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(S)-2-methylbutan-1-ol 1565-80-6 MSDS
Name: Prim. active amyl alcohol 99% Material Safety Data Sheet
Synonym: l-(-)-2-Methyl-1-butanol; S(-)-2-Methyl-1-butanol
CAS: 1565-80-6
Section 1 - Chemical Product   MSDS Name:Prim. active amyl alcohol 99% Material Safety Data Sheet
Synonym:l-(-)-2-Methyl-1-butanol; S(-)-2-Methyl-1-butanol

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1565-80-6 prim. active Amyl alcohol 99% 216-366-1
Hazard Symbols: XN
Risk Phrases: 10 20

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Harmful by inhalation.Harmful.Flammable liquid.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May be harmful if swallowed.
Inhalation:
Harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Flammable liquid and vapor.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.

Section 7 - HANDLING and STORAGE
  Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Take precautionary measures against static discharges.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 1565-80-6: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 4.5 hPa @ 25 deg C
Viscosity: 5.1 mPas 20 deg C
Boiling Point: 128 deg C @ 760.00mm Hg
Freezing/Melting Point: -70 deg C
Autoignition Temperature: 400 deg C ( 752.00 deg F)
Flash Point: 43 deg C ( 109.40 deg F)
Explosion Limits, lower: 1.20 vol %
Explosion Limits, upper: 8.00 vol %
Decomposition Temperature:
Solubility in water: SOLUBLE IN WATER: 36 G/L (30C)
Specific Gravity/Density: .8190g/cm3
Molecular Formula: C5H12O
Molecular Weight: 88.15

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, ignition sources, temperatures above 40C.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 1565-80-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
prim. active Amyl alcohol - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish-toxicity: LC0(24H) creek chub 350 mg/l; LC100(24H) creek chub 500 mg/l; LC50(96H) fathead minnow 470 mg/l; LC50(96H) zebra fish 530 mg/l; LC50(48H) ide 479-492 mg/l (Code of Federal Regulations 1984,49,172.102)( Blum, D.J.W;et al.Res.J.Water.Pollut.Control Fed.1991,63(3), 198-207)(Wellens, H.Z. Wasser Abwasser Forsch.1982,15,49) Invertebrate toxicity: LC50(48H)Daphnia magna 440 mg/l; EC50(5 min,30 min)Photobacterium phosphoreum 394 mg/l Microtox test. (Verschueren, K. Handbook of Environmental Data on Organic Chemicals 2nd ed.,1983, Van Nostrand Reinhold, New York)

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: AMYL ALCOHOLS
Hazard Class: 3
UN Number: 1105
Packing Group: III
IMO
Shipping Name: AMYL ALCOHOLS
Hazard Class: 3.3
UN Number: 1105
Packing Group: III
RID/ADR
Shipping Name: AMYL ALCOHOLS
Hazard Class: 3
UN Number: 1105
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20 Harmful by inhalation.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1565-80-6: No information available.
Canada
CAS# 1565-80-6 is listed on Canada's DSL List.
CAS# 1565-80-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1565-80-6 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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