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3-(N-Styrylmethyl-2-aminoethylamino)-propyltrimethoxysilane hydrochloride 34937-00-3 MSDS
  N-[2-(N-Vinylbenzylamino)ethyl]-3-      Revision number: 5    
  aminopropyltrimethoxysilane Hydrochloride (30-40% in
  Methanol)
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        N-[2-(N-Vinylbenzylamino)ethyl]-3-aminopropyltrimethoxysilane Hydrochloride (30-    
    40% in Methanol)
             
    5
  Revision number:

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS
  Flammable liquids        Category 2    
  HEALTH HAZARDS
  Acute toxicity (Oral)        Category 5    
  Serious eye damage/eye irritation        Category 2A    
  Reproductive toxicity        Category 1B    
  Specific target organ toxicity        Visual system, Central nervous system    
  - Single exposure [Category 1]
  Specific target organ toxicity        Respiratory tract irritation, Narcotic effects    
  - Single exposure [Category 3]
  Specific target organ toxicity        Visual system, Central nervous system    
  - Repeated exposure [Category 1]
  ENVIRONMENTAL HAZARDS        Not classified    
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
  Signal word        Danger    
  Hazard statements        Highly flammable liquid and vapour    
    May be harmful if swallowed
    Causes serious eye irritation
    May damage fertility or the unborn child
    Causes damage to organs : Visual system Central nervous
    system
    Causes damage to organs through prolonged or repeated
    exposure : Visual system Central nervous system
    May cause respiratory irritation
    May cause drowsiness or dizziness
  Precautionary statements:
  N-[2-(N-Vinylbenzylamino)ethyl]-3-
  aminopropyltrimethoxysilane Hydrochloride
  (30-40% in Methanol)

Section 2. HAZARDS IDENTIFICATION
  [Prevention]        Obtain special instructions before use.    
    Do not handle until all safety precautions have been read and understood.
    Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
    Keep container tightly closed.
    Use explosion-proof electrical/ventilating/lighting equipment. Take precautionary
    measures against ignition by the static discharge and the spark.
    Do not breathe dust/fume/gas/mist/vapours/spray.
    Use only outdoors or in a well-ventilated area.
    Do not eat, drink or smoke when using this product.
    Wash hands thoroughly after handling.
    Wear protective gloves/eye protection/face protection.
  [Response]        IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for    
    breathing.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
    skin with water/shower.
    IF exposed or concerned: Get medical advice/attention.
  [Storage]        Store in a well-ventilated place. Keep container tightly closed.    
    Store locked up.
  [Disposal]        Dispose of contents/container through a waste management company authorized by    
    the local government.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Mixture    
  Components:        N-[2-(N-Vinylbenzylamino)ethyl]-3-aminopropyltrimethoxysilane Hydrochloride (30-    
    40% in Methanol)
  Percent:        ....    
    34937-00-3
  CAS Number:
  Synonyms:        Trimethoxy-N-[2-(N-vinylbenzylamino)ethyl]aminopropylsilane Hydrochloride    
  Chemical Formula:        C17H30N2O3Si·HCl    

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.    
    Get medical advice/attention.
    Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
  Skin contact:
    soap and water. Get medical advice/attention.
    Rinse cautiously with water for several minutes. Remove contact lenses, if present
  Eye contact:
    and easy to do. Get medical advice/attention.
    Get medical advice/attention.Rinse mouth.
  Ingestion:
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-    
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
    Dry chemical, foam, water in large amounts, carbon dioxide.
  Suitable extinguishing
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.    
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by
    spraying with water. Eliminate all ignition sources if safe to do so.
    When extinguishing fire, be sure to wear personal protective equipment.
  Special protective
  equipment for firefighters:
  N-[2-(N-Vinylbenzylamino)ethyl]-3-
  aminopropyltrimethoxysilane Hydrochloride
  (30-40% in Methanol)

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use extra personal protective equipment (self-contained breathing apparatus). Keep    
  protective equipment and people away from and upwind of spill/leak. Ensure adequate ventilation. Entry to non-
  emergency procedures: involved personnel should be controlled around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Absorb spilled material in dry sand or inert absorbent before recovering it into an
  containment and cleaning airtight container. In case of large amount of spillage, contain a spill by bunding.
  up: Adhered or collected material should be promptly disposed of, in accordance with
    appropriate laws and regulations.
  Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in
    case of a fire. Use spark-proof tools and explosion-proof equipment.
  hazards:

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
    Handling is performed in a well ventilated place. Wear suitable protective equipment.
  Technical measures:
    Prevent generation of vapour or mist. Keep away from heat/sparks/open flame/hot
    surfaces. -No smoking. Take measures to prevent the build up of electrostatic
    charge. Use explosion-proof equipment. Wash hands and face thoroughly after
    handling.
    Use a closed system if possible. Use a ventilation, local exhaust if vapour or aerosol
    will be generated.
  Advice on safe handling: Avoid all contact!
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool, dark and well-ventilated place.    
    Store under inert gas.
    Protect from moisture.
    Store locked up.
    Store away from incompatible materials such as oxidizing agents.
    Moisture-sensitive
  Packaging material:        Comply with laws.    

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
    Install a closed system or local exhaust. Also install safety shower and eye bath.
  Engineering controls:
  Exposure limits:        (Methanol)    
    ACGIH TLV(TWA):200 ppm (skin)
    ACGIH TLV(STEL):250 ppm (skin)
    OSHA PEL(TWA):200 ppm
  Personal protective equipment
  Respiratory protection: Half or full facepiece respirator, self-contained breathing apparatus(SCBA), supplied
    air respirator, etc. Use respirators approved under appropriate government standards
    and follow local and national regulations.
  Hand protection:        Impervious gloves.    
    Safety goggles. A face-shield, if the situation requires.
  Eye protection:
  Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Liquid    
    Clear
  Form:
  Colour:        Yellow - Deep yellow red    
    Characteristic
  Odour:
  pH: No data available
  Melting point/freezing point:No data available
    (Methanol) -98°C
    No data available
  Boiling point/range:
  N-[2-(N-Vinylbenzylamino)ethyl]-3-
  aminopropyltrimethoxysilane Hydrochloride
  (30-40% in Methanol)

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
    (Methanol) 64°C
  Flash point:        No data available    
    (Methanol) 12°C
  Flammability or explosive
  limits:
  Lower:        No data available    
  Upper:        No data available    
  Relative density:        No data available    
  Solubility(ies):
  [Water]        No data available    
  [Other solvents]        No data available    
  Log Pow:        (Methanol) -0.82/-0.66    

Section 10. STABILITY AND REACTIVITY
    Stable under proper conditions.
  Chemical stability:
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Conditions to avoid:        Spark, Open flame, Static discharge    
  Incompatible materials: Oxidizing agents, Acid chlorides, Acid anhydrides, Reducing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx), Hydrogen chloride,
    Silicon oxides
  products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available    
    (Methanol)
    orl-hmn LDLo:143 mg/kg
    orl-rat LD50:5600 mg/kg
    ihl-rat LC50:64000 ppm/4H
    skn-rbt LD50:15800 mg/kg
  Skin corrosion/irritation: No data available
    (Methanol)
    skn-rbt 20 mg/24H MOD
  Serious eye        No data available    
  damage/irritation:
    (Methanol)
    eye-rbt 40 mg MOD
  Germ cell mutagenicity: No data available
    (Methanol)
    dni-hmn-lym 300 mmol/L
    mmo-smc 12 pph (-S9)
    mmo-mus-lym 7900 mg/L (+S9)
    cyt-mus-ipr 75 mg/kg
  Carcinogenicity:
    No data available
  IARC =
  NTP =        No data available    
    No data available
  Reproductive toxicity:

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available    
  Crustacea:        No data available    
  Algae:        No data available    
  Persistence / degradability: No data available
  Bioaccumulative        No data available    
  potential(BCF):
  N-[2-(N-Vinylbenzylamino)ethyl]-3-
  aminopropyltrimethoxysilane Hydrochloride
  (30-40% in Methanol)

Section 12. ECOLOGICAL INFORMATION
  Mobility in soil
    No data available
  Log Pow:
  Soil adsorption (Koc):        No data available    
    No data available
  Henry's Law
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
    incinerator equipped with an afterburner and scrubber system but exert extra care in igniting as this material is
    highly flammable. Observe all federal, state and local regulations when disposing of the substance

Section 14. TRANSPORT INFORMATION
    3: Flammable liquid.
  Hazards Class:
  Subsidiary risk:        6.1: Toxic substance.    
    1230
  UN-No:
  Proper shipping name:        Methanol solution    
    II
  Packing group:

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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