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  Product identifiers
    Product name        : cis-5,8,11,14,17-Eicosapentaenoic acid methyl ester    
    CAS-No.        : 2734-47-6    
  Relevant identified uses of the substance or mixture and uses advised against
    Identified uses        : Laboratory chemicals, Manufacture of substances    

  Classification of the substance or mixture
  Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
    Skin irritation (Category 2)
    Specific target organ toxicity - single exposure (Category 3)
    Aspiration hazard (Category 1)
    Acute aquatic toxicity (Category 1)
    Chronic aquatic toxicity (Category 1)
  Classification according to EU Directives 67/548/EEC or 1999/45/EC
    Harmful: may cause lung damage if swallowed. Irritating to skin. Very toxic to aquatic organisms, may
    cause long-term adverse effects in the aquatic environment. Vapours may cause drowsiness and
  Label elements
  Labelling according Regulation (EC) No 1272/2008 [CLP]
    Signal word        Danger    
    Hazard statement(s)
    H304        May be fatal if swallowed and enters airways.    
    H315        Causes skin irritation.    
    H336        May cause drowsiness or dizziness.    
    H410        Very toxic to aquatic life with long lasting effects.    
    Precautionary statement(s)
    P261        Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.    
    P273        Avoid release to the environment.    
    P301 + P310        IF SWALLOWED: Immediately call a POISON CENTER or doctor/    
    P331        Do NOT induce vomiting.    
    P501        Dispose of contents/ container to an approved waste disposal plant.    
    Supplemental Hazard        none    
  According to European Directive 67/548/EEC as amended.
    Hazard symbol(s)
    R38        Irritating to skin.    
    R50/53        Very toxic to aquatic organisms, may cause long-term adverse effects in    
    the aquatic environment.
    R65        Harmful: may cause lung damage if swallowed.    
    R67        Vapours may cause drowsiness and dizziness.    
    S61        Avoid release to the environment. Refer to special instructions/ Safety    
    data sheets.
    S62        If swallowed, do not induce vomiting: seek medical advice immediately    
    and show this container or label.
    Caution - this mixture contains a substance not yet fully tested.
  Other hazards - none

    Formula        : C21H32O2    
    Molecular Weight        : 316,48 g/mol    
    Component        Classification        Concentration    
    CAS-No.        142-82-5        Flam. Liq. 2; Skin Irrit. 2;        50 - 100 %    
    EC-No.        205-563-8        STOT SE 3; Asp. Tox. 1;    
    Index-No.        601-008-00-2        Aquatic Acute 1; Aquatic    
    Chronic 1; H225, H304, H315,
    H336, H410
    F, Xn, N, R11 - R38 - R65 -
    R67 - R50/53
    For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

  Description of first aid measures
  General advice
    Consult a physician. Show this safety data sheet to the doctor in attendance.
  If inhaled
    If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
  In case of skin contact
    Wash off with soap and plenty of water. Consult a physician.
  In case of eye contact
    Flush eyes with water as a precaution.
  If swallowed
    Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
    water. Consult a physician.
  Most important symptoms and effects, both acute and delayed
    Nausea, Dizziness, Headache, Prolonged or repeated exposure to skin causes defatting and dermatitis.,
    Central nervous system depression, narcosis, Damage to the lungs.
  Indication of any immediate medical attention and special treatment needed
    no data available

  Extinguishing media
  Suitable extinguishing media
    Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
  Special hazards arising from the substance or mixture
    Carbon oxides
  Advice for firefighters
    Wear self contained breathing apparatus for fire fighting if necessary.
  Further information
    no data available

  Personal precautions, protective equipment and emergency procedures
    Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
    Evacuate personnel to safe areas.
  Environmental precautions
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
    environment must be avoided.
  Methods and materials for containment and cleaning up
    Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
    containers for disposal.
  Reference to other sections
    For disposal see section 13.

  Precautions for safe handling
    Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
  Conditions for safe storage, including any incompatibilities
    Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
    opened must be carefully resealed and kept upright to prevent leakage.
    Recommended storage temperature: -20 °C
  Specific end use(s)
    no data available

  Control parameters
  Components with workplace control parameters
  Exposure controls
  Appropriate engineering controls
    Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
    at the end of workday.
  Personal protective equipment
  Eye/face protection
    Face shield and safety glasses Use equipment for eye protection tested and approved under
    appropriate government standards such as NIOSH (US) or EN 166(EU).
  Skin protection
    Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
    (without touching glove's outer surface) to avoid skin contact with this product. Dispose of
    contaminated gloves after use in accordance with applicable laws and good laboratory practices.
    Wash and dry hands.
    The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
    the standard EN 374 derived from it.
  Body Protection
    Complete suit protecting against chemicals, The type of protective equipment must be selected
    according to the concentration and amount of the dangerous substance at the specific workplace.
  Respiratory protection
    Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
    with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
    to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
    respirator. Use respirators and components tested and approved under appropriate government
    standards such as NIOSH (US) or CEN (EU).

  Information on basic physical and chemical properties
    a) Appearance        Form: liquid    
    Colour: clear, colourless
    b) Odour        no data available    
    c) Odour Threshold        no data available    
    d) pH        no data available    
    e) Melting point/freezing        Melting point/range: -91 °C    
    f) Initial boiling point and 98 °C at 1.013 hPa
    boiling range
    g) Flash point        no data available    
    h) Evaporation rate        4,3    
    i) Flammability (solid, gas) no data available
    j) Upper/lower        Upper explosion limit: 6,7 %(V)    
    flammability or        Lower explosion limit: 1,1 %(V)    
    explosive limits
    k) Vapour pressure        53 hPa at 25 °C    
    l) Vapour density        no data available    
    m) Relative density        0,690 g/cm3 at 20 °C    
    n) Water solubility        insoluble    
    o) Partition coefficient: n-        no data available    
    p) Auto-ignition        no data available    
    q) Decomposition        no data available    
    r) Viscosity        no data available    
    s) Explosive properties        no data available    
    t) Oxidizing properties        no data available    
  Other safety information
    no data available

    no data available
  Chemical stability
    no data available
  Possibility of hazardous reactions
    no data available
  Conditions to avoid
    no data available
  Incompatible materials
    Strong bases, Strong oxidizing agents
  Hazardous decomposition products
    Other decomposition products - no data available

  Information on toxicological effects
  Acute toxicity
    no data available
  Skin corrosion/irritation
    no data available
  Serious eye damage/eye irritation
    no data available
  Respiratory or skin sensitization
    no data available
  Germ cell mutagenicity
    no data available
    IARC:        No component of this product present at levels greater than or equal to 0.1% is identified as    
    probable, possible or confirmed human carcinogen by IARC.
  Reproductive toxicity
    no data available
  Specific target organ toxicity - single exposure
    no data available
  Specific target organ toxicity - repeated exposure
    no data available
  Aspiration hazard
    no data available
  Potential health effects
  Inhalation        May be harmful if inhaled. Causes respiratory tract irritation. Vapours may    
    cause drowsiness and dizziness.
  Ingestion        May be harmful if swallowed. Aspiration hazard if swallowed - can enter    
    lungs and cause damage.
  Skin        May be harmful if absorbed through skin. Causes skin irritation.    
  Signs and Symptoms of Exposure
    Nausea, Dizziness, Headache, Prolonged or repeated exposure to skin causes defatting and dermatitis.,
    Central nervous system depression, narcosis, Damage to the lungs.
  Additional Information
    RTECS: Not available

    no data available
  Persistence and degradability
    no data available
  Bioaccumulative potential
    no data available
  Mobility in soil
    no data available
  Results of PBT and vPvB assessment
    no data available
  Other adverse effects
    Very toxic to aquatic life with long lasting effects.

  Waste treatment methods
    Offer surplus and non-recyclable solutions to a licensed disposal company.
  Contaminated packaging
    Dispose of as unused product.

  UN number
    ADR/RID: 1206        IMDG: 1206        IATA: 1206    
  UN proper shipping name
    IATA:        Heptanes    
  Transport hazard class(es)
    ADR/RID: 3        IMDG: 3        IATA: 3    
  Packaging group
    ADR/RID: II        IMDG: II        IATA: II    
  Environmental hazards
    ADR/RID: yes        IMDG Marine Pollutant: yes        IATA: no    
  Special precautions for user
    no data available

    This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
  Safety, health and environmental regulations/legislation specific for the substance or mixture
    no data available
  Chemical Safety Assessment
    no data available

  Text of H-code(s) and R-phrase(s) mentioned in Section 3
    Aquatic Acute        Acute aquatic toxicity    
    Aquatic Chronic        Chronic aquatic toxicity    
    Asp. Tox.        Aspiration hazard    
    Flam. Liq.        Flammable liquids    
    H225        Highly flammable liquid and vapour.    
    H304        May be fatal if swallowed and enters airways.    
    H315        Causes skin irritation.    
    H336        May cause drowsiness or dizziness.    
    H410        Very toxic to aquatic life with long lasting effects.    
    Skin Irrit.        Skin irritation    
    STOT SE        Specific target organ toxicity - single exposure    
    F        Highly flammable    
    N        Dangerous for the environment    
    Xn        Harmful    
    R11        Highly flammable.    
    R38        Irritating to skin.    
    R50/53        Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic    
    R65        Harmful: may cause lung damage if swallowed.    
    R67        Vapours may cause drowsiness and dizziness.    
  Further information
    Copyright 2012 Co. LLC. License granted to make unlimited paper copies for internal use
    The above information is believed to be correct but does not purport to be all inclusive and shall be
    used only as a guide. The information in this document is based on the present state of our knowledge
    and is applicable to the product with regard to appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Corporation and its Affiliates shall not be held
    liable for any damage resulting from handling or from contact with the above product. See
     and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

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