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Potassium hexachloroplatinate(IV)
CAS No.: 16921-30-5
Synonyms:
Formula: ClKPt
Exact Mass: 268.89700
Molecular Weight: 269.62900
PSA: 0.00000
LogP: 0.68700
Reference Price: $4,317/kg Inquiry Now
Potassium hexachloroplatinate(IV) 16921-30-5 MSDS
Name: Platinium (IV) potassium chloride Material Safety Data Sheet
Synonym: Potassium chloroplatinate; Potassium platinichloride; Platinate(2-), hexachloro-, dipotassium,(oc-6-11)-
CAS: 16921-30-5
Section 1 - Chemical Product   MSDS Name:Platinium (IV) potassium chloride Material Safety Data Sheet
Synonym:Potassium chloroplatinate; Potassium platinichloride; Platinate(2-), hexachloro-, dipotassium,(oc-6-11)-

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
16921-30-5 Platinium (IV) potassium chloride 100 240-979-3
Hazard Symbols: T
Risk Phrases: 25 41 42/43

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Toxic if swallowed. Risk of serious damage to eyes. May cause sensitization by inhalation and skin contact.
Potential Health Effects
Eye:
Causes eye irritation and possible burns. Risk of serious damage to eyes.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
May cause liver and kidney damage. May cause effects similar to those of acute inhalation.
Inhalation:
May cause cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood). May cause respiratory tract irritation.
May cause asthma and shortness of breath. May cause respiratory sensitization.
Chronic:
May cause liver and kidney damage.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Store protected from light.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 16921-30-5: United States OSHA: 0.002 mg/m3 TWA (as Pt) (listed under Platin soluble salts).
Belgium - TWA: (listed as platinum soluble salts): 0.002 mg/m3 VL (as Pt) Japan: (listed as platinum soluble salts): 0.001 mg/m3 OEL (as Pt Malaysia: (listed as platinum soluble salts): 0.002 mg/m3 TWA (as Netherlands: (listed as platinum soluble salts): 0.002 mg/m3 MAC Pt) Personal Protective Equipment Eyes: Wear safety glasses and chemical goggles if splashing is possible.
Skin:
Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystalline powder
Color: yellow orange
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: decomposes
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 250 C
Solubility in water: Soluble in hot water. Slt. sol in cold.
Specific Gravity/Density: 3.4990
Molecular Formula: K2PtCl6
Molecular Weight: 485.9946

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Metals, strong oxidizing agents, Corrosive to steel and aluminum..
Hazardous Decomposition Products:
Hydrogen chloride, chlorine.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 16921-30-5: TP1650000 LD50/LC50:
Not available.
Oral, rat LD50: 195 mg/kg.
Carcinogenicity:
Platinium (IV) potassium chloride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S
Hazard Class: 6.1
UN Number: 3290
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S
Hazard Class: 6.1
UN Number: 3290
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S
Hazard Class: 6.1
UN Number: 3290
Packing group: II

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 25 Toxic if swallowed.
R 41 Risk of serious damage to eyes.
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 16921-30-5: 2
Canada
CAS# 16921-30-5 is listed on Canada's DSL List.
CAS# 16921-30-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 16921-30-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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