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(S)-(-)-Propylene oxide
CAS No.: 16088-62-3
Synonyms:
Formula: C3H6O
Exact Mass: 58.04190
Molecular Weight: 58.07910
PSA: 12.53000
LogP: 0.40510
Reference Price: $251/L Inquiry Now
(S)-(-)-Propylene oxide 16088-62-3 MSDS
Name: (s)-(-)-Propylene Oxide 99% Material Safety Data Sheet
Synonym: 1,2-Epoxypropane; Methyloxiran
CAS: 16088-62-3
Section 1 - Chemical Product   MSDS Name:(s)-(-)-Propylene Oxide 99% Material Safety Data Sheet
Synonym:1,2-Epoxypropane; Methyloxiran

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
16088-62-3 (S)-(-)-Propylene oxide 99% 240-241-0
Hazard Symbols: T F+
Risk Phrases: 12 20/21/22 36/37/38 45

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Extremely flammable. Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. May cause cancer.Toxic.Cancer suspect agent.
Potential Health Effects
Eye:
Causes severe eye irritation. May cause eye burns.
Skin:
Causes severe skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause skin burns. May cause severe pain, swelling, tissue destruction, and possible shock. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Dust is irritating to the respiratory tract. Causes respiratory tract irritation. Causes irritation of mucous membrane.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic inhalation may cause effects similar to those of acute inhalation.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Extremely flammable liquid and vapor.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry chemical, or carbon dioxide. Water may be ineffective.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Do not ingest or inhale. Use only in a chemical fume hood. This product may be under pressure; cool before opening. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Loosen closure cautiously before opening.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use only under a chemical fume hood.
Exposure Limits CAS# 16088-62-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: APHA: 5 max
Odor: Ether-like odor.
pH: Not available.
Vapor Pressure: 585 hPa @ 20 deg C
Viscosity: 0.32 mPas 20 deg C
Boiling Point: 34 deg C @ 760.00mm Hg
Freezing/Melting Point: -112 deg C
Autoignition Temperature: 449 deg C ( 840.20 deg F)
Flash Point: -35 deg F ( -37.22 deg C)
Explosion Limits, lower: 2.3%
Explosion Limits, upper: 36.0%
Decomposition Temperature:
Solubility in water: 40G/100ML (20C)
Specific Gravity/Density: .8300g/cm3
Molecular Formula: C3H6O
Molecular Weight: 58.08

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Acids; bases; oxidizing agents; copper and copper alloys; ethylene oxide and polyhydric alcohols; epoxy resin and sodium hydroxide, ammonium hydroxide, hydrochloric acid, hydrofluoric acid, and nitric acid..
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 16088-62-3: UJ2651000 LD50/LC50:
Not available.
Carcinogenicity:
(S)-(-)-Propylene oxide - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: PROPYLENE OXIDE
Hazard Class: 3
UN Number: 1280
Packing Group: I
IMO
Shipping Name: PROPYLENE OXIDE
Hazard Class: 3.1
UN Number: 1280
Packing Group: I
RID/ADR
Shipping Name: PROPYLENE OXIDE
Hazard Class: 3
UN Number: 1280
Packing group: I

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F+
Risk Phrases:
R 45 May cause cancer.
R 12 Extremely flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 16088-62-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 16088-62-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 16088-62-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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