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glyphosine 2439-99-8 MSDS

Section I.Chemical Product and Company Identification
    Chemical Name Glycine-N,N-bis(methylenephosphonic Acid)
    Portland OR
    Synonym        N,N-Bis(phosphonomethyl)glycine, Glyphosine    
    Chemical Formula        HOOCCH2N[CH2P:O(OH)2]2    
    CAS Number        2439-99-8    

Section II.        Composition and Information on Ingredients    
    Chemical Name        CAS Number Percent (%)        TLV/PEL        Toxicology Data    
    Glycine-N,N-bis(methylenephosphonic Acid)        2439-99-8        Min. 97.0 (T) Not available.        Rat LD50 (oral) 3925mg/kg    

Section III. Hazards Identification
    Acute Health Effects        Severely irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system.    
    Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching,
    scaling, reddening, or, occasionally, blistering. Follow safe industrial hygiene practices and always wear proper
    protective equipment when handling this compound.
    CARCINOGENIC EFFECTS : Not available.
    Chronic Health Effects
    MUTAGENIC EFFECTS : Not available.
    TERATOGENIC EFFECTS : Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    There is no known effect from chronic exposure to this product. Repeated or prolonged exposure to this compound is
    not known to aggravate existing medical conditions.

Section IV.        First Aid Measures    
    Eye Contact        Check for and remove any contact lenses. IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping    
    eyelids open. COLD water may be used. DO NOT use an eye ointment. Flush eyes with running water for a minimum of
    15 minutes, occasionally lifting the upper and lower eyelids. Seek medical attention. Treat symptomatically and
    supportively.
    Skin Contact        After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with    
    running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. COLD water
    may be used. Cover the irritated skin with an emollient. Seek medical attention. Treat symptomatically and supportively.
    Wash any contaminated clothing before reusing.
    Inhalation        If the victim is not breathing, perform artificial respiration. Loosen tight clothing such as a collar, tie, belt or waistband. If    
    breathing is difficult, oxygen can be administered. Seek medical attention. Treat symptomatically and supportively.
    Ingestion        INDUCE VOMITING by sticking finger in throat. Lower the head so that the vomit will not reenter the mouth and throat.    
    Loosen tight clothing such as a collar, tie, belt, or waistband. If the victim is not breathing, administer artificial respiration.
    Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material
    was ingested; the absence of such signs, however, is not conclusive. Seek immediate medical attention and, if possible,
    show the chemical label. Treat symptomatically and supportively.

Section V. Fire and Explosion Data
    Not available.
    Combustible.        Auto-Ignition    
    Flammability
    Flammable Limits
    Flash Points        Not available.    
    Not available.
    Combustion Products        These products are toxic carbon oxides (CO, CO 2), nitrogen oxides (NO, NO2), phosphates.    
    Fire Hazards
    No specific information is available regarding the flammability of this compound in the presence of various materials.
    Explosion Hazards        Risks of explosion of the product in presence of mechanical impact: Not available.    
    Risks of explosion of the product in presence of static discharge: Not available.
    No additional information is available regarding the risks of explosion.
    Fire Fighting Media
    SMALL FIRE: Use DRY chemicals, CO 2, water spray or foam.
    LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.
    and Instructions
    Continued on Next Page
    Glycine-N,N-bis(methylenephosphonic Acid)

Section VI.        Accidental Release Measures    
    Spill Cleanup        Severly irritating material.    
    Instructions        In case of a spill and/or a leak, always shut off any sources of ignition, ventilate the area, and exercise caution. Use a    
    shovel to put the material into a convenient waste disposal container. Finish cleaning the spill by rinsing any
    contaminated surfaces with copious amounts of water. Consult federal, state, and/or local authorities for assistance on
    disposal.

Section VII. Handling and Storage
    SEVERLY IRRITANT. Keep away from heat and sources of ignition. Mechanical exhaust required. When not in use,
    Handling and Storage
    tightly seal the container and store in a dry, cool place. Avoid excessive heat and light. DO NOT ingest. DO NOT
    Information
    breathe dust. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice
    immediately and show the container or the label. Treat symptomatically and supportively. Avoid contact with skin and
    eyes.
    Always store away from incompatible compounds such as oxidizing agents.

Section VIII. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below    
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
    airborne contaminants below the exposure limit.
    Personal Protection        Splash goggles. Lab coat. Dust respirator. Boots. Gloves. A MSHA/NIOSH approved respirator must be used to avoid    
    inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
    this product.
    Exposure Limits
    Not available.

Section IX. Physical and Chemical Properties
    Physical state @ 20°C        Powder.        Solubility    
    Soluble in cold water, hot water.
    Not available.
    Specific Gravity
    Molecular Weight        Partition Coefficient    
    263.08        Not available.    
    Boiling Point        Vapor Pressure    
    Not available.        Not available.    
    Melting Point        198°C (388.4°F)        Vapor Density        Not available.    
    Refractive Index        Not available.        Volatility        Not available.    
    Critical Temperature        Not available.        Odor        Not available.    
    Viscosity        Not available.        Taste        Not available.    

Section X.        Stability and Reactivity Data    
    Stability    
This material is stable if stored under proper conditions. (See Section VII for instructions)    
    Conditions of Instability        Avoid excessive heat and light. Slightly corrosive to metals.    
    Incompatibilities
    Reactive with strong oxidizing agents.

Section XI. Toxicological Information
    RTECS Number        MB9120000    
    Routes of Exposure        Eye contact. Inhalation. Ingestion. Skin contact.    
    Toxicity Data        Rat LD50 (oral) 3925mg/kg    
    CARCINOGENIC EFFECTS : Not available.
    Chronic Toxic Effects
    MUTAGENIC EFFECTS : Not available.
    TERATOGENIC EFFECTS : Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    There is no known effect from chronic exposure to this product. Repeated or prolonged exposure to this compound is not
    known to aggravate existing medical conditions.
    Acute Toxic Effects        Severely irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system.    
    Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching,
    scaling, reddening, or, occasionally, blistering. Follow safe industrial hygiene practices and always wear proper
    protective equipment when handling this compound.
    Continued on Next Page
    Glycine-N,N-bis(methylenephosphonic Acid)

Section XII.        Ecological Information    
    Ecotoxicity        Not available.    
    Environmental Fate        Not available.    

Section XIII. Disposal Considerations
    Recycle to process, if possible. Consult your local or regional authorities. You may be able to dissolve or mix material with
    Waste Disposal
    a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all
    federal, state, and local regulations when disposing of this substance.

Section XIV. Transport Information
    DOT Classification        Not a DOT controlled material (United States).    
    PIN Number        Not applicable.    
    Proper Shipping Name
    Not applicable.
    Packing Group (PG)        Not applicable.    
    DOT Pictograms

Section XV. Other Regulatory Information and Pictograms
    TSCA Chemical Inventory        This compound is ON the EPA Toxic Substances Control Act (TSCA) inventory list.    
    (EPA)
    WHMIS Classification
    Not available.
    (Canada)
    EINECS Number (EEC) 219-468-4
    EEC Risk Statements        R36/37/38- Irritating to eyes, respiratory system and skin.    


SECTION 16 - ADDITIONAL INFORMATION
N/A

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