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SAFETY DATA SHEET
Section 1. IDENTIFICATION
Product name: Tris(1,3-dichloro-2-propyl) Phosphate
Revision number: 5
Section 2. HAZARDS IDENTIFICATION
PHYSICAL HAZARDS Not classified
Acute toxicity (Oral) Category 4
Acute aquatic hazard Category 2
Long-term aquatic hazard
GHS label elements, including precautionary statements
Pictograms or hazard symbols
Signal word Warning
Hazard statements Harmful if swallowed
Toxic to aquatic life
Toxic to aquatic life with long lasting effects
Avoid release to the environment.
Do not eat, drink or smoke when using this product.
Wash hands thoroughly after handling.
[Response] IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Dispose of contents/container through a waste management company authorized by
the local government.
Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Components: Tris(1,3-dichloro-2-propyl) Phosphate
CAS Number: 13674-87-8
Synonyms: Phosphoric Acid Tris(1,3-dichloro-2-propyl) Ester
Chemical Formula: C9H15Cl6O4P
Section 4. FIRST AID MEASURES
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical advice/attention if you feel unwell.
Skin contact: Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. If skin irritation or rash occurs: Get medical advice/attention.
Eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical
Ingestion: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth.
A rescuer should wear personal protective equipment, such as rubber gloves and air-
Protection of first-aiders:
Section 5. FIRE-FIGHTING MEASURES
Suitable extinguishing Dry chemical, foam, water spray, carbon dioxide.
Unsuitable extinguishing Solid streams of water
Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
from the chemical: generate poisonous fume.
Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Remove movable
containers if safe to do so.
Special protective When extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:
Section 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, Use personal protective equipment. Keep people away from and upwind of spill/leak.
protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled
emergency procedures: around the leakage area by roping off, etc.
Environmental precautions: Be careful not to let it flow into rivers, etc., since adverse effects on the environment
Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust).
containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected
up: material should be promptly disposed of, in accordance with appropriate laws and
Section 7. HANDLING AND STORAGE
Precautions for safe handling
Technical measures: Handling is performed in a well ventilated place. Wear suitable protective equipment.
Prevent generation of vapour or mist. Wash hands and face thoroughly after
Use a ventilation, local exhaust if vapour or aerosol will be generated.
Advice on safe handling: Avoid contact with skin, eyes and clothing.
Conditions for safe storage, including any
Storage conditions: Keep container tightly closed. Store in a cool and dark place.
Store away from incompatible materials such as oxidizing agents.
Packaging material: Comply with laws.
Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Install a closed system or local exhaust as possible so that workers should not be
exposed directly. Also install safety shower and eye bath.
Personal protective equipment
Respiratory protection: Vapor respirator. Follow local and national regulations.
Eye protection: Safety glasses. A face-shield, if the situation requires.
Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Skin and body protection: Protective clothing. Protective boots, if the situation requires.
Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C): Liquid
Colour: Colorless - Very pale yellow
pH: No data available
Melting point/freezing point:No data available
Boiling point/range: 252°C/2kPa
Flash point: 249°C
Flammability or explosive
Lower: No data available
Upper: No data available
Relative density: 1.52
[Water] Insoluble (7mg/L, 24°C)
Soluble: Many organic solvents
Log Pow: 3.65
Section 10. STABILITY AND REACTIVITY
Stable under proper conditions.
Possibility of hazardous No special reactivity has been reported.
Incompatible materials: Oxidizing agents
Hazardous decomposition Carbon monoxide, Carbon dioxide, Phosphorus oxides, Hydrogen chloride
Section 11. TOXICOLOGICAL INFORMATION
Acute Toxicity: skn-rbt LD50:>4640 mg/kg
orl-rat LD50:1850 mg/kg
Skin corrosion/irritation: No data available
Serious eye No data available
Germ cell mutagenicity: mmo-sat 100 ug/plate (-S9)
mmo-sat 100 umol/plate (+S9)
Carcinogenicity: orl-rat TDLo:58400 mg/kg/2Y-C
IARC = No data available
No data available
Reproductive toxicity: No data available
Section 12. ECOLOGICAL INFORMATION
Fish: 48h LC50:3.7 ppm (Oryzias latipes)
Crustacea: No data available
Algae: No data available
Persistence / degradability: 1 % (by BOD), 0 % (by GC)
Bioaccumulative 0.30 - 3.3 (conc. 0.02 ppm), 2.2 - 22 (conc. 0.002 ppm)
Mobility in soil
Log Pow: 3.65
Soil adsorption (Koc): 1497
2.6 x 10-4
Section 13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
disposing of the substance.
Section 14. TRANSPORT INFORMATION
Hazards Class: 9: Miscellaneous dangerous goods.
Environmentally hazardous substance, liquid, n.o.s.
Proper shipping name:
Packing group: III
Section 15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.
SECTION 16 - ADDITIONAL INFORMATION