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Phosphoric Acid Tris(1,3-Dichloro-2-Propyl) Ester 13674-87-8 MSDS
  Tris(1,3-dichloro-2-propyl) Phosphate      Revision number: 5    
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        Tris(1,3-dichloro-2-propyl) Phosphate    
    
  Revision number:        5    

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified    
  HEALTH HAZARDS
  Acute toxicity (Oral)        Category 4    
  ENVIRONMENTAL HAZARDS
  Acute aquatic hazard        Category 2    
    Category 2
  Long-term aquatic hazard
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
  Signal word        Warning    
  Hazard statements        Harmful if swallowed    
    Toxic to aquatic life
    Toxic to aquatic life with long lasting effects
  Precautionary statements:
    Avoid release to the environment.
  [Prevention]
    Do not eat, drink or smoke when using this product.
    Wash hands thoroughly after handling.
  [Response]        IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.    
    Rinse mouth.
    Collect spillage.
    Dispose of contents/container through a waste management company authorized by
  [Disposal]
    the local government.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance    
  Components:        Tris(1,3-dichloro-2-propyl) Phosphate    
  Percent:        >95.0%(GC)    
  CAS Number:        13674-87-8    
  Synonyms:        Phosphoric Acid Tris(1,3-dichloro-2-propyl) Ester    
  Chemical Formula:        C9H15Cl6O4P    
  Tris(1,3-dichloro-2-propyl) Phosphate

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.    
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Rinse skin with    
    water/shower. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present    
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth.    
    A rescuer should wear personal protective equipment, such as rubber gloves and air-
  Protection of first-aiders:
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.    
  media:
  Unsuitable extinguishing Solid streams of water
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.    
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.    
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use personal protective equipment. Keep people away from and upwind of spill/leak.    
  protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled
  emergency procedures: around the leakage area by roping off, etc.
  Environmental precautions: Be careful not to let it flow into rivers, etc., since adverse effects on the environment
    are concerned.
  Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust).
  containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected
  up: material should be promptly disposed of, in accordance with appropriate laws and
    regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.    
    Prevent generation of vapour or mist. Wash hands and face thoroughly after
    handling.
    Use a ventilation, local exhaust if vapour or aerosol will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.    
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Comply with laws.    

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust as possible so that workers should not be    
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection:        Vapor respirator. Follow local and national regulations.    
    Protective gloves.
  Hand protection:
  Eye protection:        Safety glasses. A face-shield, if the situation requires.    
  Tris(1,3-dichloro-2-propyl) Phosphate

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Liquid    
    Clear
  Form:
  Colour:        Colorless - Very pale yellow    
    Slight
  Odour:
  pH: No data available
  Melting point/freezing point:No data available
  Boiling point/range:        252°C/2kPa    
  Flash point:        249°C    
  Flammability or explosive
  limits:
  Lower:        No data available    
  Upper:        No data available    
  Relative density:        1.52    
  Solubility(ies):
  [Water]        Insoluble (7mg/L, 24°C)    
  [Other solvents]
  Soluble:        Many organic solvents    
  Log Pow:        3.65    

Section 10. STABILITY AND REACTIVITY
    Stable under proper conditions.
  Chemical stability:
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Phosphorus oxides, Hydrogen chloride
  products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        skn-rbt LD50:>4640 mg/kg    
    orl-rat LD50:1850 mg/kg
  Skin corrosion/irritation: No data available
  Serious eye        No data available    
  damage/irritation:
  Germ cell mutagenicity: mmo-sat 100 ug/plate (-S9)
    mmo-sat 100 umol/plate (+S9)
  Carcinogenicity:        orl-rat TDLo:58400 mg/kg/2Y-C    
  IARC =        No data available    
    No data available
  NTP =
  Reproductive toxicity:        No data available    
    UB1473000
  RTECS Number:

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        48h LC50:3.7 ppm (Oryzias latipes)    
  Crustacea:        No data available    
  Algae:        No data available    
  Persistence / degradability: 1 % (by BOD), 0 % (by GC)
  Bioaccumulative        0.30 - 3.3 (conc. 0.02 ppm), 2.2 - 22 (conc. 0.002 ppm)    
  potential(BCF):
  Mobility in soil
  Log Pow:        3.65    
  Soil adsorption (Koc):        1497    
    2.6 x 10-4
  Henry's Law
  constant(PaM3/mol):
  Tris(1,3-dichloro-2-propyl) Phosphate

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
    incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
    disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        9: Miscellaneous dangerous goods.    
  UN-No:        3082    
    Environmentally hazardous substance, liquid, n.o.s.
  Proper shipping name:
  Packing group:        III    
    Y
  Marine pollutant

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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