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amitraz 33089-61-1 MSDS
    Version 2.5
    Regulation (EC) No 1907/2006

    1 - Product and Company Information

    Product Name        AMITRAZ, 250MG, NEAT    

    2 - Hazards Identification

    SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
    Harmful if swallowed. May cause sensitization by skin contact.
    Harmful: danger of serious damage to health by prolonged exposure
    if swallowed. Very toxic to aquatic organisms, may cause long-term
    adverse effects in the aquatic environment.

    3 - Composition/Information on Ingredients

    Product Name        CAS #        EC no        Annex I    
    Index Number
    AMITRAZ, PESTANAL        33089-61-1 251-375-4 612-086-00-2    
    Formula        C19H23N3    
    Molecular Weight        293,4000 AMU    
    Synonyms        Acarac * Amitraz * Amitraze (French) * Amitraz    
    estrella * Azaform * Azadieno * BAAM * Bipin *
    N,N-Bis(2,4-xylyliminomethyl)methylamine * Boots
    BTS 27419 * BTS 27,419 *
    1,5-Di(2,4-dimethylphenyl)-3-methyl-1,3,5-triazap
    enta-1,4-diene *
    N'-(2,4-Dimethylphenyl)-N-(((2,4-dimethylphenyl)i
    mino)methyl)-N-methylmethanimidamide *
    N,N-Di-(2,4-xylyliminomethyl)methylamine *
    Ectodex * Edrizar * ENT 27967 * Fumilat A *
    Methanimidamide,
    N'-(2,4-dimethylphenyl)-N-(((2,4-dimethylphenyl)i
    mino)methyl)-N-methyl- *
    N-Methyl-bis(2,4-xylyliminomethyl)amine *
    2-Methyl-1,3-di(2,4-xylylimino)-2-azapropane *
    N,N'-((Methylimino)dimethylidyne)di-2,4-xylidine
    *
    N-Methyl-N'-2,4-xylyl-N-(N-2,4-xylylformimidoyl)f
    ormamidine * Mitaban * Mitac * R.D. 27419 *
    Taktic * U-36059 * Upjohn U-36059
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    4 - First Aid Measures

    AFTER INHALATION
    If inhaled, remove to fresh air. If not breathing give
    artificial respiration. If breathing is difficult, give oxygen.
    AFTER SKIN CONTACT
    In case of skin contact, flush with copious amounts of water for
    at least 15 minutes. Remove contaminated clothing and shoes.
    Call a physician.
    AFTER EYE CONTACT
    In case of contact with eyes, flush with copious amounts of
    water for at least 15 minutes. Assure adequate flushing by
    separating the eyelids with fingers. Call a physician.
    AFTER INGESTION
    If swallowed, wash out mouth with water provided person is
    conscious. Call a physician.

    5 - Fire Fighting Measures

    EXTINGUISHING MEDIA
    Suitable: Water spray. Carbon dioxide, dry chemical powder, or
    appropriate foam.
    SPECIAL RISKS
    Specific Hazard(s): Emits toxic fumes under fire conditions.
    SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
    Wear self-contained breathing apparatus and protective clothing
    to prevent contact with skin and eyes.

    6 - Accidental Release Measures

    PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
    Evacuate area.
    PROCEDURE(S) OF PERSONAL PRECAUTION(S)
    Wear self-contained breathing apparatus, rubber boots, and heavy
    rubber gloves.
    METHODS FOR CLEANING UP
    Sweep up, place in a bag and hold for waste disposal. Avoid
    raising dust. Ventilate area and wash spill site after material
    pickup is complete.

    7 - Handling and Storage

    HANDLING
    Directions for Safe Handling: Do not breathe dust. Avoid contact
    with eyes, skin, and clothing. Avoid prolonged or repeated
    exposure.
    STORAGE
    Conditions of Storage: Keep tightly closed.

    8 - Exposure Controls / Personal Protection

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    ENGINEERING CONTROLS
    Mechanical exhaust required. Safety shower and eye bath.
    GENERAL HYGIENE MEASURES
    Wash thoroughly after handling.
    PERSONAL PROTECTIVE EQUIPMENT
    Respiratory Protection: Use respirators and components tested and
    approved under appropriate government standards such as NIOSH (US)
    or CEN (EU). Where risk assessment shows air-purifying respirators
    are appropriate use a full-face particle respirator type N99 (US)
    or type P2 (EN 143) respirator cartridges as a backup to
    engineering controls. If the respirator is the sole means of
    protection, use a full-face supplied air respirator.
    Hand Protection: Compatible chemical-resistant gloves.
    Eye Protection: Chemical safety goggles.

    9 - Physical and Chemical Properties

    Appearance        Physical State: Solid    
    Color: Colorless
    Property        Value        At Temperature or Pressure    
    pH N/A
    BP/BP Range        > 200,000 °C        760,000 mmHg    
    MP/MP Range        > 45,000 °C    
    Flash Point        N/A    
    Flammability        N/A    
    Autoignition Temp        N/A    
    Oxidizing Properties N/A
    Explosive Properties N/A
    Explosion Limits        N/A    
    Vapor Pressure        N/A    
    Partition Coefficient N/A
    Viscosity        N/A    
    Vapor Density        N/A    
    Saturated Vapor Conc. N/A
    Evaporation Rate        N/A    
    Bulk Density        N/A    
    Decomposition Temp.        N/A    
    Solvent Content        N/A    
    Water Content        N/A    
    Surface Tension        N/A    
    Conductivity        N/A    
    Miscellaneous Data        N/A    
    Solubility        Solubility in Water:Insoluble.    
    Other Solvents: MOSTORGANIC SOLVENTS

    10 - Stability and Reactivity

    STABILITY
    Stable: Stable.
    Materials to Avoid: Strong oxidizing agents.
    HAZARDOUS DECOMPOSITION PRODUCTS
    Hazardous Decomposition Products: Carbon monoxide, carbon dioxide,
    and nitrogen oxides.
    HAZARDOUS POLYMERIZATION
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    Hazardous Polymerization: Will not occur

    11 - Toxicological Information

    RTECS NUMBER: ZF0480000
    ACUTE TOXICITY
    LDLO
    Oral
    Woman
    200 UL/KG
    Remarks: Cardiac:Other changes. Kidney, Ureter, Bladder:Changes
    in tubules (including acute renal failure, acute tubular
    necrosis). Brain and Coverings:Other degenerative changes.
    LD50
    Oral
    Rat
    400,000000 mg/kg
    LC50
    Inhalation
    Rat
    65.000, mg/m3
    6H
    LD50
    Skin
    Rat
    > 1600,000000 mg/kg
    LD50
    Intraperitoneal
    Rat
    800 MG/KG
    LD50
    Oral
    Mouse
    1085,000000 mg/kg
    LD50
    Oral
    Dog
    100,000000 mg/kg
    LD50
    Oral
    Rabbit
    > 100,000000 mg/kg
    LD50
    Skin
    Rabbit
    > 200,000000 mg/kg
    LD50
    Oral
    Guinea pig
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    > 400,000000 mg/kg
    LD50
    Oral
    Quail
    788,000000 mg/kg
    LD50
    Oral
    Duck
    7000,000000 mg/kg
    SENSITIZATION
    Sensitization: Sensitizer.
    Skin: May cause allergic skin reaction.
    SIGNS AND SYMPTOMS OF EXPOSURE
    To the best of our knowledge, the chemical, physical, and
    toxicological properties have not been thoroughly investigated.
    ROUTE OF EXPOSURE
    Skin Contact: May cause skin irritation.
    Skin Absorption: May be harmful if absorbed through the skin.
    Eye Contact: May cause eye irritation.
    Inhalation: May be harmful if inhaled. Material may be
    irritating to mucous membranes and upper respiratory tract.
    Ingestion: Harmful if swallowed.
    CHRONIC EXPOSURE - REPRODUCTIVE HAZARD
    Species: Rat
    Dose: 140 MG/KG
    Route of Application: Oral
    Exposure Time: (7D PRE)
    Result: Effects on Newborn: Delayed effects.

    12 - Ecological Information

    ECOTOXICOLOGICAL EFFECTS
    Test Type: EC50 Daphnia
    Species: Daphnia magna
    Time: 48,0 h
    Value: 3,400 mg/l
    Test Type: LC50 Fish
    Species: Lepomis macrochirus (Bluegill)
    Time: 96,0 h
    Value: 0,340 mg/l
    Test Type: LC50 Fish
    Species: Cyprinodon variegatus (Sheepshead minnow)
    Time: 96,0 h
    Value: 11,500 mg/l

    13 - Disposal Considerations

    SUBSTANCE DISPOSAL
    Contact a licensed professional waste disposal service to dispose
    of this material. Dissolve or mix the material with a combustible
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    solvent and burn in a chemical incinerator equipped with an
    afterburner and scrubber. Observe all federal, state, and local
    environmental regulations.

    14 - Transport Information

    RID/ADR
    UN#: 3077
    Class: 9
    PG: III
    Proper Shipping Name: Environmentally hazardous
    substance, solid, n.o.s
    IMDG
    UN#: 3077
    Class: 9
    PG: III
    Proper Shipping Name: Environmentally hazardous
    substance, solid, n.o.s
    Marine Pollutant: No
    Severe Marine Pollutant: No
    Technical Name: Required
    IATA
    UN#: 3077
    Class: 9
    PG: III
    Proper Shipping Name: Environmentally hazardous
    substance, solid, n.o.s
    Inhalation Packing Group I: No
    Technical Name: Required

    15 - Regulatory Information

    CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
    ANNEX I INDEX NUMBER: 612-086-00-2
    INDICATION OF DANGER: Xn-N
    Harmful. Dangerous for the environment.
    R-PHRASES: 22-43-48/22-50/53
    Harmful if swallowed. May cause sensitization by skin contact.
    Harmful: danger of serious damage to health by prolonged
    exposure if swallowed. Very toxic to aquatic organisms, may
    cause long-term adverse effects in the aquatic environment.
    S-PHRASES: 24-36/37-22-60-61
    Avoid contact with skin. Wear suitable protective clothing and
    gloves. Do not breathe dust. This material and its container
    must be disposed of as hazardous waste. Avoid release to the
    environment. Refer to special instructions/safety data sheets.
    COUNTRY SPECIFIC INFORMATION
    Germany
    WGK: 3
    Self-Classification

    16 - Other Information

    WARRANTY
    The above information is believed to be correct but does not
    purport to be all inclusive and shall be used only as a guide. The
    SUPELCO        www.molbase.com    
    information in this document is based on the present state of our
    knowledge and is applicable to the product with regard to
    appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Inc.,
    shall not be held liable for any damage resulting from handling or
    from contact with the above product. See reverse side of invoice
    or packing slip for additional terms and conditions of sale.
    Copyright 2010 Co. License granted to make
    unlimitedpaper copies for internal use only.
    DISCLAIMER
    For R&D use only. Not for drug, household or other uses.
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SECTION 16 - ADDITIONAL INFORMATION
N/A

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