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Bis(2,4-pentanediono)nickel 3264-82-2 MSDS
Name: Nickel(ii) acetylacetonate dihydrate 99+% (titr.) Material Safety Data Sheet
Synonym: Nickel 2,4-Pentanedionate; Bis(2,4-Pentanediono) Nickel; 2,4-Pentanedione, nickel(II) deriv.; Acetylacetonate, nickel (III); Bis(pentane-2,4-dionato-O,O')nickel;Nickel, bis(2,4-pentanedionato-kappaO,kappaO')-, (SP-4-1)-; Nickel, bis(2,4-pe
CAS: 3264-82-2
Section 1 - Chemical Product   MSDS Name:Nickel(ii) acetylacetonate dihydrate 99+% (titr.) Material Safety Data Sheet
Synonym:Nickel 2,4-Pentanedionate; Bis(2,4-Pentanediono) Nickel; 2,4-Pentanedione, nickel(II) deriv.; Acetylacetonate, nickel (III); Bis(pentane-2,4-dionato-O,O')nickel;Nickel, bis(2,4-pentanedionato-kappaO,kappaO')-, (SP-4-1)-; Nickel, bis(2,4-pe

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
3264-82-2 Nickel acetylacetone 99+ 221-875-7
Hazard Symbols: XN
Risk Phrases: 40 43

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Limited evidence of a carcinogenic effect. May cause sensitization by skin contact.Hygroscopic (absorbs moisture from the air).Cancer suspect agent.Harmful.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause severe dermatitis and urticaria(hives).
Ingestion:
May cause irritation of the digestive tract. May cause central nervous system effects.
Inhalation:
May cause allergic respiratory reaction. Inhalation of high concentrations may cause coughing and shortness of breath. Can produce delayed pulmonary edema.
Chronic:
May cause cancer according to animal studies. Prolonged or repeated exposure may cause lung irritation, chest pain, and pulmonary edema.
May cause adverse reproductive effects.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Keep from contact with moist air and steam. Do not breathe dust.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 3264-82-2: United States OSHA: 1 mg/m3 TWA (as Ni) (listed under Nickel sol compounds).
Belgium - TWA: (listed as nickel soluble compounds): 0.1 mg/m3 VL (as Ni) Malaysia: (listed as nickel soluble compounds): 0.1 mg/m3 TWA (inhalable fraction, as Ni) Netherlands: (listed as nickel soluble compounds): 0.1 mg/m3 MAC Ni) Spain: (listed as nickel soluble compounds): 0.1 mg/m3 VLA-ED (as Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: light green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 220 deg C @ 11.00mm Hg
Freezing/Melting Point: 230 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 230 deg C
Solubility in water: soluble in water
Specific Gravity/Density: 1.455
Molecular Formula: C10H14O4Ni
Molecular Weight: 256.90

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, moisture.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, 2,4-pentanedione, nickel oxide, acrid smoke and fumes, nickel.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 3264-82-2: SA2100000 LD50/LC50:
Not available.
Carcinogenicity:
Nickel acetylacetone - California: carcinogen, initial date 5/7/04 (listed as Nickel compound NTP: Known carcinogen (listed as Nickel compounds).
IARC: Group 1 carcinogen (listed as Nickel compounds).
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 40 Limited evidence of a carcinogenic effect.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 24 Avoid contact with skin.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 3264-82-2: 2
Canada
CAS# 3264-82-2 is listed on Canada's NDSL List.
CAS# 3264-82-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3264-82-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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