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Butyl glycidyl ether 2426-08-6 MSDS

SECTION 1: Identification of the substance/mixture and of the company/undertaking
  Product identifiers
    Product name        : Butyl glycidyl ether    
    Index-No.        : 603-039-00-7    
    REACH No.        : A registration number is not available for this substance as the substance    
    or its uses are exempted from registration, the annual tonnage does not
    require a registration or the registration is envisaged for a later
    registration deadline.
    CAS-No.        : 2426-08-6    
  Relevant identified uses of the substance or mixture and uses advised against
    Identified uses        : Laboratory chemicals, Manufacture of substances    

SECTION 2: Hazards identification
  Classification of the substance or mixture
  Classification according to Regulation (EC) No 1272/2008
    Flammable liquids (Category 3), H226
    Acute toxicity, Oral (Category 4), H302
    Acute toxicity, Inhalation (Category 3), H331
    Skin corrosion (Category 1B), H314
    Skin sensitisation (Category 1), H317
    Germ cell mutagenicity (Category 2), H341
    Carcinogenicity (Category 1B), H350
    Specific target organ toxicity - single exposure (Category 3), H335
    Chronic aquatic toxicity (Category 3), H412
    For the full text of the H-Statements mentioned in this Section, see Section 16.
  Classification according to EU Directives 67/548/EEC or 1999/45/EC
    T Toxic        R23/24/25    
    T Toxic        R45    
    Xn Harmful        R68    
    Xi Irritant        R43    
    Xi Irritant        R36/37/38    
    For the full text of the R-phrases mentioned in this Section, see Section 16.
  Label elements
  Labelling according Regulation (EC) No 1272/2008
    Signal word        Danger    
    Hazard statement(s)
    H226        Flammable liquid and vapour.    
    H302        Harmful if swallowed.    
    H314        Causes severe skin burns and eye damage.    
    H317        May cause an allergic skin reaction.    
    H331        Toxic if inhaled.    
    H335        May cause respiratory irritation.    
    H341        Suspected of causing genetic defects.    
    H350        May cause cancer.    
    H412        Harmful to aquatic life with long lasting effects.    
    Precautionary statement(s)
    P201        Obtain special instructions before use.    
    P261        Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.    
    P273        Avoid release to the environment.    
    P280        Wear protective gloves/ protective clothing/ eye protection/ face    
    P305 + P351 + P338        IF IN EYES: Rinse cautiously with water for several minutes. Remove    
    contact lenses, if present and easy to do. Continue rinsing.
    P310        Immediately call a POISON CENTER or doctor/ physician.    
    Supplemental Hazard        none    
    Restricted to professional users.
  Other hazards - none

SECTION 3: Composition/information on ingredients
    Synonyms        : Butyl-2,3-epoxypropylether    
    Araldite RD-1
    Formula        : C7H14O2    
    Molecular Weight        : 130,18 g/mol    
    CAS-No.        : 2426-08-6    
    EC-No.        : 219-376-4    
    Index-No.        : 603-039-00-7    
  Hazardous ingredients according to Regulation (EC) No 1272/2008
    Component        Classification        Concentration    
  Butyl glycidyl ether
    CAS-No.        2426-08-6        Skin Sens. 1; Flam. Liq. 3;        <= 100 %    
    EC-No.        219-376-4        Carc. 2; Muta. 2; Acute Tox. 4;    
    Index-No.        603-039-00-7        STOT SE 3; Aquatic Chronic    
    3; H226, H302, H317, H332,
    H335, H341, H351, H412
    CAS-No.        106-89-8        Flam. Liq. 3; Acute Tox. 3;        5 - 10 %    
    EC-No.        203-439-8        Skin Corr. 1B; Skin Sens. 1;    
    Index-No.        603-026-00-6        Carc. 1B; H226, H301 + H311    
    Registration number        01-2119457436-33-XXXX        + H331, H314, H317, H350    
  Hazardous ingredients according to Directive 1999/45/EC
    Component        Classification        Concentration    
  Butyl glycidyl ether
    CAS-No.        2426-08-6        Xn, Carc.Cat.3, Mut.Cat.3,        <= 100 %    
    EC-No.        219-376-4        R10 - R20/22 - R37 - R40 -    
    Index-No.        603-039-00-7        R43 - R52/53 - R68    
    CAS-No.        106-89-8        T, Carc.Cat.2, R45 - R10 -        5 - 10 %    
    EC-No.        203-439-8        R23/24/25 - R34 - R43    
    Index-No.        603-026-00-6    
    Registration number        01-2119457436-33-XXXX    
    For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

SECTION 4: First aid measures
  Description of first aid measures
  General advice
    Consult a physician. Show this safety data sheet to the doctor in attendance.
  If inhaled
    If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
  In case of skin contact
    Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take
    victim immediately to hospital. Consult a physician.
  In case of eye contact
    Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
  If swallowed
    Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
    water. Consult a physician.
  Most important symptoms and effects, both acute and delayed
    The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
    section 11
  Indication of any immediate medical attention and special treatment needed
    no data available

SECTION 5: Firefighting measures
  Extinguishing media
  Suitable extinguishing media
    Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
  Special hazards arising from the substance or mixture
    Carbon oxides, Hydrogen chloride gas
  Advice for firefighters
    Wear self contained breathing apparatus for fire fighting if necessary.
  Further information
    Use water spray to cool unopened containers.

SECTION 6: Accidental release measures
  Personal precautions, protective equipment and emergency procedures
    Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove
    all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form
    explosive concentrations. Vapours can accumulate in low areas.
    For personal protection see section 8.
  Environmental precautions
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
    environment must be avoided.
  Methods and materials for containment and cleaning up
    Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and
    place in container for disposal according to local regulations (see section 13).
  Reference to other sections
    For disposal see section 13.

SECTION 7: Handling and storage
  Precautions for safe handling
    Avoid exposure - obtain special instructions before use.Avoid contact with skin and eyes. Avoid inhalation
    of vapour or mist.
    Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
    For precautions see section 2.2.
  Conditions for safe storage, including any incompatibilities
    Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
    opened must be carefully resealed and kept upright to prevent leakage.
    Air, light, and moisture sensitive.
  Specific end use(s)
    Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection
  Control parameters
  Components with workplace control parameters
  Exposure controls
  Appropriate engineering controls
    Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling
    the product.
  Personal protective equipment
  Eye/face protection
    Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection
    tested and approved under appropriate government standards such as NIOSH (US) or EN
  Skin protection
    Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
    (without touching glove's outer surface) to avoid skin contact with this product. Dispose of
    contaminated gloves after use in accordance with applicable laws and good laboratory practices.
    Wash and dry hands.
    The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
    the standard EN 374 derived from it.
    Splash contact
    Material: butyl-rubber
    Minimum layer thickness: 0,3 mm
    Break through time: 60 min
    Material tested:Butoject® (KCL 897 / Z677647, Size M)
    data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300,     test method: EN374
    If used in solution, or mixed with other substances, and under conditions which differ from EN 374,
    contact the supplier of the CE approved gloves. This recommendation is advisory only and must
    be evaluated by an industrial hygienist and safety officer familiar with the specific situation of
    anticipated use by our customers. It should not be construed as offering an approval for any
    specific use scenario.
  Body Protection
    Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type
    of protective equipment must be selected according to the concentration and amount of the
    dangerous substance at the specific workplace.
  Respiratory protection
    Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
    with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
    to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
    respirator. Use respirators and components tested and approved under appropriate government
    standards such as NIOSH (US) or CEN (EU).
  Control of environmental exposure
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
    the environment must be avoided.

SECTION 9: Physical and chemical properties
  Information on basic physical and chemical properties
    a) Appearance        Form: clear, liquid    
    Colour: colourless
    b) Odour        no data available    
    c) Odour Threshold        no data available    
    d) pH        no data available    
    e) Melting point/freezing        no data available    
    f) Initial boiling point and 164 - 166 °C - lit.
    boiling range
    g) Flash point        54 °C - closed cup    
    h) Evapouration rate        no data available    
    i) Flammability (solid, gas) no data available
    j) Upper/lower        no data available    
    flammability or
    explosive limits
    k) Vapour pressure        3,99 hPa at 20 °C    
    l) Vapour density        no data available    
    m) Relative density        0,91 g/mL at 25 °C    
    n) Water solubility        no data available    
    o) Partition coefficient: n- no data available
    p) Auto-ignition        no data available    
    q) Decomposition        no data available    
    r) Viscosity        no data available    
    s) Explosive properties        no data available    
    t) Oxidizing properties        no data available    
  Other safety information
    no data available

SECTION 10: Stability and reactivity
    no data available
  Chemical stability
    Stable under recommended storage conditions.
  Possibility of hazardous reactions
    no data available
  Conditions to avoid
    Heat, flames and sparks.
  Incompatible materials
    no data available
  Hazardous decomposition products
    Other decomposition products - no data available
    In the event of fire: see section 5

SECTION 11: Toxicological information
  Information on toxicological effects
  Acute toxicity
    no data available
  Skin corrosion/irritation
    no data available
  Serious eye damage/eye irritation
    no data available
  Respiratory or skin sensitisation
    no data available
  Germ cell mutagenicity
    no data available
    IARC:        2A - Group 2A: Probably carcinogenic to humans (Epichlorhydrin)    
  Reproductive toxicity
    no data available
  Specific target organ toxicity - single exposure
    no data available
  Specific target organ toxicity - repeated exposure
    no data available
  Aspiration hazard
    no data available
  Additional Information
    RTECS: TX4200000

SECTION 12: Ecological information
    no data available
  Persistence and degradability
    no data available
  Bioaccumulative potential
    no data available
  Mobility in soil
    no data available
  Results of PBT and vPvB assessment
    PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
  Other adverse effects
    Harmful to aquatic life.

SECTION 13: Disposal considerations
  Waste treatment methods
    Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting
    as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal
  Contaminated packaging
    Dispose of as unused product.

SECTION 14: Transport information
  UN number
    ADR/RID: 3271        IMDG: 3271        IATA: 3271    
  UN proper shipping name
    IATA:        Ethers, n.o.s.    
  Transport hazard class(es)
    ADR/RID: 3        IMDG: 3        IATA: 3    
  Packaging group
    ADR/RID: III        IMDG: III        IATA: III    
  Environmental hazards
    ADR/RID: no        IMDG Marine pollutant: no        IATA: no    
  Special precautions for user
    no data available

SECTION 15: Regulatory information
    This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
  Safety, health and environmental regulations/legislation specific for the substance or mixture
    no data available
  Chemical Safety Assessment
    For this product a chemical safety assessment was not carried out

SECTION 16: Other information
  Full text of H-Statements referred to under sections 2 and 3.
    Acute Tox.        Acute toxicity    
    Aquatic Chronic        Chronic aquatic toxicity    
    Carc.        Carcinogenicity    
    Flam. Liq.        Flammable liquids    
    H226        Flammable liquid and vapour.    
    H301 + H311 +        Toxic if swallowed, in contact with skin or if inhaled    
    H302        Harmful if swallowed.    
    H314        Causes severe skin burns and eye damage.    
    H317        May cause an allergic skin reaction.    
    H331        Toxic if inhaled.    
    H332        Harmful if inhaled.    
    H335        May cause respiratory irritation.    
    H341        Suspected of causing genetic defects.    
    H350        May cause cancer.    
    H351        Suspected of causing cancer.    
    H412        Harmful to aquatic life with long lasting effects.    
    Muta.        Germ cell mutagenicity    
    Skin Corr.        Skin corrosion    
    Skin Sens.        Skin sensitisation    
    STOT SE        Specific target organ toxicity - single exposure    
  Full text of R-phrases referred to under sections 2 and 3
    T        Toxic    
    R10        Flammable.    
    R20/22        Harmful by inhalation and if swallowed.    
    R23/24/25        Toxic by inhalation, in contact with skin and if swallowed.    
    R34        Causes burns.    
    R36/37/38        Irritating to eyes, respiratory system and skin.    
    R37        Irritating to respiratory system.    
    R40        Limited evidence of a carcinogenic effect.    
    R43        May cause sensitisation by skin contact.    
    R45        May cause cancer.    
    R52/53        Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic    
    R68        Possible risk of irreversible effects.    
    Xn        Harmful    
  Further information
    Copyright 2014 Co. LLC. License granted to make unlimited paper copies for internal use
    The above information is believed to be correct but does not purport to be all inclusive and shall be
    used only as a guide. The information in this document is based on the present state of our knowledge
    and is applicable to the product with regard to appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Corporation and its Affiliates shall not be held
    liable for any damage resulting from handling or from contact with the above product. See
     and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

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