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propan-1-olate,zirconium(4+) 23519-77-9 MSDS
  Zirconium(IV) Propoxide (ca. 70% in 1-Propanol)      Revision number: 6    
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        Zirconium(IV) Propoxide (ca. 70% in 1-Propanol)    
    
  Revision number:        6    

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS
    Category 3
  Flammable liquids
  HEALTH HAZARDS
    Category 5
  Acute toxicity (Oral)
  Acute toxicity (Dermal)        Category 5    
    Category 2
  Skin corrosion/irritation
  Serious eye damage/eye irritation        Category 1    
    Category 2
  Carcinogenicity
  Reproductive toxicity        Category 2    
    Respiratory tract irritation, Narcotic effects
  Specific target organ toxicity
  - Single exposure [Category 3]
    Category 2
  Aspiration hazard
  ENVIRONMENTAL HAZARDS        Not classified    
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
    Danger
  Signal word
  Hazard statements        Flammable liquid and vapour    
    May be harmful if swallowed or in contact with skin
    Causes skin irritation
    Causes serious eye damage
    Suspected of causing cancer
    Suspected of damaging fertility or the unborn child
    May cause respiratory irritation
    May cause drowsiness or dizziness
    May be harmful if swallowed and enters airways
  Precautionary statements:
  Zirconium(IV) Propoxide (ca. 70% in 1-
  Propanol)

Section 2. HAZARDS IDENTIFICATION
  [Prevention]        Obtain special instructions before use.    
    Do not handle until all safety precautions have been read and understood.
    Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
    Keep container tightly closed.
    Use explosion-proof electrical/ventilating/lighting equipment. Take precautionary
    measures against ignition by the static discharge and the spark.
    Avoid breathing dust/fume/gas/mist/vapours/spray.
    Use only outdoors or in a well-ventilated area.
    Wash hands thoroughly after handling.
    Wear protective gloves/eye protection/face protection.
  [Response]        IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for    
    breathing.
    IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT
    induce vomiting.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
    skin with water/shower.
    If skin irritation occurs: Get medical advice/attention.
    Take off contaminated clothing and wash before reuse.
    Immediately call a POISON CENTER or doctor/physician.
  [Storage]        Store in a well-ventilated place. Keep container tightly closed.    
    Store locked up.
  [Disposal]        Dispose of contents/container through a waste management company authorized by    
    the local government.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Mixture    
  Components:        Zirconium(IV) Propoxide (ca. 70% in 1-Propanol)    
    ....
  Percent:
  CAS Number:        23519-77-9    
    Zirconium(IV) Tetrapropoxide (ca. 70% in 1-Propanol)
  Synonyms:
  Chemical Formula:        C12H28O4Zr    

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.    
    Immediately call a POISON CENTER or doctor/physician.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of    
    soap and water. Immediately call a POISON CENTER or doctor/physician.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present    
    and easy to do. Continue rinsing.Immediately call a POISON CENTER or
    doctor/physician.
    Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT
  Ingestion:
    induce vomiting.
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-    
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.    
  media:
  Unsuitable extinguishing Solid streams of water
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
    generate poisonous fume.
  from the chemical:
  Zirconium(IV) Propoxide (ca. 70% in 1-
  Propanol)

Section 5. FIRE-FIGHTING MEASURES
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by
    spraying with water. Eliminate all ignition sources if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.    
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use extra personal protective equipment (self-contained breathing apparatus). Keep
  Personal precautions,
  protective equipment and people away from and upwind of spill/leak. Ensure adequate ventilation. Entry to non-
  emergency procedures: involved personnel should be controlled around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Absorb spilled material in dry sand or inert absorbent before recovering it into an
  containment and cleaning airtight container. In case of large amount of spillage, contain a spill by bunding.
  up: Adhered or collected material should be promptly disposed of, in accordance with
    appropriate laws and regulations.
  Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in
  hazards:        case of a fire. Use spark-proof tools and explosion-proof equipment.    

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.    
    Prevent generation of vapour or mist. Keep away from heat/sparks/open flame/hot
    surfaces. -No smoking. Take measures to prevent the build up of electrostatic
    charge. Use explosion-proof equipment. Wash hands and face thoroughly after
    handling.
    Use a closed system if possible. Use a ventilation, local exhaust if vapour or aerosol
    will be generated.
  Advice on safe handling: Avoid all contact!
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool, dark and well-ventilated place.    
    Store under inert gas.
    Protect from moisture.
    Store locked up.
    Store away from incompatible materials such as oxidizing agents.
    Moisture-sensitive
    Comply with laws.
  Packaging material:

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust. Also install safety shower and eye bath.    
  Exposure limits:        (1-Propanol)    
    ACGIH TLV(TWA):100 ppm
    OSHA PEL(TWA):200 ppm
  Personal protective equipment
  Respiratory protection: Half or full facepiece respirator, self-contained breathing apparatus(SCBA), supplied
    air respirator, etc. Use respirators approved under appropriate government standards
    and follow local and national regulations.
  Hand protection:        Impervious gloves.    
  Eye protection:        Safety goggles. A face-shield, if the situation requires.    
  Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Liquid    
  Form:        Clear    
  Colour:        Very pale yellow - Yellow    
  Zirconium(IV) Propoxide (ca. 70% in 1-
  Propanol)

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Odour:        No data available    
  pH: No data available
  Melting point/freezing point:No data available
    (1-Propanol) -127°C
  Boiling point/range:        No data available    
    (1-Propanol) 97°C
  Flash point:        28°C    
  Flammability or explosive
  limits:
  Lower:        No data available    
  Upper:        No data available    
  Relative density:        1.04    
  Solubility(ies):
  [Water]        No data available    
  [Other solvents]
  Soluble:        Alcohols, Toluene    
  Log Pow:        (1-Propanol) 0.25    

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.    
  Possibility of hazardous No special reactivity has been reported.
  reactions:
    Spark, Open flame, Static discharge
  Conditions to avoid:
  Incompatible materials: Oxidizing agents, Acids
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Zirconium oxides
  products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available    
    (1-Propanol)
    orl-wmn LDLo:5700 mg/kg
    orl-rat LD50:1870 mg/kg
    skn-rbt LD50:5040 mg/kg
    ihl-rat LCLo:4000 ppm/4H
  Skin corrosion/irritation: No data available
    (1-Propanol)
    skn-hmn 100 %/24H MLD
    skn-rbt 500 mg open MLD
  Serious eye        No data available    
  damage/irritation:
    (1-Propanol)
    eye-rbt 20 mg/24H MOD
  Germ cell mutagenicity: No data available
    (1-Propanol)
    mmo-esc 4 pph (-S9)
    sln-asn 18000 ppm
  Carcinogenicity:
    No data available
  IARC =
  NTP =        No data available    
    (1-Propanol)
    orl-rat TDLo:50 g/kg/81W-I
    scu-rat TDLo:6 g/kg/95W-I
  Reproductive toxicity:        No data available    

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Zirconium(IV) Propoxide (ca. 70% in 1-
  Propanol)

Section 12. ECOLOGICAL INFORMATION
  Fish:        No data available    
  Crustacea:        No data available    
  Algae:        No data available    
  Persistence / degradability: No data available
  Bioaccumulative        No data available    
  potential(BCF):
  Mobility in soil
    No data available
  Log Pow:
  Soil adsorption (Koc):        No data available    
  Henry's Law        No data available    
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
    incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
    disposing of the substance.

Section 14. TRANSPORT INFORMATION
    3: Flammable liquid.
  Hazards Class:
  UN-No:        1274    
  Proper shipping name:        n-Propanol solution    
  Packing group:        III    

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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