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2-PROPOXYETHANOL 2807-30-9 MSDS
Name: 2-Propoxyethanol 98% (gc) Material Safety Data Sheet
Synonym: Ethylene glycol propyl ether
CAS: 2807-30-9
Section 1 - Chemical Product   MSDS Name:2-Propoxyethanol 98% (gc) Material Safety Data Sheet
Synonym:Ethylene glycol propyl ether

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
2807-30-9 2-Propoxyethanol 98 220-548-6
Hazard Symbols: XN XI F
Risk Phrases: 10 21 36

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Harmful in contact with skin. Irritating to eyes.
Potential Health Effects
Eye:
Causes severe eye irritation. May cause eye injury.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May cause liver and kidney damage. May cause blood abnormalities. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. Vapors may cause dizziness or suffocation.
Chronic:
None

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. May form explosive peroxides. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined areas. May be ignited by heat, sparks, and flame.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Regularly check inhibitor levels to maintain peroxide levels below 1%. Storage under a nitrogen blanket has been recommended.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 2807-30-9: Germany: 20 ppm TWA; 86 mg/m3 TWA Germany: Skin absorber Netherlands: 10 ppm MAC; 44 mg/m3 MAC Spain: 20 ppm VLA-ED; 86 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear yellow
Odor: ethereal odor
pH: Not available.
Vapor Pressure: 1.7 mbar @ 20 deg C
Viscosity: 2.42mPas
Boiling Point: 149.5 deg C
Freezing/Melting Point: -90 deg C
Autoignition Temperature: 230 deg C ( 446.00 deg F)
Flash Point: 125 deg F ( 51.67 deg C)
Explosion Limits, lower: 1.26 vol%
Explosion Limits, upper: 15.8 vol%
Decomposition Temperature:
Solubility in water: soluble in water
Specific Gravity/Density: .9130g/cm3
Molecular Formula: C5H12O2
Molecular Weight: 104.15

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures. On long term storage, substances with similar functional groups form explosive peroxides.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 2807-30-9: KM2800000 LD50/LC50:
CAS# 2807-30-9: Dermal, guinea pig: LD50 = 1 gm/kg; Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, eye: 750 ug/24H Severe; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 1530 ppm/7H; Inhalation, rat: LC50 = 9060 mg/m3; Oral, mouse: LD50 = 1774 mg/kg; Oral, rat: LD50 = 3089 mg/kg; Oral, rat: LD50 = 3090 mg/kg; Skin, rabbit: LD50 = 960 uL/kg.
Oral, rat: LD50 = 1746-10502 mg/kg Carcinogenicity:
2-Propoxyethanol - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Fathead Minnow: >100ul/l; 96hr; LC50Daphnia: Water Flea: >100ul/l; 96hr; LC50

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN XI F
Risk Phrases:
R 10 Flammable.
R 21 Harmful in contact with skin.
R 36 Irritating to eyes.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 2807-30-9: 1
Canada
CAS# 2807-30-9 is listed on Canada's DSL List.
CAS# 2807-30-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2807-30-9 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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