|1,2-Bis(diphenylphosphino)ethane nickel(II) chloride|
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|Name:||1 2-Bis(diphenylphosphino)ethane nickel(II) chloride Material Safety Data Sheet|
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 40
Section 3 - HAZARDS IDENTIFICATION
Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect.
Potential Health Effects
Causes eye irritation.
Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
May cause irritation of the digestive tract. May be harmful if swallowed.
Causes respiratory tract irritation. May be harmful if inhaled.
Symptoms of overexposure to nickel can cause sensitization, dermatitis, allergic asthma and pneumonitis.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid. Wash mouth out with water.
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation.
Section 7 - HANDLING and STORAGE
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid breathing dust.
Store in a cool, dry place. Store in a tightly closed container.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 14647-23-5: United States OSHA: 1 mg/m3 TWA (as Ni) (listed under Nickel insoluble compounds).
Belgium - TWA: (listed as nickel insoluble compounds): 1 mg/m3 VL (as Ni) Malaysia: (listed as nickel insoluble compounds): 0.2 mg/m3 TWA (inhalable fraction, as Ni) Spain: (listed as nickel insoluble compounds): 0.2 mg/m3 VLA-ED ( Ni) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Crystals
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 263 - 265 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Solubility in water: Insoluble.
Molecular Formula: C26H24Cl2NiP2
Molecular Weight: 528.04
Section 10 - STABILITY AND REACTIVITY
Conditions to Avoid:
Incompatibilities with Other Materials:
Oxidizing agents, halogens, active metals.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of phosphorus, carbon dioxide, nickel oxide.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
CAS# 14647-23-5 unlisted.
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride - California: carcinogen, initial date 5/7/04 (listed as Nickel compound NTP: Known carcinogen (listed as Nickel compounds).
IARC: Group 1 carcinogen (listed as Nickel compounds).
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
Not regulated as a hazardous material.
Not regulated as a hazardous material.
No information available.
Section 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
R 36/37/38 Irritating to eyes, respiratory system
R 40 Limited evidence of a carcinogenic effect.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
WGK (Water Danger/Protection)
CAS# 14647-23-5: No information available.
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 14647-23-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 14647-23-5 is not listed on the TSCA inventory.
It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION