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dipotassium bis[μ-tartrato(4-)]diantimonate(2-) trihydrate 28300-74-5 MSDS
Name: Potassium antimonyl-tartrate hemihydrate 99+% Material Safety Data Sheet
Synonym: Antimony potassium tartrate; Potassium antimonyl d-tartrat
CAS: 28300-74-5
Section 1 - Chemical Product   MSDS Name:Potassium antimonyl-tartrate hemihydrate 99+% Material Safety Data Sheet
Synonym:Antimony potassium tartrate; Potassium antimonyl d-tartrat

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
28300-74-5 ANTIMONY POTASSIUM TARTRATE 99+% unlisted
Hazard Symbols: XN
Risk Phrases: 20/22

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver damage. May cause headache.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Minimize dust generation and accumulation. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 28300-74-5: United Kingdom, WEL - TWA: (listed as antimony): 0.5 mg/m3 TWA United Kingdom, WEL - STEL: (listed as antimony): 1.5 mg/m3 STEL United States OSHA: 0.5 mg/m3 TWA (listed under Antimony).
Belgium - TWA: (listed as antimony): 0.5 mg/m3 VLE France - VME: (listed as antimony): 0.5 mg/m3 VME Germany: (listed as antimony): 0.5 mg/m3 VME Japan: (listed as antimony): 0.1 mg/m3 OEL Malaysia: (listed as antimony): 0.5 mg/m3 TWA Netherlands: (listed as antimony): 0.5 mg/m3 MAC Russia: (listed as antimony): 0.5 mg/m3 TWA Russia: (listed as antimony): 0.2 mg/m3 STEL Spain: (listed as antimony): 0.5 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: Not available.
Odor: Odorless.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 100 deg C
Autoignition Temperature: Not available.
Flash Point: 100 deg C ( 212.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 100 deg C
Solubility in water: insoluble in alcohol
Specific Gravity/Density:
Molecular Formula: C4H4O7SbK.0.5H2O
Molecular Weight: 333.92

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizers - acids - bases - salts of heavy metals - lime water - albumin - soap .
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, antimony/antimony oxides, oxides of potassium.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 28300-74-5: CC6825000 LD50/LC50:
CAS# 28300-74-5: Oral, mouse: LD50 = 600 mg/kg; Oral, rabbit: LD50 = 115 mg/kg; Oral, rat: LD50 = 115 mg/kg.
Carcinogenicity:
ANTIMONY POTASSIUM TARTRATE - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Water Danger/Protection: WGK 2

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: ANTIMONY POTASSIUM TARTRATE
Hazard Class: 6.1
UN Number: 1551
Packing Group: III
IMO
Shipping Name: ANTIMONY POTASSIUM TARTRATE
Hazard Class: 6.1
UN Number: 1551
Packing Group: III
RID/ADR
Shipping Name: ANTIMONY POTASSIUM TARTRATE
Hazard Class: 6.1
UN Number: 1551
Packing group: III
USA RQ: CAS# 28300-74-5: 100 lb final RQ; 45.4 kg final RQ

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
Safety Phrases:
S 22 Do not breathe dust.
WGK (Water Danger/Protection)
CAS# 28300-74-5: 3
Canada
CAS# 28300-74-5 is listed on Canada's DSL List.
CAS# 28300-74-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 28300-74-5 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).


SECTION 16 - ADDITIONAL INFORMATION
N/A

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