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Dipropylene glycol monomethyl ether 34590-94-8 MSDS
  Dipropylene Glycol Monomethyl Ether (mixture of      Revision number: 5    
  isomers)
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        Dipropylene Glycol Monomethyl Ether (mixture of isomers)    
                  
  Revision number:        5    

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS
    Category 4
  Flammable liquids
  HEALTH HAZARDS
    Category 3
  Skin corrosion/irritation
  Serious eye damage/eye irritation        Category 2B    
  Specific target organ toxicity        Respiratory tract irritation, Narcotic effects    
  - Single exposure [Category 3]
  ENVIRONMENTAL HAZARDS        Not classified    
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
  Signal word        Warning    
    Combustible liquid
  Hazard statements
    Causes mild skin irritation
    Causes eye irritation
    May cause respiratory irritation
    May cause drowsiness or dizziness
  Precautionary statements:
  [Prevention]        Keep away from flames and hot surfaces.    
    Avoid breathing dust/fume/gas/mist/vapours/spray.
    Use only outdoors or in a well-ventilated area.
    Wear protective gloves and eye/face protection.
  [Response]        IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for    
    breathing.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    Wash hands thoroughly after handling.
    If skin irritation occurs: Get medical advice/attention.
    Call a POISON CENTER or doctor/physician if you feel unwell.
  [Storage]        Store in a well-ventilated place. Keep container tightly closed.    
    Store locked up.
  of isomers)

Section 2. HAZARDS IDENTIFICATION
  [Disposal]        Dispose of contents/container through a waste management company authorized by    
    the local government.
  Other hazards which do not        May form explosive peroxides.    
  result in classification

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
    Substance
  Substance/mixture:
  Components:        Dipropylene Glycol Monomethyl Ether (mixture of isomers)    
    >98.0%(GC)
  Percent:
  CAS Number:        34590-94-8    
  Chemical Formula:        C7H16O3    

Section 4. FIRST AID MEASURES
    Remove victim to fresh air and keep at rest in a position comfortable for breathing.
  Inhalation:
    Call a POISON CENTER or doctor/physician if you feel unwell.
    Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
  Skin contact:
    soap and water. If skin irritation or rash occurs: Get medical advice/attention.
    Rinse cautiously with water for several minutes. Remove contact lenses, if present
  Eye contact:
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth.    
  Most important        Cough, Dizziness, Drowsiness, Dry skin, Redness, Pain    
  symptoms/effects, acute
  and delayed:
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-    
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
    Dry chemical, foam, water in large amounts, carbon dioxide.
  Suitable extinguishing
  media:
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.    
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use extra personal protective equipment (self-contained breathing apparatus). Keep    
  protective equipment and people away from and upwind of spill/leak. Ensure adequate ventilation. Entry to non-
  emergency procedures: involved personnel should be controlled around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust).
  containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected
  up: material should be promptly disposed of, in accordance with appropriate laws and
    regulations.
  Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in
    case of a fire. Use spark-proof tools and explosion-proof equipment.
  hazards:

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
    Handling is performed in a well ventilated place. Wear suitable protective equipment.
  Technical measures:
    Prevent generation of vapour or mist. Keep away from flames and hot surfaces. Take
    measures to prevent the build up of electrostatic charge. Use explosion-proof
    equipment. Wash hands and face thoroughly after handling.
  of isomers)

Section 7. HANDLING AND STORAGE
    Use a closed system, ventilation.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
    Confirm in advance if peroxides exist when operations involving heating such as
    distillation are carried out.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool, dark and well-ventilated place.    
    Store locked up.
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Comply with laws.    

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
    Install a closed system or local exhaust. Also install safety shower and eye bath.
  Engineering controls:
  Exposure limits:
    100 ppm (skin)
  ACGIH TLV(TWA):
  ACGIH TLV(STEL):        150 ppm (skin)    
    100 ppm (skin)
  OSHA PEL(TWA):
  Personal protective equipment
  Respiratory protection: Half or full facepiece respirator, self-contained breathing apparatus(SCBA), supplied
    air respirator, etc. Use respirators approved under appropriate government standards
    and follow local and national regulations.
  Hand protection:        Impervious gloves.    
    Safety goggles. A face-shield, if the situation requires.
  Eye protection:
  Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Liquid    
    Clear
  Form:
  Colour:        Colorless - Almost colorless    
    Ether-like
  Odour:
  pH: No data available
  Melting point/freezing point:-80°C
  Boiling point/range:        188°C    
  Flash point:        77°C    
  Flammability or explosive
  limits:
  Lower:        1.3%    
  Upper:        10.4%    
  Vapour pressure:        53.3Pa/26°C    
  Vapour density:        5.1    
  Relative density:        0.95    
  Solubility(ies):
  [Water]        Miscible    
  [Other solvents]
  Miscible:        Methanol, Ether, Ethanol, Many organic solvents    
  Log Pow:        -0.064    
  Autoignition temperature:        270°C    

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        May form explosive peroxides.    
  Possibility of hazardous No special reactivity has been reported.
  reactions:
    Open flame, Air
  Conditions to avoid:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide
  products:
  of isomers)

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        orl-rat LD50:5400 uL/kg    
    skn-rbt LD50:10 mL/kg
    ihl-mam TCLo:3000 mg/m3
  Skin corrosion/irritation: skn-rbt 500 mg open MLD
  Serious eye        eye-rbt 500 mg/24H MLD    
  damage/irritation:        eye-hmn 8 mg MLD    
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available    
  NTP =        No data available    
  Reproductive toxicity:        No data available    
  RTECS Number:        JM1575000    

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
    No data available
  Fish:
  Crustacea:        No data available    
    No data available
  Algae:
  Persistence / degradability: No data available
    No data available
  Bioaccumulative
  potential(BCF):
  Mobility in soil
  Log Pow:        -0.064    
    No data available
  Soil adsorption (Koc):
    1.1 x 10-2
  Henry's Law
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
    incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
    disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        Does not correspond to the classification standard of the United Nations    
    Not listed
  UN-No:

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.
  of isomers)


SECTION 16 - ADDITIONAL INFORMATION
N/A

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