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N'-[2-(3-trimethoxysilylpropylamino)ethyl]ethane-1,2-diamine 35141-30-1 MSDS
Name: 3-[2-(2-Aminoethylamino)ethylamino]propyl-trimethoxysilane tech. Material Safety Data Sheet
Synonym: (3-(Trimethoxysilyl)propyl)diethylenetriamine
CAS: 35141-30-1
Section 1 - Chemical Product   MSDS Name:3-[2-(2-Aminoethylamino)ethylamino]propyl-trimethoxysilane tech. Material Safety Data Sheet
Synonym:(3-(Trimethoxysilyl)propyl)diethylenetriamine

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
35141-30-1 3-[2-(2-Aminoethylamino)ethylamino]pro 95 252-390-9
Hazard Symbols: C
Risk Phrases: 14 34 43

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Reacts violently with water. Causes burns. May cause sensitization by skin contact.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Contact with water liberates highly flammable gases.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Provide ventilation. Do not expose spill to water.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not breathe vapor or mist.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 35141-30-1: Personal Protective Equipment Eyes: Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear yellow
Odor: amine-like
pH: 10.4 (10 g/l@20C)
Vapor Pressure: < 0.1 hPa @ 20 deg C
Viscosity: 23 mPas@20 deg C
Boiling Point: 114-118 deg C @ 2 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density: 1.031
Molecular Formula: C10H27N3O3Si
Molecular Weight: 265.43

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable. Material generates methanol on contact with water or moisture on the skin, eyes and mucous membranes.
Conditions to Avoid:
Ignition sources, excess heat, Reacts with water to form methanol.
The heat of the reaction may ignite the vapor of the alcohol..
Incompatibilities with Other Materials:
Water, strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, silicon dioxide, methanol.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 35141-30-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-[2-(2-Aminoethylamino)ethylamino]propyl-trimethoxysilane - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: Polyamines, Liquid, Corrosive, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing Group: III
IMO
Shipping Name: Polyamines, Liquid, Corrosive, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing Group: III
RID/ADR
Shipping Name: Polyamines, Liquid, Corrosive, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 14 Reacts violently with water.
R 34 Causes burns.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 8 Keep container dry.
S 24/25 Avoid contact with skin and eyes.
S 30 Never add water to this product.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 35141-30-1: No information available.
Canada
CAS# 35141-30-1 is listed on Canada's DSL List.
CAS# 35141-30-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 35141-30-1 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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