 mg/kg Feamel 8-15 days of pregnancy.
    Toxic effects:
    Effects on fertility- Post-implantation mortality
    Effects on Embryo or Fetus- Extra embryonic structures
    Effects on Embryo or Fetus- Fetotoxicity
    Rat TDLo (Oral) 135 gm/kg Female 1 day of pregnancy-7 days after birth
    Toxic effects:
    Effects on Newborn- Behavioral
    Effects on Newborn- Physical
    Rat TDLo (Oral) 147 mg/kg Feamle 1-21 days of pregnancy.
    Toxic effects:
    Specific Developmental Abnormalities- Endocrine system
    Effects on Newborn- Delayed effects
    Repeated exposure to an highly toxic material may produce general deterioration of health by an accumulation in one or many
    human organs.
    Toxic if ingested or inhaled. Avoid prolonged contact with this material. Overexposure may result in serious illness or death.
    Acute Toxic Effects
    Irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system. Inflammation of the eye
    is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or,
    occasionally, blistering.
    Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.

Section XII.        Ecological Information    
    Not available.
    Ecotoxicity
    Environmental Fate        Not available.    

Section XIII. Disposal Considerations
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a
    Waste Disposal
    combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all
    federal, state and local regulations when disposing of the substance.

Section XIV. Transport Information
    DOT Classification        DOT CLASS 3: Flammable liquid    
    PIN Number
    Proper Shipping Name        Ethanol solution.    
    Packing Group (PG)        II    
    DOT Pictograms
    Continued on Next Page
    trans-2-Decen-1-al
    (contains trans-2-Decen-1-al Diethylacetal)(10% in Ethanol)
    Ethanol

Section XV. Other Regulatory Information and Pictograms
    TSCA Chemical Inventory        This compound is ON the EPA Toxic Substances Control Act (TSCA) inventory list.    
    (EPA)
    WHMIS Classification        CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F).    
    On DSL.
    (Canada)
    EINECS Number (EEC)        223-474-2    
    200-578-6 (Ethanol)
    EEC Risk Statements        R10- Flammable.    
    R18- In use, may form flammable/explosive vapor-air mixture.
    R46- May cause heritable genetic damage.
    R47- May cause birth defects.
    R23/24/25- Toxic by inhalation, in contact with skin and if swallowed.
    R36/37/38- Irritating to eyes, respiratory system and skin.
    R51- Toxic to aquatic organisms.
    R53- May cause long-term adverse effects in the aquatic environment.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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