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|Name:||Tetramethylthiuram disulfide 97% Material Safety Data Sheet|
|Synonym:||Bis(dimethylthiocarbamyl) disulfide; Thiram; TMTD|
Synonym:Bis(dimethylthiocarbamyl) disulfide; Thiram; TMTD
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/22 36/38 43 48/22 50/53
Section 3 - HAZARDS IDENTIFICATION
Harmful by inhalation and if swallowed. Irritating to eyes and skin.
May cause sensitization by skin contact. Harmful : danger of serious damage to health by prolonged exposure if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Causes eye irritation.
Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Harmful if inhaled. May cause respiratory tract irritation.
Repeated or prolonged exposure may cause allergic reactions in sensitive individuals.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Use extinguishing media appropriate to the surrounding fire. Substance is noncombustible.
Containers may explode when heated.
Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use water spray, fog or regular foam. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Section 7 - HANDLING and STORAGE
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 137-26-8: United States OSHA: 5 mg/m3 TWA Belgium - TWA: 1 mg/m3 VLE France - VME: 5 mg/m3 VME Germany: 5 mg/m3 TWA (inhalable fraction) Malaysia: 1 mg/m3 TWA Netherlands: 5 mg/m3 MAC Russia: 0.5 mg/m3 TWA Spain: 1 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Wear appropriate protective gloves and clothing to prevent skin exposure.
Wear appropriate protective clothing to minimize contact with skin.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Crystalline powder
Odor: characteristic odor
pH: Not available.
Vapor Pressure: Negligible
Viscosity: Not available.
Boiling Point: 129 deg C @ 20 mmHg
Freezing/Melting Point: > 146 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Solubility in water: and carbon disulfide
Specific Gravity/Density: 1.29 @ 20C
Molecular Formula: C6H12N2S4
Molecular Weight: 240.41
Section 10 - STABILITY AND REACTIVITY
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Acids - oxidizing agents - reducing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
CAS# 137-26-8: JO1400000 LD50/LC50:
CAS# 137-26-8: Draize test, rabbit, eye: 100 mg/24H Moderate; Inhalation, rat: LC50 = 500 mg/m3/4H; Oral, mouse: LD50 = 1250 mg/kg; Oral, rabbit: LD50 = 210 mg/kg; Oral, rat: LD50 = 560 mg/kg.
Tetramethylthiuram disulfide - Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
Shipping Name: Not regulated.
Shipping Name: Not regulated.
Shipping Name: Not regulated.
USA RQ: CAS# 137-26-8: 10 lb final RQ; 4.54 kg final RQ
Section 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
R 20/22 Harmful by inhalation and if swallowed.
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitization by skin contact.
R 48/22 Harmful : danger of serious damage to health
by prolonged exposure if swallowed.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37 Wear suitable protective clothing and
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 137-26-8: No information available.
CAS# 137-26-8 is listed on Canada's DSL List.
CAS# 137-26-8 is listed on Canada's Ingredient Disclosure List.
CAS# 137-26-8 is listed on the TSCA inventory.
SECTION 16 - ADDITIONAL INFORMATION