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epibromohydrin 3132-64-7 MSDS
Name: Epibromohydrin 98% Material Safety Data Sheet
Synonym: 1-Bromo-2,3-epoxypropane; Epibromohydrine; (Bromomethyl)ethylene oxide; 2-(Bromomethyl)oxirane; Propane, 3-bromo-1,2-epoxy
CAS: 3132-64-7
Section 1 - Chemical Product   MSDS Name:Epibromohydrin 98% Material Safety Data Sheet
Synonym:1-Bromo-2,3-epoxypropane; Epibromohydrine; (Bromomethyl)ethylene oxide; 2-(Bromomethyl)oxirane; Propane, 3-bromo-1,2-epoxy

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
3132-64-7 Epibromohydrin 98 221-525-3
Hazard Symbols: T+
Risk Phrases: 10 26/27/28 40

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Very toxic by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect.Lachrymator (substance which increases the flow of tears).Corrosive.Water-reactive.
Potential Health Effects
Eye:
May cause severe eye irritation. May cause eye burns. Lachrymator (substance which increases the flow of tears).
Skin:
May be fatal if absorbed through the skin. May cause severe irritation and possible burns.
Ingestion:
May be fatal if swallowed. May cause irritation of the digestive tract and possible burns.
Inhalation:
May be fatal if inhaled. May cause respiratory tract irritation.
Vapors may cause dizziness or suffocation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately. Induce vomiting only when instructed to do so by a physician.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors.

Section 7 - HANDLING and STORAGE
  Handling:
Use only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Do not ingest or inhale. Do not allow contact with water. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water. Flammables-area. Keep refrigerated. (Store below 4C/39F.)

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 3132-64-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: Colorless Liquid
Odor: None reported.
pH: Not available.
Vapor Pressure: 2 mm Hg @ 25 C
Viscosity: Not available.
Boiling Point: 134.0 - 136.0 deg C @ 760.00m
Freezing/Melting Point: -40 deg C
Autoignition Temperature: Not available.
Flash Point: 56 deg C ( 132.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts
Specific Gravity/Density: 1.6010g/cm3
Molecular Formula: C3H5BrO
Molecular Weight: 136.98

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Acids, aluminum, magnesium, sodium, strong oxidizing agents, zinc, water.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 3132-64-7: TX4115000 LD50/LC50:
Not available.
Intraperitoneal, mouse: LD50 = 300 Carcinogenicity:
Epibromohydrin - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Estimated Koc value = 22. This value indicates that epibromohydrin will not adsorb to soil and leaching may occur. Estimated BCF value = 0.5. This value indicates that epibromohydrin will not bioconcentrate in aquatic organisms.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: EPIBROMOHYDRIN
Hazard Class: 6.1 (3)
UN Number: 2558
Packing Group:
IMO
Shipping Name: EPIBROMOHYDRIN
Hazard Class: 6.1 (3)
UN Number: 2558
Packing Group: I
RID/ADR
Shipping Name: EPIBROMOHYDRIN
Hazard Class: 6.1
UN Number: 2558
Packing group: I

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 10 Flammable.
R 26/27/28 Very toxic by inhalation, in contact with
skin and if swallowed.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 7/9 Keep container tightly closed and in a
well-ventilated place.
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 27 Take off immediately all contaminated clothing.
S 33 Take precautionary measures against static
discharges.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 3132-64-7: No information available.
Canada
CAS# 3132-64-7 is listed on Canada's NDSL List.
CAS# 3132-64-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3132-64-7 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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