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HYDRAZINE MONOHYDROBROMIDE
CAS No.: 13775-80-9
Synonyms:
Formula: BrH5N2
Exact Mass: 111.96400
Molecular Weight: 112.95700
PSA: 52.04000
LogP: 1.17750
Reference Price: $420/kg Inquiry Now
HYDRAZINE MONOHYDROBROMIDE 13775-80-9 MSDS

Section I.Chemical Product and Company Identification
    Chemical Name Hydrazine Monohydrobromide
    Portland OR
    Synonym        Hydrazine, hydrobromide (1:1) (CA INDEX NAME);    
    Hydrazinium Monobromide
    H4N2•HBr
    Chemical Formula
    CAS Number        13775-80-9    

Section II.        Composition and Information on Ingredients    
    Toxicology Data
    Chemical Name        CAS Number Percent (%)        TLV/PEL    
    This chemical is classified as a Not available.
    Hydrazine Monohydrobromide        13775-80-9        Min. 98.0 (T)    
    possible carcinogen. There is
    no acceptable exposure limit for
    a carcinogen.
    This compound is classified as
    a possible mutagen. There is
    no acceptable exposure limit for
    a mutagen.

Section III. Hazards Identification
    Toxic if ingested or inhaled. Avoid prolonged contact with this material. Overexposure may result in serious illness or death.
    Acute Health Effects
    Corrosive to skin, eyes, and respiratory system. Liquid or spray mist may produce tissue damage, particularly in mucous
    membranes of the eyes, mouth and respiratory tract. Skin contact may produce burns. Eye contact can result in corneal
    damage or blindness. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
    coughing, choking, or shortness of breath. Corrosive materials may cause serious injury if ingested.
    Skin contact may result in sensitization. Always cover all exposed skin with an impermeable layer and use proper eye
    protection. A OSHA/MSHA approved dust and vapor respirator is required when working with this material.
    Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.
    CARCINOGENIC EFFECTS : Not available.
    Chronic Health Effects
    MUTAGENIC EFFECTS : Not available.
    TERATOGENIC EFFECTS : Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local
    skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung
    damage. Repeated exposure to an highly toxic material may produce general deterioration of health by an accumulation in
    one or many human organs.

Section IV.        First Aid Measures    
    Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
    Eye Contact
    minutes. Get medical attention.
    In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
    Skin Contact
    and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
    Inhalation        If the victim is not breathing, perform mouth-to-mouth resuscitation. Loosen tight clothing such as a collar, tie, belt or    
    waistband. If breathing is difficult, oxygen can be administered. Seek medical attention if respiration problems do not
    improve.
    Ingestion        DO NOT INDUCE VOMITING. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing,    
    perform mouth-to-mouth resuscitation. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible
    indication that the toxic material was ingested; the absence of such signs, however, is not conclusive.
    Continued on Next Page
    Hydrazine Monohydrobromide

Section V.        Fire and Explosion Data    
    Not available.
    Flammability        May be combustible at high temperature.        Auto-Ignition    
    Flammable Limits        Not available.    
    Flash Points        Not available.    
    Combustion Products        These products include nitrogen oxides (NOx), halogenated compounds.    
    Fire Hazards
    Not available.
    Risks of explosion of the product in presence of mechanical impact: Not available.
    Explosion Hazards
    Risks of explosion of the product in presence of static discharge: Not available.
    Fire Fighting Media
    SMALL FIRE: Use DRY chemical powder.
    LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.
    and Instructions
    Consult with local fire authorities before attempting large scale fire-fighting operations.

Section VI.        Accidental Release Measures    
    Toxic material. Corrosive material. This material is a skin sensitizer. Possibly carcinogenic material. Possibly mutagenic
    Spill Cleanup
    material. Hygroscopic material. Heat and shock sensitive material. Light sensitive material.
    Instructions
    Stop leak if without risk. DO NOT get water inside container. DO NOT touch spilled material. Use water spray to reduce
    vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all sources of ignition. Consult
    federal, state, and/or local authorities for assistance on disposal.

Section VII. Handling and Storage
    Handling and Storage        TOXIC. CORROSIVE. SENSITIZER. POSSIBLE CARCINOGEN. POSSIBLE MUTAGEN. HYGROSCOPIC. HEAT AND    
    SHOCK SENSITIVE. LIGHT SENSITIVE. Keep locked up.. Keep container dry. Keep away from heat. Mechanical exhaust
    Information
    required. When not in use, tightly seal the container and store in a dry, cool place. Avoid excessive heat and light. DO NOT
    ingest. Do not breathe dust. Never add water to this product. Wear suitable protective clothing. If ingested, seek medical
    advice immediately and show the container or the label. Treat symptomatically and supportively.
    Always store away from incompatible compounds such as oxidizing agents, alkalis (bases), moisture.

Section VIII. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended    
    exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
    below the exposure limit.
    Face shield. Lab coat. Dust respirator. Boots. Gloves. A MSHA/NIOSH approved respirator must be used to avoid
    Personal Protection
    inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
    product.
    This chemical is classified as a possible carcinogen. There is no acceptable exposure limit for a carcinogen.
    Exposure Limits
    This compound is classified as a possible mutagen. There is no acceptable exposure limit for a mutagen.

Section IX. Physical and Chemical Properties
    Physical state @ 20°C        Solid. (White crystalline powder.)        Solubility        Soluble in water.    
    Not available.
    Specific Gravity
    Molecular Weight        112.96        Partition Coefficient        Not available.    
    Boiling Point        Not available.        Not applicable.    
    Vapor Pressure
    Melting Point        88°C (190.4°F)        Vapor Density        Not available.    
    Not available.        Not available.    
    Refractive Index        Volatility    
    Critical Temperature        Not available.        Odor        Not available.    
    Not available.        Not available.    
    Viscosity        Taste    

Section X.        Stability and Reactivity Data    
    Stability    
This material is stable if stored under proper conditions. (See Section VII for instructions)    
    Conditions of Instability        Avoid excessive heat and light. Moisture sensitive. Hygroscopic; keep container tightly closed.    
    Incompatibilities        Reactive with oxidizing agents, alkalis (bases), moisture.    
    Continued on Next Page
    Hydrazine Monohydrobromide

Section XI.        Toxicological Information    
    RTECS Number        Not available.    
    Eye Contact. Ingestion. Inhalation. Skin contact.
    Routes of Exposure
    Toxicity Data        Not available.    
    CARCINOGENIC EFFECTS : Not available.
    Chronic Toxic Effects
    MUTAGENIC EFFECTS : Not available.
    TERATOGENIC EFFECTS : Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local
    skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung
    damage. Repeated exposure to an highly toxic material may produce general deterioration of health by an accumulation in
    one or many human organs.
    Toxic if ingested or inhaled. Avoid prolonged contact with this material. Overexposure may result in serious illness or death.
    Acute Toxic Effects
    Corrosive to skin, eyes, and respiratory system. Liquid or spray mist may produce tissue damage, particularly in mucous
    membranes of the eyes, mouth and respiratory tract. Skin contact may produce burns. Eye contact can result in corneal
    damage or blindness. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
    coughing, choking, or shortness of breath. Corrosive materials may cause serious injury if ingested.
    Skin contact may result in sensitization. Always cover all exposed skin with an impermeable layer and use proper eye
    protection. A OSHA/MSHA approved dust and vapor respirator is required when working with this material.
    Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.

Section XII.        Ecological Information    
    Ecotoxicity        Not available.    
    Not available.
    Environmental Fate

Section XIII. Disposal Considerations
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a
    Waste Disposal
    combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all
    federal, state and local regulations when disposing of the substance.

Section XIV. Transport Information
    DOT CLASS 6.1: Toxic material.
    DOT Classification
    DOT CLASS 8: Corrosive material
    PIN Number
    Proper Shipping Name        Toxic solid, corrosive, inorganic, n.o.s.    
    Packing Group (PG)        II    
    DOT Pictograms

Section XV. Other Regulatory Information and Pictograms
    TSCA Chemical Inventory        This compound is ON the EPA Toxic Substances Control Act (TSCA) inventory list.    
    (EPA)
    WHMIS Classification        CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC).    
    CLASS E: Corrosive solid.
    (Canada)
    On NDSL.
    EINECS Number (EEC) 237-412-7
    EEC Risk Statements        R23/24/25- Toxic by inhalation, in contact with skin and if swallowed.    
    R34- Causes burns.
    R45- May cause cancer.
    R46- May cause heritable genetic damage.
    R47- May cause birth defects.
    Japanese Regulatory Data        ENCS No. 1-105; 1-374    
    Continued on Next Page


SECTION 16 - ADDITIONAL INFORMATION
N/A

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